赣南北部黄陂河流域离子型稀土矿地区水质与健康风险评价

水质安全和健康是保障中国赣南老区乡村振兴发展的重要因素。赣南离子型稀土矿长期开发利用,导致浸矿剂和矿体中重金属元素等危害人体健康的物质进入水循环系统,给周边乡村饮用水卫生安全带来了潜在风险。目前,针对当地复垦后稀土矿及周边地区水质和健康风险缺乏系统调查评价,本文以《生活饮用水卫生标准》(GB 5749—2006)为评价依据,选择赣南北部黄陂河流域典型离子型稀土矿及周边的水体开展调查研究,采用电感耦合等离子体发射光谱/质谱等技术测定锰、镉等元素含量,采用水质指数(WQI)、危害商(HQ)、致癌风险(CR)评价了锰和铅等9种指标及其健康风险。结果表明：地表水中的异常指标有氨氮(平均值750μg/L)、锰(平均值207μg/L),地下水中的异常指标有氨氮(平均值4533μg/L)、锰(平均值4009μg/L);世界卫生组织(WHO)公布的Ⅰ类致癌物砷在地表水及地下水均未见异常。WQI显示研究区内85.7%的地表水适宜饮用。地表水及地下水中氨氮的HQ平均值<1,对人类健康没有不良影响;地下水中锰的HQ平均值>1,可能会对人类健康产生不良影响。地表水及地下水中致癌元素砷的CR值分布区...     

Geochemistry,Paleoenvironment and Mechanism of Organic-Matter Enrichment in the Lower Silurian Longmaxi Formation Shale in the Sichuan Basin,China

To investigate the mechanism of the organic-matter enrichment in the Lower Longmaxi Formation shale, the geochemistry and total organic carbon(TOC) of the Longmaxi Formation black shales in the Jiaoshiba, Zhaotong, and Weiyuan areas of the Sichuan Basin were analyzed. Paleoproductivity proxy parameters(Babio, Siex, and Ni/Al), clastic influx proxies(TiO_2 and Ti/Al), redox indices(V/Cr, Ni/Co, V/(V+Ni), and U/Th), and hydrothermal indicators(Fe, Mn,and Y concentrations; Fe/Ti ratio and a Ni-Zn-Co diagram) were employed to decipher the paleoenvironment of the Lower Longmaxi Formation shales. TiO_2 and Ti/Al indicated low terrigenous detrital influx in all three areas. However, Babio, Siex,and Ni/Al indicated high productivity in the Jiaoshiba area. V/Cr, Ni/Co, and U/Th indicated higher oxygen content with larger fluctuations in the Zhaotong and Weiyuan areas. Fe, Mn, and Y concentrations and the Fe/Ti ratio implied greater active hydrothermal activity in the Weiyuan area. These heterogeneities were considered to be closely related to the paleoenvironment and paleogeography, and the large basement faults that developed during the Chuanzhong paleo-uplift could have provided vents for deep-hydrothermal-fluid upwelling. The redox indices(V/Cr, Ni/Co, and U/Th) and a paleoproductivity proxy(Ni/Al) displayed a significant correlation with the TOC, suggesting that both excellent preservation conditions and high paleoproductivity were the controlling factors for the enrichment of organic matter in the Longmaxi Formation shale. There was no obvious correlation between the clastic influx proxy(Ti/Al) and the TOC due to the extremely low supply of terrigenous debris. The hydrothermal indicator(Fe/Ti) was negatively correlated with the TOC in the Weiyuan area, indicating that hydrothermal activity may have played a negative role in the accumulation of organic matter. This study suggests that the enrichment of organic matter in the Longmaxi Formation marine shale varied according to the paleogeography and sedimentary environment.     

Drought assessment in a south Mediterranean transboundary catchment

ABSTRACT

Predicting the impacts of climate change on water resources remains a challenging task and requires a good understanding of the dynamics of the forcing terms in the past. In this study, the variability of precipitation and drought patterns is studied over the Mediterranean catchment of the Medjerda in Tunisia based on an observed rainfall dataset collected at 41 raingauges during the period 1973–2012. The standardized precipitation index and the aridity index were used to characterize drought variability. Multivariate and geostatistical techniques were further employed to identify the spatial variability of annual rainfall. The results show that the Medjerda is marked by a significant spatio-temporal variability of drought, with varying extreme wet and dry events. Four regions with distinct rainfall regimes are identified by utilizing the K-means cluster analysis. A principal component analysis identifies the variables that are responsible for the relationships between precipitation and drought variability.     

河南夏季高温日数的时空分布特征及500 hPa环流型

对河南省40个代表站1961-2005年夏季≥35℃高温日数进行经验正交函数(EOF)展开分析,结果显示,前3个典型场基本能反映河南夏季高温日数分布的主要特征,前3个模态的累积方差贡献率达85%.据此,得出河南夏季≥35℃高温日数的时空分布类型为全省一致型、西北至东南差异型和西南至东北差异型.第一模态对应的时间系数序列的变化幅度最大,第二模态对应的时间系数序列的变化幅度比前一个时间序列要小.第一模态的时间系数演变显示,河南夏季高温日数平均呈减少趋势,且存在2～4 a、8～14 a的周期变化,目前河南夏季高温日数正处于偏多状态中.应用逐日20时500 hPa ECMWF北半球格点资料,对1991-2005年河南典型的大面积持续高温下的环流形势进行普查、分类,分别求各种类型下的环流平均场,从而得到河南省高温的两种环流型,即贝加尔湖高压型和副热带高压型.     

风云卫星数据服务评价指标的验证分析

简述了目前我国风云卫星数据服务以及气象服务效益评估业务的现状,利用层次分析法提出风云卫星数据服务评价的6个1级指标和19个2级指标。设计了风云卫星数据服务评测量表,并采用分半信度、因子分析等方法对量表作信度和效度分析,结果表明所设计的评测量表具有良好的信度和效度,确定了包括服务平台易用性、服务流程规范性、服务响应及时性、服务内容完整性、服务工作主动性、服务宣传广泛性等6个方面的风云卫星数据服务评价指标。     

走廊南山河流纵剖面高海拔裂点的成因

河流水力侵蚀物理模型表明基岩河道纵剖面在均衡状态时表现为平滑上凹的形态,其特征反映了构造、基岩抗侵蚀能力和气候的作用;然而自然界河道纵剖面多呈现以裂点为特征的不均衡形态,不均衡的剖面形态以及裂点的研究同样可以对外力作用的变化起到很好的指示作用。位于北祁连的走廊南山高海拔河道纵剖面普遍呈现不均衡形式且发育海拔较高的裂点。通过对裂点成因分析发现,这些裂点并不主要受控于岩性、气候、构造等因素,而反映了冰川作用遗留地形与河流地形的分界。这一结果说明在对河道纵剖面高海拔裂点进行分析时要考虑到古冰川遗留地形也会对现代河道纵剖面产生重要影响,为进一步认识和理解造山带地貌演化以及控制因素提供了思路。     

气候变化对中国集中供暖气候指标的影响

应用高空间分辨率的网格逐日气象数据,根据国家集中供暖有关设计规范定义了集中供暖气候指标,分析了气候变暖对中国集中供暖气候指标的影响。结果表明：近55 a来中国集中供暖初日均呈后延趋势,初日特征线年代际南北移动较小。供暖终日均呈提前趋势,终日特征线在110°E以东地区南北移动较大,2000年以来终日特征线较20世纪60年代北抬了200~300 km。供暖期长度均呈减少趋势,东北、华北地区近55 a减少了10~15 d,西北地区减少了15~20 d;东北、华北、西北地区供暖强度分别减少了12%、20%、15%。从1991~2015年冬季气温变化来看,东北地区最冷冬季与最暖冬季的温度相差可达6.2℃,对供暖强度的影响可达28.9%,华北和西北地区冬季气温最大变幅分别为3.7℃、3.3℃,对供暖强度的影响分别为26.8%和17.6%。气候变暖对中国集中供热气候指标产生了显著的影响。供热部门应该根据天气变化来安排供暖,同时还要注意气候变暖背景下极端冷事件的发生,保证集中供暖安全运行。     

Spatial and Temporal Characteristics of Horizontal Rolls and Cells in the Atmospheric Boundary Layer Based on Radar and in Situ Observations

This paper is the second of a series devoted to the observation and analysis of coherent structures in the cloudy Atmospheric Boundary Layer (ABL) such as horizontal rolls or thermal cells. In the first paper, the TRAC (Turbulence Radar Aircraft Cells) experiment which is the observational support of this investigation based on coupled radar-aircraft measurements, was presented along with an overview of the main results of this campaign held in June 1993 in France. Here the analysis is focused on the spatial characteristics (length-scale, orientation ... ) of the coherent structures, their temporal evolution and vertical distribution deduced from the radar reflectivity fields acquired in clear air at several levels for five different ABLs. For that, an original and efficient image processing method able to extract the major mode of the organisation was developed. These characteristics are examined in relation to the dynamic and thermodynamic state of the ABL using mean and turbulent information as observed by the in-situ aircraft. These experimental results are the basis of a future Large Eddy Simulation modeling of an organised ABL which is in progress and will be the concern of the third paper in the series.     

建筑群对城市冠层动力、热力效应的数值试验研究

利用中尺度模式MM5,分别耦合传统的边界层参数化方案和城市冠层参数化方案,模拟了2001年冬季北京冠层大气的动力、热力特征,并和观测资料进行了对比分析.分析结果表明,城市冠层参数化方案更能细致描述建筑群对城市冠层大气的动力、热力作用.由于建筑群的动力、热力作用,使北京城区的温度升高,风速减小,湍流动能增强,形成了明显的增温区、阻风区和湍能增强区,中心均位于城区高大建筑群附近,并向郊区递减.     

Geochemical constraints on the modes of carbonate precipitation in peridotites from the Logatchev Hydrothermal Vent Field and Gakkel Ridge

The ultramafic-hosted Logatchev Hydrothermal Field (LHF) at 15°N on the Mid-Atlantic Ridge and the Arctic Gakkel Ridge (GR) feature carbonate precipitates (aragonite, calcite, and dolomite) in voids and fractures within different types of host rocks. We present chemical and Sr isotopic compositions of these different carbonates to examine the conditions that led to their formation. Our data reveal that different processes have led to the precipitation of carbonates in the various settings. Seawater-like ⁸⁷Sr/⁸⁶Sr ratios for aragonite in serpentinites (0.70909 to 0.70917) from the LHF are similar to those of aragonite from the GR (0.70912 to 0.70917) and indicate aragonite precipitation from seawater at ambient conditions at both sites. Aragonite veins in sulfide breccias from LHF also have seawater-like Sr isotope compositions (0.70909 to 0.70915), however, their rare earth element (REE) patterns show a clear positive europium (Eu) anomaly indicative of a small (< 1%) hydrothermal contribution. In contrast to aragonite, dolomite from the LHF has precipitated at much higher temperatures (~ 100 °C), and yet its ⁸⁷Sr/⁸⁶Sr ratios (0.70896 to 0.70907) are only slightly lower than those of aragonite. Even higher temperatures are calculated for the precipitation of deformed calcite veins in serpentine–talc fault schists form north of the LHF. These calcites show unradiogenic ⁸⁷Sr/⁸⁶Sr ratios (0.70460 to 0.70499) indicative of precipitation from evolved hydrothermal fluids. A simple mixing model based on Sr mass balance and enthalpy conservation indicates strongly variable conditions of fluid mixing and heat transfers involved in carbonate formation. Dolomite precipitated from a mixture of 97% seawater and 3% hydrothermal fluid that should have had a temperature of approximately 14 °C assuming that no heat was transferred. The much higher apparent precipitation temperatures based on oxygen isotopes (~ 100 °C) may be indicative of conductive heating, probably of seawater prior to mixing. The hydrothermal calcite in the fault schist has precipitated from a mixture of 67% hydrothermal fluid and 33% seawater, which should have had an isenthalpic mixing temperature of ~ 250 °C. The significantly lower temperatures calculated from oxygen isotopes are likely due to conductive cooling of hydrothermal fluid discharging along faults. Rare earth element patterns corroborate the results of the mixing model, since the hydrothermal calcite, which formed from waters with the greatest hydrothermal contribution, has REE patterns that closely resemble those of vent fluids from the LHF. Our results demonstrate, for the first time, that (1) precipitation from pure seawater, (2) conductive heating of seawater, and (3) conductive cooling of hydrothermal fluids in the sub-seafloor all can lead to carbonate precipitation within a single ultramafic-hosted hydrothermal system.