南海中部海区次表层NO2^——N的最大值

本文根据1983年9月至1985年1月南海中部海区综合调查所获得的NO_2~--N及有关参数的观测资料,分析了该海区NO_2~--N的分布变化特征及其与环境因子的关系。结果表明,调查海区NO_2~--N含量的变化范围在0～0.54μmol/L之间,其中小于0.05μmol/L的测定值约占测定总数的82.1%,而大于0.05μmol/L测定值基本上出现在50～150m层。文中还对该海区次表层NO_2~--N最大值形成的机理作了初步探讨,指出密度跃层的终年存在、铵的氧化和浮游植物的代谢过程是调查海区次表层NO_2~--N最大值形成的主要因素。     

塞曼石墨炉原子吸收法直接测定海水中的铬

海水基体对Cr有增感作用。本文研究了抗坏血酸、柠檬酸三铵、酒石酸、乙酸铵等有机基体改进剂对消除基体干扰效果。前二者均有效地消除基体干扰,但1％抗坏血酸 1％柠檬酸三铵混合试剂的效果更好,它不仅可以消除基体干扰,还可降低背景及噪声,Cr的吸收峰也较平滑。本法准确,相对偏差在0.7—4.4％范围内。回收率在92—109％范围内。若海水Cr含量低于定量下限时,可采用多次进样法。     

胜利二号极浅海步行坐底式钻井平台防腐措施研究

本文根据胜利二号极浅海步行坐底钻井平台的作业和工作环境特点，进行了防腐措施研究，设计了切合实际的防腐措施。该平台在海上作业近四年进坞修理，经观测防腐情况良好。     

Mechanism for the rapid motion of the Qianjiangping landslide during reactivation by the first impoundment of the Three Gorges Dam reservoir, China

The first impoundment of the Three Gorges Dam reservoir in China started from a water surface elevation of 95 m on June 1, 2003 and reached 135 m on June 15, 2003. Shortly after the water level reached 135 m, many slopes began to deform and some landslides occurred. The Qianjiangping landslide is the largest one; it occurred on the early morning of July 14, 2003 and caused great loss of lives and property. Field investigation revealed that, although failure occurred after the reservoir reached 135 m, the stability of the slope was already reduced by preexisting sheared bedding planes. To study the mechanism of the rapid motion of this reactivated landslide, two soil samples were taken from a yellow clay layer and a black silt layer in the sliding zone, respectively, and a series of ring shear tests were conducted on the samples. One series of ring shear tests simulates the creep deformation behavior, while the other series simulates different shear rates. Conclusions drawn from analysis of the ring shear tests indicate that the mechanism of the rapid motion of the reactivated landslide was caused by the rate effect of the black silt layer during the motion phase after the creep failure. The yellow clay layer did not play any important role in the rapid motion in the 2003 event.     

海水入侵水化学指标及侵染程度评价研究

选择Ｃｌ＾,Ｍ、Ｂｒ＾－,ｒＨＣＯ３／ｒＣｌ及ＳＡＲ５项水化学要素作为综合判断海水入侵的指标：染程度划分为４级;确定了各项指标入程度的等级范围。入侵程度的衡理采用模糊数学综合判模型。     

船载物探电子设备的接地问题及解决方案

船栽物探电子设备,是一个电气结合复杂的数据采集记录系统.各系统电子线路因船舶配电方式、工作环境的特殊性,其接地很重要,但容易被忽视.而接地处理不当,在使用时会受到噪声干扰、振荡;或造成仪器的输出榆入电路损坏,不能正常工作.更严重地甚至机壳漏电,危及人身安全.船栽物探电子设备接地问题.可分为"接地保护"和"接地故障"."接地保护"是将电气设备的金属外壳、支架和电缆的护套与大地等单位的金属船体(船壳)作永久性良好的电气连接,它分为保护接地和功能接地."接地故障"是指因设备不正确接地或由于绝缘层的破损、老化及环境恶劣引起绝缘电阻低下或者接地干扰等问题.文中从船载物探电子设备的使用特性出发.讨论在实际接地处理中出现问题的原因,分析了各种接地干扰的原理.并提出了相应的解决方案,对于船栽物探电子设备的实际安装应用有一定的指导意义.     

莱州湾南岸海水入侵现状评价

根据莱州湾南岸海水入侵区地下水水质特点,将海水入侵等级划分为4级。同时,选取Cl^-,矿化度,SO4^2-,rHCO3^-/rCl^-,K^-等指标作为评价因子,并分别确定了这5项指标的等级划分范围。然后,运用模糊数学的综合评判方法,对研究区内海水入侵现状做出评价。     

含水层中海水入侵的数学模型

提出了考虑过渡带的适合潜水含水层和承压含水层的海水入侵数学模型,导出了相应的方程和定解条件.经实例验证,模型是合理和可靠的.     

海水热力学方程TEOS-10及其与海水状态方程EOS-80的比较

新的2010年海水热力学方程TEOS-10采用1990年国际温标以及考虑世界大洋海水组成空间差异的绝对盐度,与旧的1980年海水状态方程EOS-80相比,具有更高的准确度和更广的适用范围,能够直接计算包括熵、焓、热容量在内的旧方程无法计算的热力学变量,将给海洋学研究带来重要的影响。借助气候态平均数据计算的结果表明,新旧方程计算的密度之差,在全球大多数海域可超过10-2kg/m3。在赤道以北的太平洋和印度洋海域,包括中国东海和南海的深海区域,该差别尤为显著,在精度要求较高的研究中必须予以考虑。新方程对密度计算的这一修正主要归因于其首次提出的绝对盐度,考虑了包括中性溶质在内的所有溶质的作用,弥补了实用盐标的缺陷。新旧方程计算冰点等其他物理量也有相应的修正。应尽快推广应用TEOS-10以及绝对盐度,充分发挥其对海洋学发展的推动作用。     

Precise/ Small Sample Size Determinations of Lithium Isotopic Compositions of Geological Reference Materials and Modern Seawater by MC-ICP-MS

The Li isotope ratios of four international rock reference materials, USGS BHVO-2, GSJ JB-2, JG-2, JA-1 and modern seawater (Mediterranean, Pacific and North Atlantic) were determined using multi-collector inductively coupled plasma-mass spectrometry (MC-ICP-MS). These reference materials of natural samples were chosen to span a considerable range in Li isotope ratios and cover several different matrices in order to provide a useful benchmark for future studies. Our new analytical technique achieves significantly higher precision and reproducibility (< ± O.3%o 2s) than previous methods, with the additional advantage of requiring very low sample masses of ca . 2 ng of Li.