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61.
The primary occurrence of ruby in the Mogok area, northern Myanmar is exclusively found in marble along with spinel–forsterite-bearing marble and phlogopite–graphite marble. These marble units are enclosed within banded biotite–garnet–sillimanite–oligoclase gneisses. Samples of these marbles collected for C–O stable isotope analysis show two trends of δ13C–δ18O variation resulting most likely from fluid–rock interactions. Ruby-bearing marble and phlogopite–graphite marble follow a trend with coupled C–O depletion, whereas spinel–forsterite-bearing marble follows a δ18O depletion trend with relatively constant δ13C values. Ruby formation might have resulted from CO2-rich fluid–rock interaction, while spinel–forsterite-bearing marble was genetically related to CO2-poor fluid–rock interaction. Both fluids may have arisen from external sources. Based on graphite Raman spectral thermometry, the estimated temperature for phlogopite–graphite marble, and probably ruby-bearing marble, was lower than 607 °C, and for spinel–forsterite-bearing marble, lower than 710 °C. Contrasting C/O diffusion between graphite/ruby/spinel/forsterite and calcite, local variations of isotopic compositions of newly formed minerals as a result of non-pervasive fluid infiltration, and open-system isotopic disturbance during cooling may have affected C-/O-isotopic fractionations between minerals. The estimated high formation temperatures for ruby and spinel/forsterite imply that the parental fluids may have been related to nearby igneous intrusions and/or metamorphic processes. Whether these two types of fluid were genetically related is unclear based on the present data. 相似文献
62.
Krzysztof Birkenmajer Przemysaw Gedl Ryszard Myczyski Jarosaw Tyszka 《Cretaceous Research》2008,29(3):535-549
This is a critical assessment of the paper by Oszczypko et al. (2004: Cretaceous Research 25, 89–113), in which they tried to prove a mid-Cretaceous age for the Szlachtowa (“black flysch”) and Opaleniec Formations, in the Pieniny Klippen Belt, West Carpathians, both of which had previously been shown to be of Jurassic age. We argue that the mid-Cretaceous age assignment is a misinterpretation, primarily resulting from their field samples having been collected from some Cretaceous lithostratigraphic units, tectonically associated with the Jurassic formations, and/or from tectonic contact-breccias involving Jurassic and Cretaceous strata. In addition, we suggest that they have overlooked a number of significant palaeontological papers, published since 1962, which record the presence of in situ ammonites, aptychi, belemnites, thin-shelled bivalves (Bositra), gryphaeids, foraminifera, and ostracod assemblages, all indicating a Jurassic (mainly Aalenian), and not a Cretaceous, age for the Szlachtowa Formation, and also the in situ Jurassic (Bajocian) ammonites and thin-shelled bivalves (Bositra), Bositra-microfacies, and age-diagnostic foraminiferal assemblages of the Opaleniec Formation.Our presentation here of recently published dinocyst data from well-preserved assemblages further supports the Jurassic ages for the Szlachtowa (“black flysch”) and Opaleniec Formations. 相似文献
63.
碱消解-高效液相色谱-电感耦合等离子体质谱法测定生物样品中的甲基汞和乙基汞 总被引:7,自引:2,他引:5
建立了碱消解-高效液相色谱-电感耦合等离子体质谱联用系统测定生物样品中甲基汞(MeHg)与乙基汞(EtHg)的分析方法。为提高灵敏度,选用微流量的PFA雾化器,在优化的检测条件下,MeHg及EtHg检出限可达到0.036μg/L和0.03μg/L;线性范围达到4个数量级,两条工作曲线线性相关系数为1。对1.78μg/L MeHg、1.65μg/L EtHg的混合标准溶液重复测定7次,色谱峰面积的相对标准偏差(RSD)分别为1.79%和1.44%。对标准物质BCR 464(金枪鱼)的分析结果表明,测定值与标准值基本吻合,但略低于标准值;甲基汞和乙基汞的加标回收率分别为85.9%和84.5%。高效液相色谱与质谱联用技术的高灵敏度和低检出限能够满足生物样品中汞形态定量分析的要求。 相似文献
64.
65.
激光拉曼光谱法分析多种显微组分荧光变化及其应用 总被引:1,自引:1,他引:0
利用激发488 nm激光的氩离子激光器作为RENISHAW inVia型激光拉曼光谱仪的光源,建立了多种显微组分荧光变化(FAMM)分析方法,并对镜质体反射率明显抑制的东营凹陷有效烃源岩进行了测定。结果表明,东营凹陷有效烃源岩的有机质类型越好,镜质体反射率抑制程度越高,有效烃源岩的真实成熟度应主要处于0.64%~1.30%,而不是实测镜质体反射率所反映的0.37%~1.10%。 相似文献
66.
高、低煤阶煤层气藏地质特征及控气作用差异性研究 总被引:4,自引:0,他引:4
高、低煤阶煤层气地质特征及控气作用差异性是研究煤层气富集成藏的重要组成部分,是煤层气勘探开发理论研究过程中重要的基础性研究领域之一。本文以中国沁水、阜新盆地和美国粉河盆地等典型的含气盆地为例,探讨了高、低煤阶煤层气的储层物性差异,分析了构造控气和水文地质控气作用的差异性。研究表明,高煤阶气藏含气量高,CH4百分含量高,δ13C1值大于-38.75‰,储层渗透率变化小,储层改造难,构造热事件对煤层气的生成、富集贡献大,持续的水动力使气藏遭到破坏,且破坏幅度大,现今地下水格局对气藏的形成具有一定的影响;低煤阶气藏含气量低,CH4百分含量低,δ13C1值大于-49.11‰,储层渗透率变化大,储层易改造,煤热演化史及煤阶影响着煤层气的生成、富集,在煤层气生成过程中活跃的水动力是甲烷生成的主要的水文地质条件之一,但持续的水动力使气藏遭到破坏,且破坏幅度小,而合适的地层水矿化度则是低煤阶煤层气生成的重要条件,地下水格局对气藏的调整和改造起到决定性的影响。 相似文献
67.
Delineation of groundwater protection zones by the backward particle tracking method: theoretical background and GIS-based stochastic analysis 总被引:1,自引:0,他引:1
Konstadinos N. Moutsopoulos Alexandra Gemitzi Vassilios A. Tsihrintzis 《Environmental Geology》2008,54(5):1081-1090
The backward particle tracking method, an effective and powerful tool that can be used to delineate groundwater protection
zones, is presented. The theoretical background and insights on the applicability of this method are provided. Moreover, the
present work enriches the backward particle tracking method with an uncertainty analysis concerning the porosity values, applying
a Monte Carlo (MC) approach, coupled with the use of geographical information systems (GIS). As an application example, a
wellfield in the Komotini area, Greece, is investigated. The present study may serve as a potential guideline for wellfield
delineation, particularly in areas like Greece where lack of data related to the hydrogeological system is often a problem. 相似文献
68.
The largest karst cave discovered in a tunnel during motorway construction in Slovenia’s Classical Karst (Kras) 总被引:1,自引:0,他引:1
Karst researchers of the Karst Research Institute ZRC SAZU are regularly consulted during the planning of Slovenia’s motorways
and invited to observe and monitor construction in the karst areas. More than 350 caves have been discovered in the course
of building 60 km of new motorways over the past decade. Access to the most important caves is preserved by concrete tubes
closed with metal covers at the roadside. The largest cave system in a tunnel, named LC-S647, is almost entirely preserved.
The protection of this cave will serve as a good example for the preservation of natural heritage in the future. Construction
work for the motorway uncovered a high degree of karstification. In particular, the discovery of this cave in the Kastelec
tunnel LC-S647 showed the existence of a major cave system in the geological and speleological past. A number of unconnected
passages have also been found. Caves discovered during highway construction have brought new knowledge about the cavernosity
and the geological history of this part of the karst. 相似文献
69.
Landslide susceptibility mapping for a landslide-prone area (Findikli,NE of Turkey) by likelihood-frequency ratio and weighted linear combination models 总被引:17,自引:0,他引:17
Landslides are very common natural problems in the Black Sea Region of Turkey due to the steep topography, improper use of
land cover and adverse climatic conditions for landslides. In the western part of region, many studies have been carried out
especially in the last decade for landslide susceptibility mapping using different evaluation methods such as deterministic
approach, landslide distribution, qualitative, statistical and distribution-free analyses. The purpose of this study is to
produce landslide susceptibility maps of a landslide-prone area (Findikli district, Rize) located at the eastern part of the
Black Sea Region of Turkey by likelihood frequency ratio (LRM) model and weighted linear combination (WLC) model and to compare
the results obtained. For this purpose, landslide inventory map of the area were prepared for the years of 1983 and 1995 by
detailed field surveys and aerial-photography studies. Slope angle, slope aspect, lithology, distance from drainage lines,
distance from roads and the land-cover of the study area are considered as the landslide-conditioning parameters. The differences
between the susceptibility maps derived by the LRM and the WLC models are relatively minor when broad-based classifications
are taken into account. However, the WLC map showed more details but the other map produced by LRM model produced weak results.
The reason for this result is considered to be the fact that the majority of pixels in the LRM map have high values than the
WLC-derived susceptibility map. In order to validate the two susceptibility maps, both of them were compared with the landslide
inventory map. Although the landslides do not exist in the very high susceptibility class of the both maps, 79% of the landslides
fall into the high and very high susceptibility zones of the WLC map while this is 49% for the LRM map. This shows that the
WLC model exhibited higher performance than the LRM model. 相似文献
70.
Historical evidence shows block breakdown and collapse are actively occurring in large fault aligned caverns in the Yorkshire Dales karst. Deployment of ground penetrating radar at two such sites has provided detailed images of the sedimentary sequences below the present day cavern floor but no large blocks are imaged within the sediments. Solutional processes must be removing limestone from the sediment to allow continued cavern growth. Possible mechanisms to account for the lack of large blocks within the sediment fill are discussed. 相似文献