胶州湾沉积物重金属形态不同浸取方法的比较与污染讯息指示作用初探

海洋沉积物中重金属的活性形态对于指示沉积物污染状况具有重要作用;为探寻简洁且能够有效提取重金属活性形态的浸提方法;实验研究了0.1 mol/L和1 mol/L盐酸的单级提取和欧共体标准局（European Community Bureau of Reference）提出的BCR分级提取法对胶州湾表层沉积物中重金属（Cr、Cu、Ni、Pb、Zn）和Al、Fe、Mn的浸取效果。结果显示;3种提取方法提取的金属含量呈显著正相关关系;两种浓度的稀盐酸对BCR方法中的酸可提取态和可还原态金属均具有较好浸提效果;但对可氧化态金属浸提能力相对较弱。不同提取方法的人为信号指数（ASI）计算结果表明;BCR浸取法提取结果的金属ASI值最大;表明其对沉积物中金属活性形态提取效率较高;1 mol/L HCl提取结果的金属ASI值最低;可能是较高浓度强酸使沉积物较大颗粒内层中“惰性”金属被浸取出来;“增加”了金属活性组分的污染讯息信号;对沉积物中Cu、Pb和Zn而言;0.1 mol/L HCl提取结果的ASI值与BCR方法接近。经过Al归一化后;0.1 mol/L HCl浸提的重金属含量的空间分布与胶州湾的实际污染状况相吻合;表明0.1 mol/L的HCl在一定程度上能够代替复杂的BCR浸取法;此方法可简化重金属活性形态的提取步骤;适合大范围沉积物重金属污染评价。     

Geochemical characteristics of the Paleogene shales in the Dongying depression,eastern China

Fluctuations in lacustrine sedimentary environments significantly affect distributions of organic matter (OM), uranium, and other elements in shales. In this study a high-resolution geochemical record of fluctuations in the paleo-depositional environment of a terrestrial lake basin is provided on the basis of extensive samples collected from the Member 3 of the Paleogene Shahejie Formation (Es₃) of the Niu-38 well in the Dongying Depression, Eastern China. These samples were tested for total organic carbon (TOC), element concentrations, and biomarkers to study the evolution and fluctuation in the depositional environments of an ancient lake basin and associated geochemical response. The evolution and fluctuation of the sedimentary environment from a deep lake to a semi-deep lake and then to a shallow lake delta were indicated by geochemical response. During this evolution, the values of TOC, S₁, S₂, Sr, and Ts/(Ts + Tm) remarkably decreased, whereas those of Co, Ni, Rb, Na, Fe/Mn, Fe/(Ca + Mg), and C₂₉ mortane/C₂₉ hopane significantly increased. The deep lake basin shows depositional fluctuations, as indicated by rock lithofacies and their geochemical parameters. A close interrelationship was observed among U concentration, TOC content, and inorganic element content. Uranium concentrations are positively correlated with TOC contents, Ca and Sr concentrations, and Sr/Ba and Ca/Mg ratios but negatively with K, Na, Ba, and Rb contents and Fe/(Ca + Mg) and Fe/Mn ratios. The observed increase in U concentration in the lower Es₃ section is closely related to surface adsorption by clay minerals and OM, together with some replacements of Ca and Sr by U in the shales.     

东山乌礁湾海滩表层沉积物粒度时空变化分析

为了进一步了解海岛岬湾海岸表层沉积物粒度的时空分布特征和形成机制,作者以福建东山岛乌礁湾为典型研究区,通过秋、春、夏3个不同季节海滩表层沉积物的采集和点位测量,综合应用激光法和筛析法进行粒度测定。结果表明,东山乌礁湾海滩表层沉积物以0.16～0.50 mm之间的中、细砂为主,并含有少量的粗砂和细砾,这与区域砂质沉积背景有关;湾内从南到北剖面沉积物粒径由粗砂到细砂逐渐变细,主要受剖面地形、局地物源、季节性风浪作用和近岸往复水动力的影响。时间变化上,各取样站位表现出沉积物粒径粗、细不同程度的多种变化趋势,以秋季为参考,整体上表现为由南到北粒级的变小、增大和稳定,这与东北、南南西季风影响下的浪、潮作用以及沿岸流系格局变化下的水动力环境有关。     

区域地球化学特征及其主控因素——对内蒙古珠斯楞地区找矿的意义

在1∶5万水系沉积物测量的基础上,对内蒙古额济纳旗珠斯愣地区的地球化学特征及其主控因素进行初步分析,并对元素分布特征、元素相关性分析、单元素异常与构造之间关系、综合异常与构造之间关系进行了探讨。研究发现,Cu、Au、Sb为区内具一定潜力的找矿元素,与呼伦西白-珠斯楞海尔罕反"S"形构造带南端内、外旋面的转换的珠斯楞海尔罕一带形成一个与断裂构造吻合度较高的、半环性的成矿成晕中心。因而推断,区内具有形成与中酸性侵入岩有关的热液铜多金属矿的可能,其中珠斯楞海尔罕铜金矿和道布青乌苏南北金锑矿2个找矿靶区严格受呼伦西白-珠斯楞海尔罕反"S"形构造的控制。     

Development and Extension of An Aggregated Scale Model: Part 1 – Background to ASMITA

Whilst much attention has been given to models that describe wave, tide and sediment transport processes in sufficient detail to determine the local changes in bed level over a relatively detailed representation of the bathymetry, far less attention has been given to models that consider the problem at a much larger scale (e.g. that of geomorphological elements such as a tidal flat and tidal channel). Such aggregated or lumped models tend not to represent the processes in detail but rather capture the behaviour at the scale of interest. One such model developed using the concept of an equilibrium concentration is the Aggregated Scale Morphological Interaction between Tidal basin and Adjacent coast (ASMITA). In this paper we provide some new insights into the concepts of equilibrium, and horizontal and vertical exchange that are key components of this modelling approach. In a companion paper, we summarise a range of developments that have been undertaken to extend the original model concept, to illustrate the flexibility and power of the conceptual framework. However, adding detail progressively moves the model in the direction of the more detailed process-based models and we give some consideration to the boundary between the two.     

The Sediment Source and Transport Trends around the Abandoned Yellow River Delta,China

Sediment source and transport trends are influenced by various hydrodynamic factors, and thus play important roles in sedimentary evolution and coastal stability. To examine sediment transport trends around the abandoned Yellow River delta promontory and its erosion mechanism, we employ empirical orthogonal function (EOF) analysis to study sedimentary characteristics and transport trends of the abandoned Yellow River delta in northern Jiangsu Province, China. The results showed that: (1) the main sediment source in the abandoned Yellow River delta is the submarine coastal slope and both sides of the abandoned Yellow River Delta; (2) the main hydrodynamics controlling sediment transport is the current that runs along the shore, coupled with waves, especially southward currents; (3) the sediment of the study area was redistributed under hydrodynamics; coarse sediments were eroded and broadly transported to the south. Therefore, it is concluded that the sediment sources and transport have important influence on coastal evolution: the sediment source area shows mass loss of deposits and erosion; deposits in the submarine coastal slope provide the source and were continuously eroded to provide materials to other places as a sediment source.     

A Preliminary Study on the Soft–Sediment Deformation Structures in the Late Quaternary Lacustrine Sediments at Tashkorgan, Northeastern Pamir, China

This study identified soft–sediment deformation structures(SSDS) of seismic origin from lacustrine sediments in the late Quaternary paleo–dammed lake at Tashkorgan, northeastern Pamir. The observed deformation structures include sand dykes, liquefied diapir and convolute structures, gravity induced SSDS, and thixotropic pillar and tabular structures. We conducted a preliminary study on the morphology, formation and trigger mechanisms of pillar and tabular structures formed by liquefaction of underlying coarse sand and thixotropy of the upper silty clay. The regional tectonic setting and distribution of lacustrine strata indicate that the most probable trigger for the SSDS in lacustrine sediments was seismic activity, with an approximate earthquake magnitude of M6.0; the potential seismogenic fault is the southern part of the Kongur normal fault extensional system. AMS 14 C dating results indicate that the SSDS were formed by seismic events occurring between 26050±100 yr BP and 22710±80 yr BP, implying intense fault activity in this region during the late Pleistocene. This study provides new evidence for understanding tectonic activity and regional geodynamics in western China.     

小秦岭太峪水系沉积物重金属污染生态危害评价

以金矿开发影响的黄河二级支流太峪水系沉积物为研究对象,沿河采集16个表层沉积物样品,分层采集垂向剖面10件水库沉积物样品,测定了样品中重金属元素Hg、Pb、Cd、Cr、As、Cu和Zn的含量,采用Hakanson潜在生态指数法和Tomlinson污染负荷指数法评价重金属元素污染程度和潜在生态风险。结果表明,矿业活动是太峪水系沉积物重金属元素污染的主要因素;变异系数、富集系数和最高污染系数均反映Hg、Pb、Cd是太峪水系沉积物的特征污染重金属元素,Cr和As的质量分数接近地区背景值;太峪水系表层沉积物受到重金属元素的极强污染,山区段污染较山外更严重;整个流域的Hg、Pb、Cd具有很强的潜在生态危害,Cr、As、Zn的潜在生态危害轻微;太峪水系沉积物垂向各层沉积物都受到重金属元素的极强污染,生态问题以Hg、Pb、Cd的潜在生态危害为主,其污染和生态危害程度都高于流向上的沉积物。潜在生态危害指数评价突出了不同元素的毒性和危害程度,而污染负荷指数法侧重于样本空间上的污染程度,二者互补使用有利于实际问题的全面评价。     

Assessment of soil erosion in a tropical mountain river basin of the southern Western Ghats,India using RUSLE and GIS

Revised Universal Soil Loss Equation(RUSLE) model coupled with transport limited sediment delivery(TLSD) function was used to predict the longtime average annual soil loss, and to identify the critical erosion-/deposition-prone areas in a tropical mountain river basin, viz., Muthirapuzha River Basin(MRB; area=271.75 km~2), in the southern Western Ghats, India. Mean gross soil erosion in MRB is 14.36 t ha~(-1) yr~(-1), whereas mean net soil erosion(i.e., gross erosion-deposition) is only 3.60 t ha~(-1) yr~(-1)(i.e., roughly 25% of the gross erosion). Majority of the basin area(~86%) experiences only slight erosion(5 t ha~(-1) yr~(-1)), and nearly 3% of the area functions as depositional environment for the eroded sediments(e.g., the terraces of stream reaches, the gentle plains as well as the foot slopes of the plateau scarps and the terrain with concordant summits). Although mean gross soil erosion rates in the natural vegetation belts are relatively higher, compared to agriculture, settlement/built-up areas and tea plantation, the sediment transport efficiency in agricultural areas and tea plantation is significantly high,reflecting the role of human activities on accelerated soil erosion. In MRB, on a mean basis, 0.42 t of soil organic carbon(SOC) content is being eroded per hectare annually, and SOC loss from the 4th order subbasins shows considerable differences, mainly due to the spatial variability in the gross soil erosion rates among the sub-basins. The quantitative results, on soil erosion and deposition, modelled using RUSLE and TLSD, are expected to be beneficial while formulating comprehensive land management strategies for reducing the extent of soil degradation in tropical mountain river basins.     

A New Reference Material for Tritium Organic Molecules in Sediment: Results of an International Intercomparison Exercise

Solid matrix ³H reference materials are challenging to prepare given the volatile nature of ³H and are often unrepresentative of the range of ³H forms that may be encountered during routine analysis. As a result, few ³H reference materials are currently available, undermining verification of analytical techniques for environmental ³H measurement. To address this, an International Working Group on Organically‐Bound Tritium Analysis determined to produce a tritium natural matrix reference material (NMRM). The reference material comprises marine sediment blended with sewage sludge contaminated with ³H‐organic species arising from authorised discharges from a radiopharmaceutical manufacturing site. Previous studies have demonstrated that the ³H species have persisted in the environment over three decades providing valuable supporting data to underpin the characterisation of the NMRM. The preparation and characterisation of the NMRM are described along with the subsequent application of the reference material in an international intercomparison exercise involving nineteen laboratories from nine countries. A reference value of 168 ± 22 Bq kg^?1 was derived from the data arising from the proficiency test.