俯冲带碳酸盐化对深部碳循环的启示:以中国西南天山碳酸盐化云母片岩为例

俯冲带可将地球表层碳输送至深部地幔,同时也记录着俯冲板片来源碳质流体的迁移沉淀机制,对地球深部碳循环具有重大影响。近年来,俯冲带脱碳机制的研究表明流体溶解脱碳作用是冷的大洋俯冲板片释放COH流体的重要方式,而上覆板块(尤其地幔楔)则被认为是缓冲这些COH流体的重要场所,甚至是俯冲带CO_2的唯一"归宿"。事实上,俯冲带岩石本身的固碳能力却受到了忽视,而对俯冲带岩石捕获和固存CO_2(carbon capture and storage,CCS)能力的评估对全球碳通量的估算尤为重要。本文以中国西南天山高压-超高压变质带中碳酸盐化云母片岩为例,探讨俯冲带岩石的碳酸盐化对深部碳循环的影响。西南天山长阿吾子一带的碳酸盐化云母片岩记录了俯冲板片起源的碳质流体对俯冲带云母片岩的交代作用,地球化学特征表明蛇纹岩释放的富水流体溶解俯冲洋壳中的碳酸盐可能是产生COH流体的重要机制。基于碳质流体对多硅白云母(Si(a.p.f.u.)=3.58～3.73)的交代及相对高压的碳酸盐矿物(主要为白云石和菱镁矿)与金红石的共生,结合区域上碳酸盐化云母片岩与高压碳酸盐化蛇纹岩(HP-ophidolomite)的伴生,我们认为云母片岩的碳酸盐化作用可能发生在俯冲板片峰期稍后的高压折返阶段。俯冲带云母片岩的固碳作用表明除了上覆板块,俯冲带岩石本身对于碳质流体也具有很好的吸收能力。初步估算表明俯冲带云母片岩的碳酸盐化每年可固存至少2.46～6.68Mt/yr,约占俯冲板片每年进碳量的4%～17%。     

新特提斯洋俯冲起始的地质记录:土耳其南部蛇绿岩和变质底板

在现行板块构造理论的框架下,板块的初始俯冲是岩浆活动和构造运动发生转变的重要过程,亦是理解板块运动的关键节点。在俯冲起始过程中,主要存在四个方面的地质记录,分别为一系列地球化学成分多样的岩浆活动、SSZ型蛇绿岩、变质底板和玻安岩及其对应的铬铁矿床。特提斯造山带作为公认的研究板块构造理论尤其是初始俯冲的关键场所,一直备受地学界的重视。而土耳其南部构造带作为特提斯造山带的重要组成部分,亦是确定亚欧板块和阿拉伯板块之间缝合线存在的重要标志。该南部构造带是研究新特提斯洋俯冲起始的理想场所,上述关于俯冲初始的四个地质记录均保存良好,且有如下方面的重要特点:1)不同地区的镁铁质岩石甚至同一地区的镁铁质岩石具有不同的地球化学特征,从似洋中脊玄武岩,到过渡型岩石类型和玻安质岩石均有发育; 2)大部分蛇绿岩具有完整的序列,各单元及变质底板岩石中普遍发育侵入的基性岩脉,产状多变,是多期岩浆事件的产物; 3)蛇绿岩下部通常发育一套角闪岩相变质底板,且其年龄与蛇绿岩的形成年龄基本一致; 4)蛇绿岩中普遍发育铬铁矿床,以高Cr型为主,部分蛇绿岩中还赋存高Al-高Cr的过渡型铬铁矿,均被认为是幔源岩浆与地幔橄榄岩反应的产物。因而,这些地质体完整记录了新特提斯洋形成-俯冲-消减的演化过程。     

Geochemistry of Khor Um-Safi ophiolitic serpentinites,central Eastern desert,Egypt: Implications for neoproterozoic arc-basin system in the Arabian-Nubian shield

Serpentinites in the Eastern Desert of Egypt are the most distinctive lithological unit in the Arabian–Nubian Shield (ANS) ophiolite sequence which associated with major suture zones. Khor Um-Safi (KUS) serpentinites represent dismembered fragments of ophiolitic rocks located in the central Eastern Desert (CED) of Egypt.KUS serpentinites exhibit affinity to the typical metamorphic peridotites with harzburgitic protolith compositions. Their opaque mineral assemblage (pentlandite, heazlewoodite and magnetite) is similar to that observed in oceanic serpentinites and implies serpentinization under highly reducing conditions. They have refractory major element compositions with Al₂O₃ contents comparable to oceanic and active margin peridotites as well as Pan-African serpentinites. The Cr and TiO₂ contents reflect evolution within a supra-subduction zone (SSZ) environment. This implication is confirmed by the Al₂O₃/SiO₂ and MgO/SiO₂ ratios which akin to ANS ophiolitic peridotites in fore-arc setting. Their enrichment in compatible trace elements (Cr, Ni and Co) reveals a depleted mantle peridotite protolith.Modelling trace elements indicates that they represent the mantle residues from 15 to 20 % melting of spinel peridotite at oxygen fugacity conditions of the QFM + 1 buffer. This range of melt extraction is consistent with the typical range of SSZ peridotite. Oxygen fugacity estimation suggests evolution under more oxidizing regime similar to modern fore-arc basin system. Moreover, this implication indicates that the KUS mantle represents arc lithosphere interacted with arc melt.     

Peralkaline rhyolites from the ordovician tweeddale lavas,peeblesshire, scotland

The riebeckite-bearing rhyolite of Winkston Hill, Peebles, is shown to be peralkaline and may be named a pantellerite. Trace element comparison with other more altered members of the Tweeddale lavas from Wrae Hill suggests that the whole suite is peralkaline. It is thought most unlikely that the suite was developed in association with an Upper Ordovician subduction zone, and it was perhaps erupted on an oceanic island.     

Historical tsunami in the Makran Subduction Zone off the southern coasts of Iran and Pakistan and results of numerical modeling

Tsunami hazard in the Makran Subduction Zone (MSZ), off the southern coasts of Iran and Pakistan, was studied by numerical modeling of historical tsunami in this region. Although the MSZ triggered the second deadliest tsunami in the Indian Ocean, among those known, the tsunami hazard in this region has yet to be analyzed in detail. This paper reports the results of a risk analysis using five scenario events based on the historic records, and identifies a seismic gap area in western Makran off the southern coast of Iran. This is a possible site for a future large earthquake and tsunami. In addition, we performed numerical modeling to explain some ambiguities in the historical reports. Based on the modeling results, we conclude that either the extreme run-up of 12–15 m assigned for the 1945 Makran tsunami in the historical record was produced by a submarine landslide triggered by the parent earthquake, or that these reports are exaggerated. The other possibility could be the generation of the huge run-up heights by large displacements on splay faults. The results of run-up modeling reveal that a large earthquake and tsunami in the MSZ is capable of producing considerable run-up heights in the far field. Therefore, it is possible that the MSZ was the source of the tsunami encountered by a Portuguese fleet in Dabhul in 1524.     

对橄榄石相变形核率的估算

地幔主要矿物橄榄石［(Mg089Fe011)2SiO4］的相变与深源地震的解释以及俯冲带和周围地幔的相互作用相关. 其中,形核率和长大率是刻画其相变动力学的两个重要参数. 因为实验技术的原因,目前人们还没有基于实验数据给出橄榄石的形核率. 本文首先通过对挤碰物理图像的分析,对边界形核情形的相变动力学理论中表征挤碰程度的无量纲参数进行了修正. 在此基础上,根据已有的实验资料,首次对橄榄石相变的形核率进行了估计. 通过对形核率数据的拟合,可以得到形核率参数K0和γ1/3. 得到两个形核率参数的变化范围分别为K0=55×1021～87×1027s-1·m-2·K-1,γ1/3=0～020 J·m-2,最佳拟合值为：K0=69×1024s-1·m-2·K-1,γ1/3=016 J·m-2.     

Subduction and back-arc activity at the Hikurangi convergent Margin,New Zealand

The Hikurangi Margin is a region of oblique subduction with northwest-dipping intermediate depth seismicity extending southwest from the Kermadec system to about 42°S. The current episode of subduction is at least 16–20 Ma old. The plate convergence rate varies along the margin from about 60 mm/a at the south end of the Kermadec Trench to about 45 mm/a at 42°S. The age of the Pacific lithosphere adjacent to the Hikurangi Trench is not known.The margin divides at about latitude 39°S into two quite dissimilar parts. The northern part has experienced andesitic volcanism for about 18 Ma, and back-arc extension in the last 4 Ma that has produced a back-arc basin onshore with high heaflow, thin crust and low upper-mantle seismic velocities. The extension appears to have arisen from a seawards migration of the Hikurangi Trench north of 39°S. Here the plate interface is thought to be currently uncoupled, as geodetic data indicate extension of the fore-arc basin, and historic earthquakes have not exceededM _s=7.South of 39°S there is no volcanism and a back-arc basin has been produced by downward flexure of the lithosphere due to strong coupling with the subducting plate. Heatflow in the basin is normal. Evidence for strong coupling comes from historic earthquakes of up to aboutM _s=8 and high rates of uplift on the southeast coast of the North Island.The reason for this division of the margin is not known but may be related to an inferred increase, from northeast to southwest, in the buoyancy of the Pacific lithosphere.     

俯冲带的后撤与弧后扩张

西太平洋地壳年龄较老,因而岩石层较冷和比重较大,俯冲带的角度也较大,活动和成熟的弧后盆地则较多;条件与之相反的东太平洋弧后盆地则较少.本文探讨这种相关关系的力学成因,计算了俯冲板块诱生的弧后上涌地幔流动.计算表明,俯冲角度大及存在后撤俯冲时,有利于在弧后地区产生明显的上涌地幔流,这种深部热物质的上涌会导致弧后扩张.反之,年龄较轻的海洋地块较热和较轻,俯冲角度一般也较小,不易诱生上涌地幔物质流动和弧后扩张.大陆地壳密度小于地幔物质,大陆碰撞区就更不具备弧后扩张的条件.     

环太平洋地震带与柯里奥利力

柯里奥利力是地球自转的一种惯性力，它使垂直下降的物体向东偏转，垂直上升的物体向西偏转，是形成环太平洋地震带中东西两岸构造应力差别的根本原因。     

古太平洋岩石圈消减与中国东南部晚中生代火成岩成因——岩石圈消减与玄武岩底侵相结合模式的补充证据

本文根据中国东南部 140个晚中生代火成岩 Rb- Sr等时线年龄匹配的 Isr值 ,勾画了 Isr等值线图。该图与 TDM等值线图有好的对应 ,都在浙闽沿海地区、南岭东段和武夷山北段出现低值区或低值带 ,反映中国东南地壳在晚中生代时期 ,有广泛的地幔物质的加入 ,它们以底侵的形式底垫在中 -下地壳。沿海地区 Isr、TDM的低值区、带受地壳厚度的控制 ,内陆的低值区、带可能与局部应力场导致的拉张减薄有关。浙闽沿海晚中生代火成岩岩石地球化学显示大离子亲石元素 Rb、Sr、Ba、Th和 Ce富集 ,高场强元素 Nb、Ta、Zr、Hf和重稀土 Y、Yb亏损 ,具有明显的消减带岩浆作用的特征。西太平洋地震层析成像显示 ,西太平洋板块俯冲是连续的。在大约 2 0 0 0～ 12 0 0 km深度 ,地幔中正在下沉的古俯冲洋壳明显偏西 ,可能反映那时为低角度俯冲。中国东南部广泛发育的NE- NNE褶皱和断裂构造 ,与古太平洋板块向欧亚大陆之下的俯冲作用有关。大规模晚中生代岩浆活动之前的陆相沉积 ( T3- J2 )是造山磨拉石建造。上述地质证据均支持消减作用和底侵作用相结合的模式