Continuous scanning of the mobility and size distribution of charged clusters and nanometer particles in atmospheric air and the Balanced Scanning Mobility Analyzer BSMA

Measuring of charged nanometer particles in atmospheric air is a routine task in research on atmospheric electricity, where these particles are called the atmospheric ions. An aspiration condenser is the most popular instrument for measuring atmospheric ions. Continuous scanning of a mobility distribution is possible when the aspiration condenser is connected as an arm of a balanced bridge. Transfer function of an aspiration condenser is calculated according to the measurements of geometric dimensions, air flow rate, driving voltage, and electric current. The most complicated phase of the calibration is the estimation of the inlet loss of ions due to the Brownian deposition. The available models of ion deposition on the protective inlet screen and the inlet control electrofilter have the uncertainty of about 20%. To keep the uncertainty of measurements low the adsorption should not exceed a few tens of percent. The online conversion of the mobility distribution to the size distribution and a correct reduction of inlet losses are possible when air temperature and pressure are measured simultaneously with the mobility distribution. Two instruments called the Balanced Scanning Mobility Analyzers (BSMA) were manufactured and tested in routine atmospheric measurements. The concentration of atmospheric ions of the size of about a few nanometers is very low and a high air flow rate is required to collect enough of ion current. The air flow of 52 l/s exceeds the air flow in usual aerosol instruments by 2–3 orders of magnitude. The high flow rate reduces the time of ion passage to 60 ms and the heating of air in an analyzer to 0.2 K, which suppresses a possible transformation of ions inside the instrument. The mobility range of the BSMA of 0.032–3.2 cm² V^− 1 s^− 1 is logarithmically uniformly divided into 16 fractions. The size distribution is presented by 12 fractions in the diameter range of 0.4–7.5 nm. The measurement noise of a fraction concentration is typically about 5 cm^− 3 and the time resolution is about 10 min when measuring simultaneously both positive and negative ions in atmospheric air.     

准噶尔盆地车38井区地震物理模型技术研究

利用地震物理模型技术,依据准噶尔盆地车38井区三维地震的地质解释成果,按一定的模拟相似比,制作一个三维物理模型.利用超声波反射技术,用2种观测系统对模型进行全三维数据采集.通过不同面元三维数据效果对比,提供针对不同地质目标确定面元大小的试验依据,提出从野外采集、资料处理到解释的成套方案.根据不同地震地质条件和勘探目标要求,应用模型正演技术可以指导合理确定三维地震勘探面元大小和其它采集参数.     

Particle size truncation effect on the inference of effective particle diameter

The effective ice crystal particle diameter (De) of cirrus clouds can be inferred by comparing the measured radar / lidar backscattering ratio with the theoretically calculated one. The calculated ratios are based upon assump-tions of ice crystal particle density and size distribution, and it will be affected by the artificially assumed particle size ranges. This size truncation effect on the inference of effective particle diameter will be investigated theoretically by assuming the cirrus ice particle spherical and particle density of 0.9g / cm3. Results show that the truncation at large particle end has very small effect on the inference of De , but the truncation at the small particle end will have some ef-fect on the inference of De.     

Alkaline Degradation of Dissolved Organic Matter

The degradation of dissolved organic matter (DOM) was studied in alkaline solution. The products were characterised using UV/vis spectroscopy, size‐exclusion chromatography (SEC), and by the analysis of low‐molecular‐weight organic acids (LMWOA). The degradation experiments were performed with water from a brown water lake or its isolated fulvic acid fraction and sodium hydroxide at different reaction times and temperatures. Depending on the wavelength and the reaction time, the UV/vis absorbance between 230 nm and 600 nm increased or decreased. The behaviour of model compounds during reactions in alkaline media was compared to the UV/vis spectroscopic behaviour of DOM. The release of LMWOA was described by kinetic data and compared to the data of model reactions. Evidence was given for the carboxylic esters playing a significant role in the release of LMWOA only during the beginning of the alkaline degradation. The results gained by SEC with on‐line UV and DOC detection showed that the average size of DOM was decreasing, and that a major part of the degradation products consisted of low‐molecular‐weight mono‐ and dicarboxylic acids.     

Ecophysiological Studies on Size-fractionated Phytoplankton Populations by Tracer Technique in Wadi el Majanin Dam,Libya

Wadi el Majanin, one of the largest hydraulic structures in Libya was studied for ecophysiological aspects in relation to ambient environment. The waterbody is alkaline (pH=7.2) and characteristic of hydrogen-carbonate (144.8 mg L^–1 CaCO₃) system. Vertical extinction coefficients (> 4.8) indicate very high (biogenic) turbidity. Conspicuous variations of a quantitative kind in algal development (e.g., Pediastrum bloom) together with abundant diatom populations (chlorococcales-diatom assemblage), apart from very common occurrence of cyanobacteria and euglenoids show eutrophic water condition. Winter-summer alternation induced pronounced seasonal variability in the rates of in situ planktonic algal photosynthetic activities (285.7...1305 mg m^–3 d^–1 C). Dark fixation activity, attributed largely to bacterial production, oscillated by order of 2-fold magnitude, characterized by summer maxima (47.6 mg m^–3 d^–1 C). Size-fractional analysis established that smaller forms (< 60 μm), broadly regarded nanno-phytoplankton, frequently dominated (c. 70%) overall algal productivity.     

Social interactions can affect feeding behaviour of fish in tanks

Fish from the same clutch of eggs, so of the same age and family, can differ substantially in size after some time in a tank as result of social interactions. On the basis of computer simulation studies I here demonstrate that it is possible to mimic this empirical observation using the rules of the standard Dynamic Energy Budget (DEB) model, supplemented with a simple stochastic module for interaction between individuals that have identical parameters. The remarkable result is that length-at-age of two individuals in a tank where the number of food particles is kept constant closely follows von Bertalanffy growth curves with very different parameters, while in reality the individuals have identical parameters. The empirical observation demonstrates that fish are close to the supply end of the supply–demand spectrum and that age-based models for growth don't apply to supply systems. The significance of the result is discussed.     

Performance of an inshore fishery in the absence of regulatory enforcement

The principal inshore fishery in the southwest Irish Sea is currently for whelk Buccinum undatum, which expanded in the 1990s and yielded almost 10,000 t in 2003. The fleet exploiting it consisted largely of old boats many of which previously used a variety of gears but which cannot any longer compete with more modern towing craft. Whelk is the only target species for the majority. The fishery is in open access and is not regulated and the paper examines the consequences of this for the fishers, particularly the problems associated with maintaining a way of life traditionally associated with remuneration by share rather than wage. Lack of regulation, it is argued, encourages a short term, opportunistic harvesting regime, which is not conducive to maintain a biologically sustainable fishery.     

Changes in fine sediment size distributions due to interactions with streambed sediments

In the classical view of fine sediment transport and deposition in streams, particles are expected to be removed from flowing water simply by direct sedimentation onto the streambed. However, recent research has demonstrated that fine sediments can propagate into pore spaces in the streambed due to hyporheic exchange and be removed by a combination of physical and chemical processes. This behaviour can significantly alter fine sediment size distributions during in-stream sediment transport because the physical transport of fine particles and their attachment to bed sediment grains are both a function of the particle size. Herein, we present model simulations for deposition of suspended sediments with a bimodal size distribution. We also applied this approach to analyse the results of laboratory flume observations of suspended sediment deposition. Results from model simulations and flume experiments clearly show that the rate of particle deposition increases with increasing particle size. Thus, the larger particles are preferentially removed from mixtures and there is a fining of the mixed suspensions over time. Both particle deposition mechanisms, i.e. particle sedimentation and filtration, contribute to the fining of the mixed fine particle suspensions over time, and their effects are clearly demonstrated using the fundamental process-based model. These results clearly demonstrate the effects of stream-subsurface exchange on the temporal evolution of the suspended fine sediment size distribution in downstream transport.     

Seasonal variability of phytoplankton biomass and composition in the major water masses of the Indian Ocean sector of the Southern Ocean

Long-term changes in phytoplankton biomass and community composition are important in the ecosystem and biogeochemical cycle in the Southern Ocean. We aim to ultimately evaluate changes in phytoplankton assemblages in this region on a decadal scale. However, yearly continuous data are lacking, and long-term datasets often include seasonal variability. We evaluated the seasonal changes in phytoplankton abundance/composition across latitudes in the Indian Ocean sector of the Southern Ocean via multi-ship observations along the 110°E meridian from 2011 to 2013. The chlorophyll a concentration was 0.3–0.5 mg m⁻³ in the Subantarctic Zone (40–50°S) and 0.4–0.6 mg m⁻³ in the Polar Frontal Zone (50–60°S); pico-sized phytoplankton (<10 μm), mainly haptophytes, were dominant in both zones. In the Antarctic Divergence area (60–65°S), the chlorophyll a concentration was 0.6–0.8 mg m⁻³, and nano-sized phytoplankton (>10 μm), mainly diatoms, dominated. Chlorophyll a concentrations and phytoplankton community compositions were the same within a latitudinal zone at different times, except during a small but distinct spring bloom that occurred north of 45°S and south of 60°S. This small seasonal variation means that this part of the Southern Ocean is an ideal site to monitor the long-term effects of climate change.     

The relative contributions of unicellular and filamentous diazotrophs to N2 fixation in the South China Sea and the upstream Kuroshio

We studied the seasonal, diel, and vertical distribution of phytoplankton N₂ fixation to understand the relative contributions of unicellular and filamentous nitrogen fixers (diazotrophs) to N₂ fixation and nitrogen recycling in the northern South China Sea (SCS) and the neighboring upstream Kuroshio. N₂-fixation rates were measured by the ¹⁵N₂ tracer technique (addition by bubble) on unicellular (<10 or 20 µm) and the filamentous diazotrophs (>10 or 20 µm, mostly Trichodesmium and Richelia) fractionated by 10- or 20-µm mesh sizes. The mean depth-integrated total (unicellular+filamentous) N₂-fixation rates in the SCS (51.7±6.2 µmol N m⁻² d⁻¹) averaged 1/3 of that in the Kuroshio (142.7±29.6 µmol N m⁻² d⁻¹), with higher rates in the winter than in other seasons in the SCS and the opposite seasonal pattern in the Kuroshio. Unicellular diazotrophs contributed 65% of the total N₂ fixation in the SCS, which were negatively correlated with surface temperature and, as for total N₂ fixation, were higher in the winter when Trichodesmium spp. were scarce. In comparison, the unicellular diazotrophs contributed 50% of total N₂ fixation in the Kuroshio, and their contributions were not significantly correlated with surface temperature. In both the SCS and the Kuroshio, the unicellular N₂ fixation was more important during the night than during the day, and in the deep euphotic layer than in the surface layer, even in the daytime. Our results show that the unicellular diazotrophs were important N₂ fixers and contributed significantly to N₂ fixation in the tropical marginal seas, more so in the SCS than the Kuroshio.