Experimental synthesis and phase relations of phengitic muscovite from 6.5 to 11 GPa in a calcareous metapelite from the Dabie Mountains, China

The stability and phase relations of phengitic muscovite in a metapelitic bulk composition containing a mixed H₂O+CO₂ fluid were investigated at 6.5–11 GPa, 750–1050°C in synthesis experiments performed in a multianvil apparatus. Starting material consisted of a natural calcareous metapelite from the coesite zone of the Dabie Mountains, China, ultrahigh-pressure metamorphic complex that had experienced peak metamorphic pressures greater than 3 GPa. The sample contains a total of 2.1 wt.% H₂O and 6.3 wt.% CO₂ bound in hydrous and carbonate minerals. No additional fluid was added to the starting material. Phengite is stable in this bulk composition from 6.5 to 9 GPa at 900°C and coexists with an eclogitic phase assemblage consisting of garnet, omphacite, coesite, rutile, and fluid. Phengite dehydrates to produce K-hollandite between 8 and 11 GPa, 750–900°C. Phengite melting/dissolution occurs between 900°C and 975°C at 6.5–8 GPa and is associated with the appearance of kyanite in the phase assemblage. The formation of K-hollandite is accompanied by the appearance of magnesite and topaz-OH in the phase assemblage as well as by significant increases in the grossular content of garnet (average X_grs=0.52, X_py=0.19) and the jadeite content of omphacite (X_jd=0.92). Mass balance indicates that the volatile content of the fluid phase changes markedly at the phengite/K-hollandite phase boundary. At P≤8 GPa, fluid coexisting with phengite appears to be relatively CO₂-rich (XCO₂/XH₂O=2.2), whereas fluid coexisting with K-hollandite and magnesite at 11 GPa is rich in H₂O (XCO₂/XH₂O=0.2). Analysis of quench material and mass balance calculations indicate that fluids at all pressures and temperatures examined contain an abundance of dissolved solutes (approximately 40 mol% at 8 GPa, 60 mol% at 11 GPa) that act to dilute the volatile content of the fluid phase. The average phengite content of muscovite is positively correlated with pressure and ranges from 3.62 Si per formula unit (pfu) at 6.5 GPa to 3.80 Si pfu at 9 GPa. The extent of the phengite substitution in muscovite in this bulk composition appears to be limited to a maximum of 3.80–3.85 Si pfu at P=9 GPa. These experiments show that phengite should be stable in metasediments in mature subduction zones to depths of up to 300 km even under conditions in which aH₂O1. Other high-pressure hydrous phases such as lawsonite, MgMgAl-pumpellyite, and topaz-OH that may form in subducted sediments do not occur within the phengite stability field in this system, and may require more H₂O-rich fluid compositions in order to form. The wide range of conditions under which phengite occurs and its participation in mixed volatile reactions that may buffer the composition of the fluid phase suggest that phengite may significantly influence the nature of metasomatic fluids released from deeply subducted sediments at depths of up to 300 km at convergent plate boundaries.     

富铌玄武岩：板片熔体交代的地幔楔橄榄岩部分熔融产物

富铌玄武岩是一类具有特殊地球化学特征的岛弧玄武岩。与正常岛弧玄武岩相比，它具有硅饱和并富钠的特征；同时具有相对高的Nb（一般>7×10-6）、TiO2（1%～2%）和P含量，以及低的LILE/HFSE和HREE/HFSE比值，并富集高场强元素；它的原始地幔标准化微量元素图显示了弱的Nb、Ta负异常（有时出现弱的正异常），原始地幔标准化La/Nb比值小于2（但很少小于0.7），它是由受埃达克质熔体交代过的地幔橄榄岩部分熔融形成的。由于富铌玄武岩与埃达克岩是大洋板片俯冲作用的直接产物，因此，通过对该岩石组合及与俯冲作用有关的流体和熔体的研究，不仅可以查明洋壳俯冲作用过程中的岩浆活动特征，还可以阐明洋壳俯冲及壳幔相互作用，具十分重要的地质意义。     

拉萨地块北部去申拉组火山岩:班公湖-怒江特提斯洋南向俯冲的产物?

拉萨地块广泛分布有中生代的岩浆活动,研究它们对于认识特提斯洋的演化和理解整个青藏高原的形成过程有着重要的启示。本文首次对出露于拉萨地块北缘的去申拉组火山岩进行了详细的主、微量及同位素地球化学研究,结果显示去申拉组火山岩主要包括亚碱性的玄武岩、玄武安山岩、安山岩,主体为中钾钙碱性系列;其明显亏损高场强元素(Nb、Ta、Ti等),相对富集大离子亲石元素(Rb、Ba、Sr等),具有岛弧火山岩的特征;稀土元素配分模式主体表现为轻稀土元素富集右倾型,少数具有较平坦的配分模式,无Eu异常;具有低Sr、高Nd(εNd:0.32～5.29)同位素特征,表明其源于亏损的地幔源区,暗示其为俯冲带地幔楔部分熔融的产物。结合区域地质资料及前人的研究成果,认为去申拉组火山岩代表了特提斯班公湖-怒江洋盆沿拉萨地块北缘南向俯冲消减的产物,从而为中生代班公湖-怒江洋盆的南向俯冲消减提供了直接的岩石学证据。     

新疆布鲁斯台辉长岩岩石学特征及对南天山洋俯冲时限的制约

布鲁斯台辉长岩位于中天山南缘缝合带中段古洛沟蛇绿岩以北30km,是该带上出露的为数不多的较大的基性侵入岩体。辉长岩主要由斜长石(35%~45%)、单斜辉石(20%~25%)和角闪石(30%~35%)组成,角闪石主要为交代辉石后的产物。岩石化学成分显示,辉长岩具有高Al2O3(15.43%~23.20%)和CaO(12.96%~14.48%),低碱K2O(0.13%~0.19%)、Na2O(1.47%~3.00%)、P2O5(0.03%~0.07%)和TiO2(0.34%~0.61%)的特征。辉长岩稀土元素球粒陨石标准化配分模式与E-MORB相似,但ΣREE低(12.91×10-6~23.14×10-6),微量元素具有Ba、U、K、Sr等LILE富集和Nb、Ta、Zr、Hf、Th等HFSE亏损的特点。锆石原位εHf(t)值为+9.7~+15.0。上述特征反映辉长岩形成的构造背景为活动大陆边缘,源区为受俯冲流体影响的亏损地幔橄榄岩,且在上升的过程中未遭受地壳的明显混染。La、Sm、Yb判别图解显示岩石可能是亏损的尖晶石二辉橄榄岩发生5%~10%的部分熔融的产物。锆石LA-ICP-MS测年表明,辉长岩形成年龄为316.8±2.1Ma(MSWD=3.4,n=36)。结合区域地质、年代学和地球化学的资料,我们提出至少在晚石炭世,南天山洋还存在洋内和洋陆俯冲事件,南天山洋闭合的时间可能在更晚的早二叠世,而不是志留纪或者早泥盆世。     

大洋环流的通风温跃层研究进展

介绍了大洋环流理论中通风温跃层研究的主要进展。给出了温跃层研究的发展过程、有关通风温跃层的基本概念、通风温跃层内环流的基本特征以及环流通风的计算结果。突出强调了在给出大洋的表面边界条件的情况下,如风应力旋度、背景层化、混合层深度、混合层密度分布以及侧边界条件,如何由通风温跃层理论得到大洋在三维尺度上水体运动的特征。     

古太平洋板块俯冲-增生时限：饶河增生杂岩的地球化学和年代学制约

饶河杂岩作为那丹哈达增生杂岩的主体,是古太平洋板块西向俯冲的直接证据。饶河增生杂岩组成与增生过程的研究对限定古太平洋板块向欧亚大陆的俯冲与增生过程具有重要的指示意义。本文在野外地质调查和饶河大岱地区大比例尺填图基础上,明确了饶河杂岩主要由枕状玄武岩、辉长岩以及大洋板块沉积地层(OPS)组成,这些岩石均呈构造透镜体状分布在海沟沉积物中,并被中生代花岗质岩脉所穿切,因此为限定饶河增生杂岩的组成、增生和就位时代提供了关键制约。地球化学数据表明玄武岩具有洋岛玄武岩(OIB)的地球化学属性。LA-ICPMS锆石测试结果表明该地区玄武岩和辉长岩的形成时代分别为166±2Ma和214±5Ma,限定了饶河杂岩中镁铁质-超镁铁质岩石的形成时代为晚三叠世至中侏罗世。结合该区粉砂质泥岩和砂岩的沉积时代下限分别为167±3Ma和133±4Ma,表明饶河杂岩的增生时代为167～133Ma,此外样品的碎屑年龄信息表明基质的物源为邻近的佳木斯地块和中亚造山带东段,其中前寒武的碎屑年龄在中国东北的多个陆块均有出现,可能源于早前存在的前寒武纪基底。本文测得侵入饶河杂岩的2个二长花岗岩形成年龄分别为126±1Ma和105±2Ma,表明饶河杂岩中的花岗岩脉主要形成于两个阶段,其中较老的花岗岩侵入体进一步限定了饶河杂岩的最终就位时代为133Ma至126Ma,表明古太平洋板块在中侏罗世至早白垩世存在西向俯冲-增生作用,为古太平洋板块的构造演化提供了重要的制约。     

Formation of intrathermocline eddies at ocean fronts by wind-driven destruction of potential vorticity

A mechanism for the generation of intrathermocline eddies (ITEs) at wind-forced fronts is examined using a high resolution numerical simulation. Favorable conditions for ITE formation result at fronts forced by “down-front” winds, i.e. winds blowing in the direction of the frontal jet. Down-front winds exert frictional forces that reduce the potential vorticity (PV) within the surface boundary in the frontal outcrop, providing a source for the low-PV water that is the materia prima of ITEs. Meandering of the front drives vertical motions that subduct the low-PV water into the pycnocline, pooling it into the coherent anticyclonic vortex of a submesoscale ITE. As the fluid is subducted along the outcropping frontal isopycnal, the low-PV water, which at the surface is associated with strongly baroclinic flow, re-expresses itself as water with nearly zero absolute vorticity. This generation of strong anticyclonic vorticity results from the tilting of the horizontal vorticity of the frontal jet, not from vortex squashing. During the formation of the ITE, high-PV water from the pycnocline is upwelled alongside the subducting low-PV surface water. The positive correlation between the ITE’s velocity and PV fields results in an upward, along-isopycnal eddy PV flux that scales with the surface frictional PV flux driven by the wind. The relationship between the eddy and wind-induced frictional PV flux is nonlocal in time, as the eddy PV flux persists long after the wind forcing is shut off. The ITE’s PV flux affects the large-scale flow by driving an eddy-induced transport or bolus velocity down the outcropping isopycnal layer with a magnitude that scales with the Ekman velocity.     

胶北晚中生代煌斑岩的岩石地球化学特征及其成因研究

胶北煌斑岩分别采自龙口、烟台和威海地区，包括拉辉煌斑岩、斜闪正煌岩和角闪煌斑岩，煌斑岩K—Ar全岩年龄变化于89．3～169．5Ma，为晚中生代岩浆活动的产物。在岩石化学组成上，SiO2=42．02％～54．95％，以钙碱性系列为主．岩石以富集大离子亲石元素（LILE）（Ba，U，K，Th）和LREE，亏损高场强元素（HFSE）（Nb，Ta和Ti）为特征，Mg^#=33．9～53．9，Eu／Eu^＊=0．71～0．89，^87Sr／^86Sr初始比值0．707642～0．709791，εNd（t）为-17．6～-10．4，^206Pb／^204Pb=37．588～38．431，^207Pb／^204Pb=15．423～15．531，^206Pb／^204Pb=17．204～18．179。表明煌斑岩源自俯冲陆壳（扬子下地壳）在地幔源区发生交代作用时形成的富集型地幔的部分熔融体．考虑到煌斑岩具有大陆边缘弧玄武岩的特征，我们认为煌斑岩在成因上同样与古大洋板块的俯冲作用有关，为碰撞后弧岩浆作用形成的脉岩。     

南苏鲁芝麻房石榴石橄榄岩中橄榄石的“C”类组构及其形成条件探讨

上地幔地震的各向异性主要归因于橄榄石的优选方位,不同的橄榄石优选方位模式可以作为上地幔不同动力学作用的指示剂。不同应力和含水量条件下的高温变形实验已经确定出五类橄榄石组构模式(“A”型、“B”型、“C”型、“D”型和“E”型)。本文运用电子背散射(EBSD)技术对来自苏鲁超高压变质带南部的芝麻房石榴石橄榄岩的橄榄石进行了优选方位测定,不同变形程度的橄榄石均显示了[100]轴近垂直于面理和[001]轴近平行于线理的特征,为“C”类组构模式,可见组构类型与变形程度没有关系,并且橄榄石组构所显示的NW向SE的剪切指向,与围岩-正、副片麻岩中形成于折返过程的石英优选方位所显示的SE向NW的剪切指向完全不同,说明芝麻房石榴石橄榄岩中橄榄石的“C”类组构是折返前形成的。结合橄榄石结构水的测量和已有的芝麻房石榴石橄榄岩形成的温压条件,推测该组构形成于含水俯冲带中,认为芝麻房石榴石橄榄岩的原岩来自于高含水的上部地幔楔碎块,与俯冲的陆壳物质一起经历了超高压变质作用并最终折返至地表。     

http://www.sciencedirect.com/science/article/pii/S1674987114001121

The Chinese Tianshan belt of the southern Altaids has undergone a complicated geological evolution.Different theories have been proposed to explain its evolution and these are still hotly debated.The major subduction polarity and the way of accretion are the main problems.Southward,northward subduction and multiple subduction models have been proposed.This study focuses on the structural geology of two of the main faults in the region,the South Tianshan Fault and the Nikolaev Line.The dip direction in the Muzhaerte valley is southward and lineations all point towards the NW.Two shear sense motions have been observed within both of these fault zones,a sinistral one,and a dextral one,the latter with an age of 236-251 Ma.Structural analyses on the fault zones show that subduction has been northward rather than southward.The two shear sense directions indicate that the Yili block was first dragged along towards the east due to the clockwise rotation of the Tarim block.After the Tarim block stopped rotating,the Yili block still kept going eastward,inducing the dextral shear senses within the fault zones.