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11.
This paper addresses the problem of quantifying the joint uncertainty in the grades of elements of interest (iron, silica, manganese, phosphorus and alumina), loss on ignition, granulometry and rock types in an iron ore deposit. Sampling information is available from a set of exploration drill holes. The methodology considers the construction of multiple rock type outcomes by plurigaussian simulation, then outcomes of the quantitative variables (grades, loss on ignition and granulometry) are constructed by multigaussian joint simulation, accounting for geological domains specific to each quantitative variable as well as for a stoichiometric closure formula linking these variables. The outcomes are validated by checking the reproduction of the data distributions and of the data values at the drill hole locations, and their ability to measure the uncertainty at unsampled locations is assessed by leave-one-out cross validation.Both the plurigaussian and multigaussian models offer much flexibility to the practitioner to face up to the complexity of the variables being modeled, in particular: (1) the contact relationships between rock types, (2) the geological controls exerted by the rock types over the quantitative variables, and (3) the cross-correlations and stoichiometric closure linking the quantitative variables. In addition to this flexibility, the use of efficient simulation algorithms turns out to be essential for a successful application, due to the high number of variables, data and locations targeted for simulation. 相似文献
12.
Kusuma G. Rao V. N. Lykossov A. Prabhu S. Sridhar E. Tonkacheyev 《Journal of Earth System Science》1996,105(3):227-260
An attempt has been made here to study the sensitivity of the mean and the turbulence structure of the monsoon trough boundary
layer to the choice of the constants in the dissipation equation for two stations Delhi and Calcutta, using one-dimensional
atmospheric boundary layer model withe-ε turbulence closure. An analytical discussion of the problems associated with the constants of the dissipation equation is
presented. It is shown here that the choice of the constants in the dissipation equation is quite crucial and the turbulence
structure is very sensitive to these constants. The modification of the dissipation equation adopted by earlier studies, that
is, approximating the Tke generation (due to shear and buoyancy production) in theε-equation by max (shear production, shear + buoyancy production), can be avoided by a suitable choice of the constants suggested
here. The observed turbulence structure is better simulated with these constants. The turbulence structure simulation with
the constants recommended by Aupoixet al (1989) (which are interactive in time) for the monsoon region is shown to be qualitatively similar to the simulation obtained
with the constants suggested here, thus implying that no universal constants exist to regulate dissipation rate.
Simulations of the mean structure show little sensitivity to the type of the closure parameterization betweene-l ande-ε closures. However the turbulence structure simulation withe-ε. closure is far better compared to thee-l model simulations. The model simulations of temperature profiles compare quite well with the observations whenever the boundary
layer is well mixed (neutral) or unstable. However the models are not able to simulate the nocturnal boundary layer (stable)
temperature profiles. Moisture profiles are simulated reasonably better. With one-dimensional models, capturing observed wind
variations is not up to the mark. 相似文献
13.
14.
闽南近海常见鲨鳐类肝油的四种理化常数和角鲨烯含量 总被引:8,自引:0,他引:8
本文分析测定了闽南近海常见鲨鳐类肝油的理化常数和角鲨烯含量。尖头斜齿鲨肝油的碘值特别高,说明其中脂肪酸的不饱和程度很高;非皂化物含量很低,约占肝油重的38×10-3(m/m);角鲨烯含量极微,在肝油中仅占84×10-5(m/m)。闽南近海常见鲨鳐类肝油的角鲨烯含量均很低,变化在(31~116)×10-5(m/m)之间。在相同的气相色谱条件下,小孔沙条鲨和狭纹虎鲨肝油中没有检测到角鲨烯。 相似文献
15.
Maria Dina Vivarelli 《Celestial Mechanics and Dynamical Astronomy》1994,60(3):291-305
This paper is an attempt to bring unity in the study of the classical Kepler problem by combining, through simple vectorial and quaternionic techniques, its two peculiar aspects: the determination of the constants of the motion and the regularization at the origin.Research supported by the Consiglio Nazionale delle Ricerche of Italy (C.N.R.-G.N.F.M.). 相似文献
16.
This paper employs the highly accurate valence internally contracted multireference configuration interaction method to investigate the potential energy curves (PECs) for the ground state (X1Σ+) and two low-lying excited states (A1Π and D1Δ of phosphorus nitride (PN) radical with the correlation-consistent basis set, aug-cc-pV6Z, in the valence range. Relativistic effects are considered in these calculations. The spectroscopic constants of the X1Σ+ and A1Π states are calculated based on the PECs, and the results are in good accord with the available experimental data. The first 30 vibrational states for the A1Π state and the first 40 vibrational states for the A1Π state are determined when J=0. For each vibrational state, molecular constants G(υ), B(υ) and D(υ) are also attained. 相似文献
17.
伊利石结晶度Kübler,Weaver和Weber指数关系式常数的确定与应用 总被引:1,自引:0,他引:1
根据衍射峰具有的不同分布特点推导出了14个伊利石结晶度Kübler指数,Weaver指数和Weber指数关系式中常数项C1-C14的数值,提出了PearsonⅦ分布中形态参数μ与C5,C6,C11,C12的4个定量方程。由此,14个伊利石结晶度指数关系式可直接用于实际计算。根据阿尔卑斯复理石伊利石形态特征Sc=0.731,由这些关系式进行近变质带上下界线的转换得出与Kübler指数0.42~0.25。△2θ界线对应的Weaver指数和Weber指数的界线值分别为5.8~17.6和300~179。讨论了在自然干燥状态下直接进行伊蒙混层鉴定的基本原理。 相似文献
18.
Water-soluble organics in atmospheric particles: A critical review of the literature and application of thermodynamics to identify candidate compounds 总被引:15,自引:0,他引:15
Although organic compounds typically constitute a substantial fraction of the fine particulate matter (PM) in the atmosphere, their molecular composition remains poorly characterized. This is largely because atmospheric particles contain a myriad of diverse organic compounds, not all of which extract in a single solvent or elute through a gas chromatograph; therefore, a substantial portion typically remains unanalyzed. Most often the chemical analysis is performed on a fraction that extracts in organic solvents such as benzene, ether or hexane; consequently, information on the molecular composition of the water-soluble fraction is particularly sparse and incomplete.This paper investigates theoretically the characteristics of the water-soluble fraction by splicing together various strands of information from the literature. We identify specific compounds that are likely to contribute to the water-soluble fraction by juxtaposing observations regarding the extraction characteristics and the molecular composition of atmospheric particulate organics with compound-specific solubility and condensibility for a wide variety of organics. The results show that water-soluble organics, which constitute a substantial fraction of the total organic mass, include C2 to C7 multifunctional compounds (e.g., diacids, polyols, amino acids). The importance of diacids is already recognized; our results provide an impetus for new experiments to establish the atmospheric concentrations and sources of polyols, amino acids and other oxygenated multifunctional compounds. 相似文献
19.
在自然界广泛分布着烃-烃不混溶体系中捕获的流体包裹体,由于这些包裹体具有复杂的组成和相态,因此不混溶包裹体组合的判别和热力学参数的计算常常难以进行。根据烃-烃不混溶体系中两个端员组分流体包裹体室温下的相态特征和在温度-压力平面图上等容线交点显示的位置,划分成三种类型流体包裹体组合,本文介绍了三种类型流体包裹体组合特征,叙述了不混溶烃-烃包裹体组合的测定和判别方法,并且阐述均一化包裹体相态方程和气-液平衡常数原理和方法。与此同时列攀了自然界简单的三种类型不混溶烃-烃包裹体组合的测定、判别和计算的几个实例,利用相态方程和气.液平衡常数,不但精确地计算出包裹体均一压力,并且精确地计算出流体密度和体积等热力学参数。最后,利用均一成气相和液相的两种包裹体在p—T平面图上等容线交点同样计算出流体包裹体组合的捕获温度和压力。 相似文献
20.