Field measurements of NO and NO2 emissions from fertilized and unfertilized soils

Field measurements of NO and NO₂ emissions from soils have been performed in Finthen near Mainz (F.R.G.) and in Utrera near Seville (Spain). The applied method employed a flow box coupled with a chemiluminescent NO _x detector allowing the determination of minimum flux rates of 2 g N m^-2 h^-1 for NO and 3 g m^-2 h^-1 for NO₂.The NO and NO₂ flux rates were found to be strongly dependent on soil surface temperatures and showed strong daily variations with maximum values during the early afternoon and minimum values during the early morning. Between the daily variation patterns of NO and NO₂, there was a time lag of about 2 h which seem to be due to the different physico-chemical properties of NO and NO₂. The apparent activation energy of NO emission calculated from the Arrhenius equation ranged between 44 and 103 kJ per mole. The NO and NO₂ emission rates were positively correlated with soil moisture in the upper soil layer.The measurements carried out in August in Finthen clearly indicate the establishment of NO and NO₂ equilibrium mixing ratios which appeared to be on the order of 20 ppbv for NO and 10 ppbv for NO₂. The soil acted as a net sink for ambient air NO and NO₂ mixing ratios higher than the equilibrium values and a net source for NO and NO₂ mixing ratios lower than the equilibrium values. This behaviour as well as the observation of equilibrium mixing ratios clearly indicate that NO and NO₂ are formed and destroyed concurrently in the soil.Average flux rates measured on bare unfertilized soils were about 10 g N m^-2 h^-1 for NO₂ and 8 g N m^-2 h^-1 for NO. The NO and NO₂ flux rates were significantly reduced on plant covered soil plots. In some cases, the flux rates of both gases became negative indicating that the vegetation may act as a sink for atmospheric NO and NO₂.Application of mineral fertilizers increased the NO and NO₂ emission rates. Highest emission rates were observed for urea followed by NH₄Cl, NH₄NO₃ and NaNO₃. The fertilizer loss rates ranged from 0.1% for NaNO₃ to 5.4% for urea. Vegetation cover substantially reduced the fertilizer loss rate.The total NO _x emission from soil is estimated to be 11 Tg N yr^-1. This figure is an upper limit and includes the emission of 7 Tg N yr^-1 from natural unfertilized soils, 2 Tg N yr^-1 from fertilized soils as well as 2 Tg N yr^-1 from animal excreta. Despite its speculative character, this estimation indicates that NO _x emission by soil is important for tropospheric chemistry especially in remote areas where the NO _x production by other sources is comparatively small.     

Termites and global methane—another assessment

New CH₄ emission data from a number of Northern and Southern Hemispheric, tropical and temperate termites, are reported, which indicate that the annual global CH₄ source due to termites is probably less than 15 Tg. The major uncertainties in this estimate are identified and found to be substantial. Nevertheless, our results suggest that termites probably account for less than 5% of global CH₄ emissions.     

Further Studies Of Atmospheric Turbulence In Layers Near The Surface: Scaling The Tke Budget Above The Roughness Sublayer

The second of two experimental studies of the TKE budget conducted on sites of different roughness is described, and results are compared. The first took place within a shallow layer above a small field of mostly bare, cultivated soil; the second was carried out above a roughness sublayer of significant depth on an extensive plain of tall dry grass. Budget terms observed in the second study were scaled with a modified u which compensated for effects of an unusually large stress gradient and ensured that the _m functions would be collinear. By showing that the modification becomes negligible in smaller gradients, it is demonstrated that in normal conditions, budgets observed above significant roughness sublayers should be normalized by scaling in terms of the unreduced Reynolds stress at the sublayer's upper surface. This procedure is shown to be consistent with the expectation that TKE budgets in layers near the surface all scale in fundamentally the same way.Other findings include: (1) the fact that most _m functions previously reported are not quite collinear is attributed to a type of overspeeding known to affect three-cup anemometers; (2) revised _m functions, collinear and largely free of the effects of overspeeding, are determined from a well-established characteristic of the linear _m relation for the stable case; (3) data that define collinear _m functions can also be represented with single hyperbolic curves; (4) dissipation is found to be 10 to 15% too small to balance total TKE production in unstable and neutral conditions and to decrease with increasing z/L in thestable regime; and (5) new relations for based on the observed behaviour of the dissipation deficit provide an improved closure for the set of equations that express the budget terms as functions of _m and z/L.     

Gully‐head erosion processes on a semi‐arid valley floor in Kenya: a case study into temporal variation and sediment budgeting

A three year monitoring programme of gully‐head retreat was established to assess the significance of sediment production in a drainage network that expanded rapidly by gully‐head erosion on the low‐angled alluvio‐lacustrine Njemps Flats in semi‐arid Baringo District, Kenya. This paper discusses the factors controlling the large observed spatial and temporal variation in gully‐head retreat rates, ranging from 0 to 15 m a^?1. The selected gullies differed in planform and in runoff‐contributing catchment area but soil material and land use were similar. The data were analysed at event and annual timescales. The results show that at annual timescale rainfall amount appears to be a good indicator of gully‐head retreat, while at storm‐event timescale rainfall distribution has to be taken into account. A model is proposed, including only rainfall (P) and the number of dry days (DD) between storms: which explains 56 per cent of the variation in retreat rate of the single‐headed gully of Lam1. A detailed sediment budget has been established for Lam1 and its runoff‐contributing area (RCA). By measuring sediment input from the RCA, the sediment output by channelized flow and linear retreat of the gully head for nine storms, it can be seen that erosion shifts between different components of the budget depending on the duration of the dry period (DD) between storms. Sediment input from the RCA was usually the largest component for the smaller storms. The erosion of the gully head occurred as a direct effect of runoff falling over the edge (GH_waterfall) and of the indirect destabilization of the adjacent walls by the waterfall erosion and by saturation (GH_mass/storage). The latter component (GH_mass/storage) was usually much larger that the former (GH_waterfall). The sediment output from the gully was strongly related to the runoff volume while the linear retreat, because of its complex behaviour, was not. Overall, the results show that the annual retreat is the optimal timescale to predict retreat patterns. More detailed knowledge about relevant processes and interactions is necessary if gully‐head erosion is to be included in event‐based soil erosion models. Copyright © 2001 John Wiley & Sons, Ltd.     

Solute and isotope constraint of groundwater recharge simulation in an arid environment,Abu Dhabi Emirate,United Arab Emirates

A simple, well-constrained simulation of solute increases in a downgradient direction was used in the shallow unconfined aquifer of eastern Abu Dhabi Emirate (United Arab Emirates). The simulation indicates that the observed exponential increase in solute concentrations results from a combination of upward transport of solutes from underlying mudstones and evaporites, and groundwater losses by evaporation. Groundwater recharge and discharge flux in unconfined regional aquifers in arid regions commonly are difficult to estimate because there are few constraints on the flux of water lost or gained from the system. Total dissolved solids (TDS) and deuterium isotopes (δ²H) in groundwater are used to constrain estimated fluxes to the shallow aquifer of eastern Abu Dhabi Emirate. Vertical upward transport of solutes from underlying mudstones and evaporites accounts for solute increases along approximately the first 80 km of the simulated flow path, but a combination of upward solute transport and evaporation is necessary to explain observed solute concentrations beyond 80 km. Mobilization and transport of solutes in the unsaturated zone by recharging precipitation is not a significant factor.

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Résumé Une simulation simple et bien contrainte de l’augmentation des solutés dans la direction de l’écoulement a été réalisée sur l’aquifère phréatique et libre de l’Est de l’émirat d’Abu Dhabi (émirats Arabes Unis). La simulation indique que l’augmentation observée de solutés, de forme exponentielle, est le produit de la combinaison du transport ascendant de solutés provenant des mudstones et des évaporites sous-jacents, et de l’évaporation des eaux souterraines. La recharge des eaux souterraines et les flux de vidange dans les aquifères régionaux libres des régions arides sont habituellement difficiles à estimer du fait du peu de contraintes agissant sur la perte ou le gain d’eau dans le système. La charge dissoute totale (TDS, en anglais) et les isotopes deutérium (δ²H) des eaux souterraines sont utilisés pour contraindre l’estimation des flux en direction de l’aquifère phréatique de l’Est de l’émirat d’Abu Dhabi. Le transport vertical ascendant des solutés à partir des mudstones et des évaporites fait parti des processus qui concentrent les solutés approximativement le long des 80 premiers kilomètres du trajet des écoulements simulés, mais une combinaison du transport ascendant des solutés et de l’évaporation est nécessaire pour expliquer les concentrations observées en soluté au delà des 80 km. La mobilisation et le transport des solutés par les précipitations efficaces dans la zone non saturée ne représentent pas des facteurs significatifs.

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Resumen Se utilizó una simulación simple y muy restringida, de incrementos de soluto en la dirección del flujo, en el acuífero libre poco profundo del Emirato oriental de Abu Dhabi, (Emiratos árabes Unidos). La simulación indica que el aumento exponencial observado en las concentraciones del soluto, resulta de una combinación de transporte ascendente de solutos desde las evaporitas y lodolitas subyacentes, y por pérdidas del agua subterránea por evaporación. Los flujos de recarga y descarga de agua subterránea, en los acuíferos libres regionales en regiones áridas, normalmente son difíciles estimar, porque hay algunas restricciones en el flujo de agua perdido o ganado por el sistema. Los sólidos disueltos totales (TDS) y los isótopos de deuterio (δ²H) en el agua subterránea, se usan para forzar los flujos estimados hacia el acuífero poco profundo del Emirato oriental de Abu Dhabi. El transporte ascendente vertical de solutos desde las lodolitas y evaporitas subyacentes, involucra los aumentos del soluto a lo largo de aproximadamente los primeros 80 Km. de la dirección de flujo simulada, pero es necesaria una combinación de transporte ascendente del soluto y la evaporación para explicar las concentraciones del soluto observadas más allá de 80 Km. La movilización y transporte de solutos en la zona no saturada, por recarga debida a precipitación, no es un factor significante.

     

Effects of climate change on the groundwater system in the Grote-Nete catchment,Belgium

The effects of climate change on the groundwater systems in the Grote-Nete catchment, Belgium, covering an area of 525 km², is modeled using wet (greenhouse), cold or NATCC (North Atlantic Thermohaline Circulation Change) and dry climate scenarios. Low, central and high estimates of temperature changes are adopted for wet scenarios. Seasonal and annual water balance components including groundwater recharge are simulated using the WetSpass model, while mean annual groundwater elevations and discharge are simulated with a steady-state MODFLOW groundwater model. WetSpass results for the wet scenarios show that wet winters and drier summers are expected relative to the present situation. MODFLOW results for wet high scenario show groundwater levels increase by as much as 79 cm, which could affect the distribution and species richness of meadows. Results obtained for cold scenarios depict drier winters and wetter summers relative to the present. The dry scenarios predict dry conditions for the whole year. There is no recharge during the summer, which is mainly attributed to high evapotranspiration rates by forests and low precipitation. Average annual groundwater levels drop by 0.5 m, with maximum of 3.1 m on the eastern part of the Campine Plateau. This could endanger aquatic ecosystem, shrubs, and crop production.     

Simulation of Atmospheric Boundary Layer Characteristics during Indian Summer Monsoon using Observations from Monsoon Trough Boundary Layer Experiment at Jodhpur, India

The diurnal structure of the boundary layer during Indian summer monsoon period is studied using a one-dimensional meteorological boundary layer model and the observations collected from the Monsoon Trough Boundary Layer Experiment conducted in 1990 at Jodhpur, India. The model was initialized with the observed temperature profiles at 0530 LST on 17 July, 1990 at Jodhpur and was run for 26 hours. The study is carried out with a geostrophic wind speed of 9.5 m s⁻¹ corresponding to the strong wind simulation. The mean thermodynamic and wind structure simulated by the model are in good agreement with those observed from 30 m tower. The computed surface layer characteristics such as the surface fluxes, TKE and standard deviations of velocity components are found to be reasonably in good agreement with those based on turbulence measurements. The shear and buoyancy budget computed from the model are also compared with the turbulence measurements. The integrated cooling budget in the nocturnal boundary layer is examined.     

A sediment budget for a cultivated floodplain in tropical North Queensland,Australia

Sugarcane is grown on the floodplains of northern Queensland adjacent to the Great Barrier Reef lagoon. Sediment and nutrient loss from these sugarcane areas is considered a potential threat to coastal and marine ecosystems. To enable sugarcane cultivation, farmers have structured the landscape into different elements, comprising fields, water furrows, ‘headlands’ and drains. In order to apply appropriate management of the landscape and reduce export of sediment, it is important to identify which of these elements act as sediment sources or sinks. In this study erosion and deposition rates were measured for the different landscape elements in a subcatchment of the Herbert River and used to create a sediment budget. Despite large uncertainties, the budget shows that the floodplain area is a net source of sediment. Estimated sediment export varies between 2 and 5 t ha^?1 y^?1. The relative importance of the landscape elements as sediment sources could also be determined. Plant cane is identified as the most important sediment source. Water furrows generate most sediment, but are a less important source of exported sediment due to their low connectivity. Headlands and minor drains act as sediment traps. Copyright © 2007 John Wiley & Sons, Ltd.     

Atmospheric, oceanic and hydrological contributions to seasonal variations in length of day

 The annual and semiannual residuals derived in the axial angular momentum budget of the solid Earth–atmosphere system reflect significant signals. They must be caused by further excitation sources. Since, in particular, the contribution for the wind term from the atmospheric layer between the 10 and 0.3 hPa levels to the seasonal variations in length of day (LOD) is still missing, it is necessary to extend the top level into the upper stratosphere up to 0.3 hPa. Under the conservation of the total angular momentum of the entire Earth, variations in the oceanic angular momentum (OAM) and the hydrological angular momentum (HAM) are further significant excitation sources at seasonal time scales. Focusing on other contributions to the Earth's axial angular momentum budget, the following data are used in this study: axial atmospheric angular momentum (AAM) data derived for the 10–0.3 hPa layer from 1991 to 1997 for computing the missing wind effects; axial OAM functions as generated by oceanic general circulation models (GCMs), namely for the ECHAM3 and the MICOM models, available from 1975 to 1994 and from 1992 to 1994, respectively, for computing the oceanic contributions to LOD changes, and, concerning the HAM variations, the seasonal estimates of the hydrological contribution as derived by Chao and O'Connor [(1988) Geophys J 94: 263–270]. Using vector representation, it is shown that the vectors achieve a close balance in the global axial angular momentum budget within the estimated uncertainties of the momentum quantities on seasonal time scales. Received: 6 April 2000 / Accepted: 13 December 2000