大陆俯冲带流体活动:超高压变质岩矿物水含量和稳定同位素制约

对超高压变质岩中含水矿物和名义上无水矿物的地球化学研究,极大地深化了我们对大陆碰撞带地壳俯冲和折返过程中流体体制的认识。就流体体制和化学地球动力学来说,有关研究在大别-苏鲁造山带进行的最为详细,因此已经成为研究大陆俯冲带变质的典型地区。本文以大别-苏鲁造山带为对象,从矿物水含量的角度,结合稳定同位素论述了大陆俯冲带流体活动。超高压变质岩中名义上无水矿物含有大量的水,以结构羟基和分子水形式存在。名义上无水矿物中结构羟基和分子水出溶与含水矿物分解共同构成了折返过程中退变质流体的主要来源。名义上无水矿物所释放的水以富集轻的氢氧同位素为特征,而含水矿物分解则提供了富集D的流体来源。折返过程中,名义上无水矿物降压脱水存在亏损D的分子水的优先丢失和不同形式水之间的相互转化。不同岩性的水含量差异导致了它们在折返过程中不同的流体活动行为。大陆板块俯冲和折返过程中,在不同矿物、不同岩性以及板片不同部位之间存在水的再分配;板片的一部分作为富水流体的源,而另一部分可能作为汇。     

The Impact of Aqueous Medium on Gas Yields and Kinetic Behaviors of Hydrogen Isotope Fractionation during Organic Matter Thermal Degradation

In order to recognize the impact of aqueous medium on gas yields and the kinetic behaviors of hydrogen isotope fractionation during organic matter thermal degradation, the gold tube apparatus was used to conduct thermal simulation experiments by mixing the nC18 with the water of different properties and proportions. The yields of natural gas components, the relation among hydrogen isotope composition of each component and the experimental temperatures vs. heating rates have been obtained, and the results indicate that under the higher temperature conditions, the hydrous experiment has obvious impact on gas yields, such as when more water is added, higher amounts of hydrocarbon gas and H2 are yielded, and the existence of water obviously prolongs the temperature interval with the existence of heavy hydrocarbon gas. It also shows that the hydrogen isotope of hydrocarbon gas generated by the hydrous experiment is obviously lighter than that generated by the anhydrous experiment, and with the increasing amount of added water, the δD value of hydrocarbon gas gradually decreases. Compared with gas yields, the variation of δD value is more sensitive to aqueous medium in the thermal simulation experiment. However, compared with the amount of the added water, the aqueous medium property has smaller impact on the gas yields, which still shows the inherit effect on hydrogen isotope composition of aqueous medium. Through the model simulation and the isotope fractionation behavior analysis, it is validated that the hydrogen isotope fractionation process can be well described by the chemical kinetic model. The difference of reaction fraction of normal methane and D-containing methane is large, corresponding to the same activation energy. The content of normal methane is obviously higher in the part with lower activation energy, while the content of D-containing methane is higher in the part with higher activation energy. Therefore, it will result in larger hydrogen isotope fractionation amplitude, and the δD values will be more sensitive to the variation of maturity. Meanwhile, the average activation energy of methane generation from nC18 in the hydrous experiment is higher than that in the anhydrous experiment, and the greater amount of added water, the larger the average activation energy of methane generation reaction. This has laid foundation for its exploratory application in the study of gas reservoir forming history and the gas-source correlation, which indicates the research and application prospects in this orientation.     

江南隆起带中段新元古代花岗岩锆石U-Pb年代学和Hf同位素组成研究

对江南隆起带中段湘东西园坑岩体和赣西九岭岩体的LA-ICPMS锆石U-Pb年代学测定和LA-MC-ICPMS锆石Hf同位素原位分析测试表明:西园坑岩体形成于(804±3)Ma,赣西九岭岩体的年龄为(813±4)Ma和(823±2)Ma,均为新元古代花岗岩.上述三个样品的εHf(t)的加权平均值分别为0.68±0.71,...     

有机溴化物的溴同位素测试技术及其生物地球化学指示意义

有机溴化物已成为继有机氯化物之后又一值得关注的全球性新兴持久性有机污染物。稳定Br同位素测试技术的快速发展,为有机溴化物生物地球化学循环研究提供了更为有效的技术支撑。在综述稳定Br同位素研究进展的基础上认为：①基于GC-MC-ICPMS技术基础上的有机单体Br同位素（CSIA-OBr）是Br同位素研究的主要趋势,难点是...     

翠宏山铁多金属矿床成矿流体包裹体及硫同位素特征

对翠宏山铁多金属矿床成矿早期阶段钨钼矿体中的石英、成矿晚期阶段铅、锌、铜矿体中的萤石流体包裹体特征及均一温度、盐度的研究表明,从早期钨钼成矿阶段至晚期铅、锌、铜成矿阶段,侵入体内接触带至外接触带,经历了一个温度剧降和盐度显著增加的过程。钨钼成矿阶段成矿流体主要为岩浆热液流体,成矿过程为单一的成矿流体冷却过程; 在晚期铅、锌、铜成矿阶段,来自岩浆中的温度较高的热流体与围岩地层中的大气降水等低温、高盐度流体混合,使成矿流体温度剧降和盐度增高,导致铅、锌、铜等成矿物质的沉淀。辉钼矿和方铅矿的δ34S ( × 10-3 ) 测试结果表明,侵入体内接触带钨钼矿体的成矿物质主要来自岩浆热液; 围岩地层中铅、锌、铜矿体的成矿物质,除岩浆热液来源外,部分可能来自雨水对地层中硫酸盐岩中硫及其他成矿物质的淋滤。     

鄂尔多斯盆地苏里格地区奥陶系马家沟组马五段白云岩的地球化学特征

苏里格地区奥陶系马家沟组马五段白云岩是重要的油气储集层.多年来,马家沟组白云岩的成因一直是地质研究者讨论的热点话题.对苏里格地区马家沟组马五段白云岩的微量元素及C、O、Sr同位素地球化学资料的分析表明,微量元素表现为高铁、低锰、低锶、低钠;白云石、白云质角砾和孔洞充填白云岩的δ13C和δ18O值较为近似,且白云岩的δ1...     

滨海地区地下水泄流研究进展

20世纪90年代以来出现的对滨海地下水的研究方式取得了有意义的结果.其中W.S.Moore通过对226Ra富集揭示了地下水对海岸水体大量补给的研究以及Jacob、Sun等关于潮夕动力地下水流法的研究对解决环境地质问题具有一定的意义.     

鞍本地区早前寒武纪地质体铅同位素组成及铀源条件定量计算方法研究

本文对比了鞍本地区前寒武纪铅-锌-银矿区和铀矿区的硫化物矿石和花岗岩长石Pb同位素组成,分别用矿石铅二阶段普通铅法、铅构造模式图解和全岩铅同位素组成三阶段拟合法计算了年龄和全岩原始铀含量。结果表明,矿石铅和长石铅模式年龄约为2000 Ma,在铅构造模式图上投影于2000~1600 Ma间,花岗岩和辽河群全岩拟合年龄为2000~1800 Ma;铅同位素组成显示铅-锌-银来自早元古代辽河群地层,连山关地区明显为放射性成因Pb同位素组成,源于富铀花岗岩。连山关矿石铅年龄和全岩三阶段年龄与该区铀矿床沥青铀矿的年龄基本一致;花岗岩原始铀的得失计算表明,该地区不同地质体均经历了约2000~1800 Ma花岗岩重熔改造,花岗质岩石发生了铀的丢失,是连山关地区铀矿的主要来源。     

我国火山地热流体地球化学研究新进展

本文综述了最近几年来中国研究者在地热流体地球化学研究领域取得的主要进展。在国际上关于地球内部流体及其作用研究取得重要进展的大背景下,我国学者在地热流体地球化学研究上也取得了一些重要成果,主要表现在火山地热区和非火山地热区两大方面,在火山学、地热学、环境学、大地构造学、地震学等五个学科领域都取得了一些重要进展。     

He–Ar Isotope Composition of Pyrite and Wolframite in the Tieshanlong Tungsten Deposit,Jiangxi, China: Implications for Fluid Evolution

The Tieshanlong tungsten‐polymetallic deposit is a large wolframite deposit of quartz vein type located in southern Jiangxi, South China. It is genetically related to a high‐K S‐type granite. Seven pyrite and two wolframite samples, selected for He and Ar isotope analyses, yielded ³He/⁴He values of 0.04–0.98 Ra, ⁴⁰Ar/³⁶Ar ratios of 293.5–368.0, and ³⁸Ar/³⁶Ar ratios of 0.176–0.193. These data indicate that the ore‐forming fluids associated with the deposit did not result from a simple mixing of the crustal‐ and mantle‐derived end‐member fluids, but that primeval meteoric fluids were also involved in the generation of the associated granitic magma by partial melting of crustal metasedimentary rocks. Further investigations show that only minimal He from the mantle was added during generation of the associated granitic magma. It is postulated that boiling and second mixing with “new” meteoric fluids took place during migration of magmatic‐hydrothermal fluids into wall‐rock fractures, resulting in a drastic decrease of their metal transport capacity, which triggered the tungsten‐polymetallic mineralization.