Weathering,Sr fluxes,and controls on water chemistry in the Lake Qinghai catchment,NE Tibetan Plateau

Strontium (Sr) concentrations and isotopic ratios have been measured in a series of water and rock samples from most of the major tributaries of the Lake Qinghai basin on the north‐eastern Tibetan Plateau. Dissolved Sr and ⁸⁷Sr/⁸⁶Sr show ranges of 488–12 240 nmol/l and 0·710497–0·716977, respectively. These data, together with measurements of major cations and anions in rivers and their tributaries and various lithologies of the catchment, were used to determine the contributions of Sr and its isotopic expense to rivers and lakes. Our results demonstrate that the chemical components and ⁸⁷Sr/⁸⁶Sr ratios of the alkaline waters are derived from mixing of carbonate and silicate sources, with the former contributing 72 ± 18% dissolved Sr to rivers. The difference in tributary compositions stems from the lithology of different river systems and low weathering intensity under a semi‐arid condition. Variation in ⁸⁷Sr/⁸⁶Sr ratios places constraint on the Sr‐isotopic compositions of the main tributaries surrounding Lake Qinghai. The water chemistry of the Buha River, the largest river within the catchment underlain by the late Paleozoic marine limestone and sandstones, dominates Sr isotopic composition of the lake water, being buffered by the waters from the other rivers and probably by groundwater. However, the characteristic chemical composition of the lake itself differs remarkably from the rivers, which can be attributed to precipitation of authigenic carbonates (low‐magnesium calcite, aragonite, and dolomite), though this does not impact the Sr isotope signature, which may remain a faithful indicator in paleo‐records. Regarding the potential role of groundwater input within the Lake Qinghai systems in the water budget and water chemistry, we have also determined the Sr concentration and ⁸⁷Sr/^S6Sr ratio of groundwater from diverse environments. This has allowed us to further constrain the Sr isotope systematic of this source. A steady‐state calculation gives an estimate for the groundwater flux of 0·19 ± 0·03 × 10⁸ m³/yr, accounting for about 8% of contemporary lake Sr budget. Copyright © 2010 John Wiley & Sons, Ltd.     

Numerical simulation of two-phase flow for sediment transport in the inner-surf and swash zones

A two-dimensional two-phase flow framework for fluid–sediment flow simulation in the surf and swash zones was described. Propagation, breaking, uprush and backwash of waves on sloping beaches were studied numerically with an emphasis on fluid hydrodynamics and sediment transport characteristics. The model includes interactive fluid–solid forces and intergranular stresses in the moving sediment layer. In the Euler–Euler approach adopted, two phases were defined using the Navier–Stokes equations with interphase coupling for momentum conservation. The k–ε$k''–''\epsilon$ closure model and volume of fluid approach were used to describe the turbulence and tracking of the free surface, respectively. Numerical simulations explored incident wave conditions, specifically spilling and plunging breakers, on both dissipative and intermediate beaches. It was found that the spatial variation of sediment concentration in the swash zone is asymmetric, while the temporal behavior is characterized by maximum sediment concentrations at the start and end of the swash cycle. The numerical results also indicated that the maximum turbulent kinetic energy and sediment flux occurs near the wave-breaking point. These predictions are in general agreement with previous observations, while the model describes the fluid and sediment phase characteristics in much more detail than existing measurements. With direct quantifications of velocity, turbulent kinetic energy, sediment concentration and flux, the model provides a useful approach to improve mechanistic understanding of hydrodynamic and sediment transport in the nearshore zone.     

植物——大气N2O的一个潜在排放源

N₂₂和CH₄的重要温室气体。目前,全球N₂₂₂O不仅是一个普遍存在的自然现象,而且其排放量可达到与土壤排放相比较的水平,因而植物可能是未知的大气N₂O的一个重要排放源;植物排放N₂O受植物的种类、生长发育阶段、养分供给、光照强度及CO₂浓度等因素的影响。     

Experiment of near surface layer parameters in ice camp over Arctic Ocean

Estimates of near surface layer parameters over 78°N drifting ice in ice camp over the Arctic ocean are made using bulk transfer methods with the data from the experiments operated by the Chinese Arctic Scientific Expedition in August 22-September 3,2003.The results show that the net radiation received by the snow surface is only 3.6 W/m2,among which the main part transported into atmosphere in term of sensible heat and latent heat,which account for 52% and 31% respectively,and less part being transported to deep ice in the conductive process.The bulk transfer coefficient of momentum is about 1.16×10-3 in the near neutral layer,which is a little smaller than that obtained over 75°N drifting ice.However,to compare with the results observed over 75°N drifting ice over the Arctic Ocean in 1999,it can be found that the thermodynamic and momentum of interactions between sea and air are significant different with latitudes,concentration and the scale of sea ice.It is very important on considering the effect of sea-air-ice interaction over the Arctic Ocean when studying climate modeling.     

Application of the groundwater-balance equation to indicate interbasin and vertical flow in two semi-arid drainage basins, Mexico

An analysis of horizontal inflow and outflow in the groundwater-budget equation and the significance for interbasin flow are presented. Two field cases in Mexico, one in the Baja California peninsula and another in central Mexico, highlight the influence of interbasin flow. A significant proportion (approximately 70%) of the abstracted (thermal) groundwater probably originates outside the drainage basin. A conclusion is that a groundwater-balance study is an unsatisfactory method for determining some parameters, such as storativity (S). Specifically, the groundwater-balance approach provides unreliable results when vertical inflow is ignored or cannot be adequately defined. Vertical flow is indicated by the presence of groundwater temperatures as much as 23 °C higher than ambient temperature. Regional faults could be the pathways for upward flow. When vertical inflow is ignored, uncertainty in the estimation of the storativity through regional groundwater-balance calculation results. On the basis of the groundwater-balance equation, a value of S=0.19 appears to represent the confined condition of the developed part of the aquifer; this result is several orders of magnitude higher than would be reasonable according to the geological conditions. Findings are useful in evaluating whether a groundwater resource is being "overexploited". Conclusions are instructive in the application of transient-flow computer models, in which vertical flow of less dense water from beneath is not included. Electronic Publication     

Transport of terrestrial organic carbon to the oceans by rivers: re-estimating flux- and burial rates

 This study re-estimates one important component in the global carbon cycle: the modern global fluviatile organic carbon discharge- and burial rates. According to these results, approximately 430×10¹² g of terrestrial organic carbon are transported to the ocean in modern times. This amount is higher than the latest estimates but takes into account new data from Oceania not previously considered in global flux studies. However, only the minor amount of 10% or approximately 43×10¹² gC year^–1 is most likely buried in marine sediments. This amount is similar to the burial of marine organic carbon in the coastal ocean (55×10¹² gC year^–1). Adding both estimates gives approximately 100×10¹² gC year^–1, which is the value calculated by Berner (1982) for "terrestrial" deltaic-shelf sediments. However, the results in this study suggest that on a global scale the organic carbon content in coastal ocean sediments is not solely of terrestrial origin but a mixture of nearly equal amounts of marine and terrestrial organic carbon. The major part of the terrestrial organic carbon that enters the ocean by rivers (approximately 400×10¹² gC year^–1) seems to be either (a) remineralised in the ocean, whereas the mechanism by which the terrestrial organic carbon is oxidised in the ocean are unknown; or (b) is dispersed throughout the oceans and accumulates in pelagic sediments. Received: 9 November 1998 / Accepted: 25 May 1999     

COMPARATIVE STUDIES ON NITROGEN BUDGETS OF CLOSED SHRIMP POLYCULTURE SYSTEMS＂

April to October, 1997 comparative studios on the nitrogen budgets of closed shrimp polyculture systems showed that, in all the studied polyculture systems, nitrogen from feeds and fertilizers were the main input items, which comprised 70.7% - 83.9% of the total input nitrogen, 3.2% - 7.4% of which was provided by nitrogen fixation. It was in monoculture enclosures (Y-4, Y-11 and Y-12) that the percentage reached the maximum value. The output nitrogen in harvested products comprised 10.8% - 24.6% of total input nitrogen, and the highest percentage, 24.6%, was found in shrimp-fish-tagelus polyculture systems. In shrimp monoculture and shrimp-fish polyculture systems, they were 19.1% and 21.9%, respectively. The nitrogen utilization efficiency was different and varied from 12.2% to 20.1%. The highest, 20.1%, was found in shrimp-fish-tagelus polycultttre systems, and the average of 20.0% was found in shrimp-tagelus polyculture systems. The lowest, 12.2%, was found in shrimp monoculture systems.All the nitrogen utilization efficiencies in shrimp-fish systems or shrimp-scallop systems seemed to be higher than that of the monoculture system, but they showed little statistical difference. The main outputs of nitrngen were found in sediment mud, and comprised 48.2% -60.8% of the total input, the lowest percentage was found in shrimp-fish-tagelus polyculture systems, and the highost percentage in shrimp-scallop systems.During the experiment, nitrogen lost through denitrification and ammonia volatilization comprised 1.9% - 6.2%, averaged 2.8%, of the total input, and the loss through seepage comprised 5.9% - 8.9% of the total.The estimated nitrogen attached to the enclosure wall comprised 3.7% - 13.3% of the total, and was highest in shrimp monoculture systems. Compared with the classic shrimp farming industry, the closed shrimp polycul-ture systems may improve the nitrogen utilization efficiency, and hence reduce the environmental impacts on coastal waters. The nitrogen discharging rates for all the studied polyculture systems ranged from 3.0% to 6.0% of total input nitrogen.     

The budgeting problem of a searching firm

This paper explores factors to be taken into consideration in determining the optimal exploration budget for a mining company readying itself for detail work within a mineral province. Optimal strategy is shown to be a combination of results from recent conventional reservation value stopping rules and optimal expenditure models appearing earlier in the literature.     

Development of a GIS-based model for extrapolating mesoscale groundwater recharge estimates using integrated geospatial data sets

A geographic information systems (GIS)-based model was used to derive spatially explicit estimates of recharge using the elevation-dependent chloride mass-balance (EDCMB) approach in a 14-basin area in southwestern Nevada, USA. For each of the 14 basins, a non-linear regression equation was developed relating chloride enrichment to the elevation of spring watersheds. The ratio of chloride enrichment as a function of elevation was used in a GIS framework to transform continuous precipitation data to recharge. Spatial masks that represented two definitions of the lower limits of recharge—one definition based on alluvium/non-alluvium boundaries, the other based on both alluvium/non-alluvium boundaries and an elevation threshold—were applied to each basin. Resultant recharge estimates were then summed for each basin. When compared to summaries of previous recharge estimates for the study area, the EDCMB approach produced results that were within 14 and 3% of two studies, but were significantly greater (31%) than a third. GIS proved to be a very effective tool for combining large spatial data with widely different resolutions into an integrated data set, and also proved to be an efficient mechanism for implementing robust statistical models to estimate recharge.

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Résumé Un modèle basé sur les systèmes d’informations géographiques (SIG) a été utilisé pour obtenir des estimations explicites de la recharge dans l’espace, en utilisant l’approche du bilan des chlorures en fonction de l’altitude (EDCMB en anglais) dans une zone de 14 bassins, dans le Sud-Ouest du Nevada aux Etats-Unis. Pour chacun des 14 bassins, une régression non-linéaire a été établie, reliant l’enrichissement des chlorures à l’altitude des bassins d’alimentation des sources. Le rapport d’enrichissement des chlorures en fonction de l’altitude a été utilisé dans une approche SIG pour transformer des données pluviométriques continues en terme de recharge. Des masques spatiaux représentant deux définitions des limites de recharge les plus basses ont été appliquées à chaque bassin ; l’une basée sur les limites alluvions/autres formations, l’autre sur ces mêmes limites ainsi que sur un seuil altitudinal. Les recharges estimées résultantes ont ensuite été additionnées pour chaque bassin. Comparée aux précédents bilans de recharge estimés dans la zone d’étude, l’approche EDCMB conduit à des résultats se situant entre 14 et 3% de ceux de deux autres études et largement supérieurs (31%) à ceux d’une troisième étude. Le SIG s’est révélé être un outil très efficace pour combiner dans une base de données intégrée, des données spatiales étendues avec des résolutions largement différentes, ainsi que pour implémenter des modèles statistiques conséquents permettant d’estimer la recharge.

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Resumen Se utilizó un modelo basado en un Sistema de Información Geográfico (SIG) para derivar espacialmente estimados explícitos de recarga usando el enfoque de balance de masa de cloruro dependiente de elevación (EDCMB) en un área de 14 cuencas en el suroeste de Nevada, Estados Unidos. Para cada una de las 14 cuencas se desarrolló una ecuación de regresión no linear que relaciona el enriquecimiento de cloruro con la elevación de las cuencas con manantiales. La relación de enriquecimiento de cloruro en función de la elevación se usó en un marco SIG para transformar datos continuos de precipitación a recarga. Se aplicaron máscaras espaciales a cada cuenca las cuales representaron dos definiciones de los límites inferiores de recarga, una definición basada en límites de aluvión/sin aluvión, el otro basado en ambos límites aluvión/sin aluvión y una elevación normal de fondo. Los estimados resultantes de recarga fueron sumados para cada cuenca. Al compararse con estimados de recarga previos para el área de estudio se encontró que el enfoque EDCMB produjo resultados que estaban entre el 14 y 3% de dos estudios pero fueron significativamente mayores (31%) que un tercer estudio. El SIG ha demostrado ser una herramienta muy efectiva para combinar datos espaciales grandes con resoluciones muy distintas en un grupo integrado de datos y también ha mostrado ser un mecanismo eficiente para implementar modelos estadísticos robustos para estimar recarga.