How tides and river flows determine estuarine bathymetries

For strongly tidal, funnel-shaped estuaries, we examine how tides and river flows determine size and shape. We also consider how long it takes for bathymetric adjustment, both to determine whether present-day bathymetry reflects prevailing forcing and how rapidly changes might occur under future forcing scenarios.Starting with the assumption of a 'synchronous' estuary (i.e., where the sea surface slope resulting from the axial gradient in phase of tidal elevation significantly exceeds the gradient in tidal amplitude ), an expression is derived for the slope of the sea bed. Thence, by integration we derive expressions for the axial depth profile and estuarine length, L, as a function of and D, the prescribed depth at the mouth. Calculated values of L are broadly consistent with observations. The synchronous estuary approach enables a number of dynamical parameters to be directly calculated and conveniently illustrated as functions of and D, namely: current amplitude Û, ratio of friction to inertia terms, estuarine length, stratification, saline intrusion length, flushing time, mean suspended sediment concentration and sediment in-fill times.Four separate derivations for the length of saline intrusion, L_I, all indicate a dependency on (U_o is the residual river flow velocity and f is the bed friction coefficient). Likely bathymetries for `mixed' estuaries can be delineated by mapping, against and D, the conditions L<sub>I</sub>/L<1,E<sub>X</sub>/L<1 (E<sub>X</sub> is the tidal excursion) alongside the Simpson-Hunter criteria D/U<sup>3</sup><50 m<sup>−2</sup> s<sup>3</sup>. This zone encompasses 24 out of 25 `randomly' selected UK estuaries.However, the length of saline intrusion in a funnel-shaped estuary is also sensitive to axial location. Observations suggest that this location corresponds to a minimum in landward intrusion of salt. By combining the derived expressions for L and L_I with this latter criterion, an expression is derived relating D_i, the depth at the centre of the intrusion, to the corresponding value of U_o. This expression indicates U_o is always close to 1 cm s⁻¹, as commonly observed. Converting from U_o to river flow, Q, provides a morphological expression linking estuarine depth to Q (with a small dependence on side slope gradients).These dynamical solutions are coupled with further generalised theory related to depth and time-mean, suspended sediment concentrations (as functions of and D). Then, by assuming the transport of fine marine sediments approximates that of a dissolved tracer, the rate of estuarine supply can be determined by combining these derived mean concentrations with estimates of flushing time, F_T, based on L_I. By further assuming that all such sediments are deposited, minimum times for these deposition rates to in-fill estuaries are determined. These times range from a decade for the shortest, shallowest estuaries to upwards of millennia in longer, deeper estuaries with smaller tidal ranges.     

Trace element diagenesis in pyrite-rich sediments of the Achterwasser lagoon, SW Baltic Sea

The early diagenesis of trace elements (V, Cr, Co, Cu, Zn, As, Cd, Ba, U) in anoxic sediments of the Achterwasser, a shallow lagoon in the non-tidal Oder estuary in the Baltic Sea, was investigated in the context of pyrite formation. The dissolved major redox parameters show a two-tier distribution with transient signals in the occasionally re-suspended fluid mud layer (FM) and a permanently established diagenetic sequence in the sediment below. Intense microbial respiration leads to rapid depletion of O₂ within the uppermost mm of the FM. The reduction zones of Mn, Fe and sulfate overlap in the FM and in the permanently anoxic sediment section which appears to be a typical feature of estuarine sediments, under low-sulfate conditions. Degrees of pyritization (DOP) range from 50% in the FM to remarkably high values > 90% at 50 cm depth. Pyrite formation at the sediment surface is attributed to the reaction of Fe-monosulfides with intermediate sulfur species via the polysulfide pathway. By contrast, intense pyritization in the permanently anoxic sediment below is attributed to mineral growth via adsorption of aqueous Fe-sulfide complexes onto pyrite crystals which had originally formed in the surface layer.The studied trace elements show differential behavior patterns which are closely coupled to the diagenetic processes described above: (i) Zn, Cu and Cd are liberated from organic matter in the thin oxic layer of the sediment and diffuse both upwards across the sediment/water boundary and downwards to be trapped as monosulfides, (ii) V, Cr, Co and As are released during reductive dissolution of Mn- and Fe-oxyhydroxides, (iii) U removal from pore water occurs concomitantly to Fe reduction in the FM and is attributed to reduction of U(VI) to U(IV), (iv) the Ba distribution is controlled by reductive dissolution of authigenic barite in the sulfate reduction zone coupled with upward diffusion and re-precipitation. The incorporation of trace elements into pyrite is most intense for Co, Mn and As, intermediate for Cu and Cr and little to negligible for U, Zn, Cd, V and Ba. The observed trend is largely in agreement with previous studies and may be explained with differing rates for ligand exchange. Slow and fast ligand exchange and thus precipitation kinetics are also displayed by downcore increasing (Mn, Cr, Co and As) or constantly low (Zn, Cu, Cd) pore water concentrations. The downward increasing degrees of trace metal pyritization (DTMP) for Co, Cu, Zn and As are, in analogy to pyrite growth, assigned to adsorption of sulfide complexes or As oxyanions onto preexisting pyrite minerals.     

海沧邻近海域表层沉积物中重矿物研究

对厦门海沧邻近海域表层沉积物中的重矿物(0．063～0．125mm粒级)进行了分析和研究，结果表明该粒级的重矿物共计49种，其优势和特征矿物为磁铁矿、赤铁矿、褐铁矿、绿帘石、铁铁矿、角闪石、锆石、红柱石等；重矿物的平均质量分数为9．56％；根据重矿物的分布和含量，并结合主要标志矿物的颗粒百分含量和分布特征，将该海域划分为5个矿物组合区，根据各区的矿物组合类型分析了该海域的物质来源及影响重矿物分布和组合的因素，进而探讨了九龙江河口湾和厦门西港海湾的沉积环境。     

大亚湾海域锥状斯氏藻赤潮及其与孢囊的关系

用沉积物捕捉器取样，研究了大亚湾海域２０００年６～９月孢囊（Ｃｙｓｔ）种群动态，同时 分析了浮游植物种群动态。研究期间（８～９月）该海域发生了一起大规模的锥状斯氏藻赤潮。 赤潮前一个月，锥状斯氏藻孢囊的平均日形成率为２．０５× １０５ｃｙｓｔｓ／（ｍ２·ｄ），丰度为５０．２２％， 该时期以有性生殖产生的静止期孢囊为主；在赤潮盛期的８，９月初，孢囊的平均日形成率达到 ２．０１ ×１０６ｃｙｓｔｓ／（ｍ２·ｄ），丰度为９６．９７％，此时期的孢囊多为营养细胞所形成的暂时性孢囊； 赤潮结束后，由于环境条件的恶化，暂时性孢囊的形成达到高峰，平均日形成率为１．２４×ｌ０７ ｃｙｓｔｓ／（ ｍ２·ｄ），丰度为９９.５３％。结果表明大亚湾丰富的孢囊是潜在的种源（Ｓｅｅｄ　ｂｅｄ），２０００年 的夏季、秋李持续高温（＞２５℃），台风减少及风力减弱等有利锥状斯氏藻的环境条件诱发孢 囊萌发，开始了该种类的赤潮。     

菊花岛海区沉积物类型及矿物特征初探

本文对菊花岛海区沉积物类型，重矿物和粘土矿物组合分区及其分布特征进行了分析，同时对测区沉积物来源进行探讨。     

薛家岛湾沉积动力学特征及海港开发研究

于１９９０年秋对胶州湾内的薛家岛湾进行海洋水动力条件及积动力学特征,泥沙运动规律研究,为开发建设港口提供科学依据。结果表明,湾内深大于１ｍ的海底泥沙发生“全面移动”的时间,一年内仅有１－２ｄ,其余处于稳定状态或“表面移动”状态。湾内泥沙来源很少,预计建港后,港池和航道年平均回淤量分别小于１６ｃｍ,１０ｃｍ对于开发中小型港口十分有利。     

Evaluation of the Risk of Marine Slope Instability: A Pseudo-3D Approach for Application to Large Areas

This article presents a methodology developed to evaluate the instability of submarine slopes that extend over a large area. Special attention was paid to (1) the complex geometry (bathymetry) and the expanse of the slope, (2) the heterogeneity of the sediment, and (3) the distribution of the pore pressure. The safety factor was considered as a spatially varying quantity. The General Formulation (GLE, Fredlund and Krahn 1977), which fully satisfies equilibrium conditions, was used for evaluating the stability of the marine slope. The submarine slope failure, which occurred on 16 October 1979 during the construction of the new Nice airport, was studied in order to test the developed model. Geotechnical parameters were taken from experimental tests carried out by IFREMER on 19 cores extracted at different depths (from 27 m to 1300 m) (Cochonat, Bourillet, and Savoye, 1993; Mulder et al., 1994). Many scenarios were proposed in order to explain the cause of the Nice slope failure (Habib, 1994). In this article, two of those scenarios were tested. Simulation results are presented and discussed.     

Non-local impact of large-scale engineering in harbors and gulfs on the environment

A system of numerical tools to predict the non-local long-term impact of large-scale constructions on the environment is described. The predictions have to be results of successive examination of free water oscillations, turbulent boundary layers on the sea bottom, and turbulent pulsation effects on sediment transport. Numerical results related to free water oscillations in diverse gulfs are shown, and non-local effects of the dam construction are found for an example of the Baltic Sea. Feasibility of suggested tools for turbulent flow is manifested.     

Particulate barium fluxes and export production in the northwestern Mediterranean

Biogenic barium, mostly in the barite (BaSO₄) form, has been proposed as a tracer for export production in the ocean. Here we report on biogenic barium (Ba_xs) and particulate organic carbon (POC) fluxes from sediment traps deployed at the DYFAMED site in the Northwestern Mediterranean Sea. Ba_xs fluxes display average values of 37 ± 45 and 50 ± 58 μg/m²/d at 200 and 1000 m respectively, and are linearly correlated to POC fluxes (mean values of 7.9 ± 9.3 and 6.8 ± 6.8 mg C/m²/d at 200 and 1000 m). Export production estimates, calculated using published Ba_xs- or POC-based algorithms, all fall below or close to the lower limit of potential export values proposed in the literature. This work clearly demonstrates the usefulness of Ba_xs as a tracer of oceanic export production in the Northwestern Mediterranean Sea. However, development of a quantitative export production proxy requires a clear understanding of the underlying cause(s) for the observed spatial variations in the relationship between Ba_xs and POC fluxes. The present study confirms that the processes leading to barite formation differ between margin and open-ocean sites and probably account for much of the regional variability in the POC/Ba_xs ratio.     

Determination of phospholipid fatty acid structures and stable carbon isotope compositions of deep-sea sediments of the Northwest Pacific, ODP site 1179

Sediment samples ranging from 0.05 to 278 m below sea floor (mbsf) at a Northwest Pacific deep-water (5564 mbsl) site (ODP Leg 191, Site 1179) were analyzed for phospholipid fatty acids (PLFAs). Total PLFA concentrations decreased by a factor of three over the first meter of sediment and then decreased at a slower rate to approximately 30 mbsf. The sharp decrease over the first meter corresponds to the depth of nitrate and Mn(IV) reduction as indicated by pore water chemistry. PLFA-based cell numbers at site 1179 had a similar depth profile as that for Acridine orange direct cell counts previously made on ODP site 1149 sediments which have a similar water depth and lithology. The mole percentage of straight chain saturated PLFAs increases with depth, with a large shift between the 0.95 and 3.95 mbsf samples. PLFA stable carbon isotope ratios were determined for sediments from 0.05 to 4.53 mbsf and showed a general trend toward more depleted δ¹³C values with depth. Both of these observations may indicate a shift in the bacterial community with depth across the different redox zones inferred from pore water chemistry data. The PLFA 10me16:0, which has been attributed to the bacterial genera Desulfobacter in many marine sediments, showed the greatest isotopic depletion, decreasing from − 20 to − 35‰ over the first meter of sediment. Pore water chemistry suggested that sulfate reduction was absent or minimal over this same sediment interval. However, 10me16:0 has been shown to be produced by recently discovered anaerobic ammonium oxidizing (anammox) bacteria which are known chemoautotrophs. The increasing depletion in δ¹³C of 10me16:0 with the unusually lower concentration of ammonium and linear decrease of nitrate concentration is consistent with a scenario of anammox bacteria mediating the oxidation of ammonium via nitrite, an intermediate of nitrate reduction.