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41.
Characterization of beryl (aquamarine variety) from pegmatites of Minas Gerais,Brazil 总被引:2,自引:0,他引:2
R. R. Viana H. Jordt-Evangelista G. Magela da Costa W. B. Stern 《Physics and Chemistry of Minerals》2002,29(10):668-679
Eight samples of the beryl variety aquamarine were selected from four pegmatites in the Governador Valadares and Araçuaí regions in northeastern Minas Gerais State, Brazil. These samples were fully characterized by chemical analysis, infrared and UV-visible spectroscopy, thermal analyses, and high-temperature X-ray diffraction (from room temperature up to 800 °C). Several physical and chemical properties of beryl were found to depend on the amount of water and ions residing in the structural channels. The thermal expansion coefficients from room temperature to about 800 °C are temperature-independent, with αa ? ?3.2 × 10?6 ° C?1 and αc ? ?8.7 × 10?6 ° C?1. The contraction of both a and c unit-cell parameters with increasing temperature and the shift of the infrared band centered at about 1200 cm?1 were tentatively ascribed to interactions between channel water and the silicate rings.The color of beryl seems to be dictated by the relative proportions of Fe3+ in the octahedralsites and of fe2+ in the channels. Thus, deep-blue samples have little Fe3+, whereas greener samples have more Fe3+ or less channel Fe2+. 相似文献
42.
From the mid 1980s through the late 1990s, the channel of the lower Yellow River experienced serious shrinkage, which has decreased the flood conveyance of the channel and the sediment carrying capacity of the flow, raised the water levels of floods, and, thus, severely threatened the safety of flood control along the river. The completion of Xiaolangdi Dam in 1999 could help mitigate the channel shrinkage problem, but the situation has not changed yet. This paper analyses the characteristics, mechanisms, and conditions resulting in channel shrinkage, points out channel instabilities, and puts forward approaches of channel rehabilitation. 相似文献
43.
Tourmalinite and tourmaline-rich rocks associated with Fe-carbonate–graphite phyllite, strata-bound polymetallic sulphide deposits, metabasite and marble were studied, for information on the mechanism of tourmaline formation in the pre-Hercynian low-grade metamorphic sequence of the Mandanici Unit in the Peloritani Mountains of Sicily, southern Italy. The major and trace element compositions of the tourmaline rocks suggest the existence of a sedimentary protolith with pre-metamorphic black shale and bedded chert. Boron was interpreted to be accumulated in a restricted sedimentary basin, between platform carbonate formations, with abundant organic matter and Fe–Al–Ti-rich laterite–bauxite soil-derived clastic supply, under a continental volcano-tectonic extensional regime accompanied by a local convective hydrothermal system along faults. Petrographic, crystal–chemical and δ11B isotopic data are compatible with a model of marine sediment dewatering at temperatures below 200 °C, which caused the removal of boron from clay. Metamorphism led to the development of tourmaline in an Al–Ti-rich environment, in equilibrium with other minerals such as ilmenite, albite and muscovite. The upper temperature of metamorphism (almost 375 °C), estimated on the basis of δ11B, fits geothermometric results from Δ13Ccarbonate–graphite on associated rocks. The estimated value of δ11B in the tourmalinite protolith, − 7.5‰ , is also compatible with continental-derived Al-rich sediments. 相似文献
44.
1INTRODUCTIONTheBrahmaputraRiveroriginatesfromtheJimayanzhongglacieratthenorthfootoftheHimalayaMountainsinSouthTibet,China.I... 相似文献
45.
应用富时叶变换红外谱仪研究了三个启三绿柱石样(包括原样与热处理)。将3435cm^-1宽吸收带归属于与铁离子成键的水。谱图表明隧道水的大量脱去是在800℃以上的温度开始的,对于富碱样品,更可能是在1000℃以后开始。隧道中碱金属离子的阻塞作用是造成绿柱石隧道水难以失去的重要原因. 相似文献
46.
Stream channel development in forested areas is profoundly influenced by large organic debris (logs, limbs and rootwads greater than 10 cm in diameter) in the channels. In low gradient meandering streams large organic debris enters the channel through bank erosion, mass wasting, blowdown, and collapse of trees due to ice loading. In small streams large organic debris may locally influence channel morphology and sediment transport processes because the stream may not have the competency to redistribute the debris. In larger streams flowing water may move large organic debris, concentrating it into distinct accumulations (debris jams). Organic debris may greatly affect channel form and process by: increasing or decreasing stability of stream banks; influencing development of midchannel bars and short braided reaches; and facilitating, with other favourable circumstances, development of meander cutoffs. In steep gradient mountain streams organic debris may enter the channel by all the processes mentioned for low gradient streams. In addition, considerable debris may also enter the channel by way of debris avalanches or debris torrents. In small to intermediate size mountain streams with steep valley walls and little or no floodplain or flat valley floor, the effects of large organic debris on the fluvial processes and channel form may be very significant. Debris jams may locally accelerate or retard channel bed and bank erosion and/or deposition; create sites for significant sediment storage; and produce a stepped channel profile, herein referred to as ‘organic stepping’, which provides for variable channel morphology and flow conditions. The effect of live or dead trees anchored by rootwads into the stream bank may not only greatly retard bank erosion but also influence channel width and the development of small scour holes along the channel beneath tree roots. Once trees fall into the stream, their influence on the channel form and process may be quite different than when they were defending the banks, and, depending on the size of the debris, size of the stream, and many other factors, their effects range from insignificant to very important. 相似文献
47.
The random model of drainage basin composition is founded on the assumptions that (a) natural channels are topologically random in the absence of geological controls and (b) for channel networks developed in similar environments, the exterior and interior link lengths are independent random variables with a common distribution for each type. The effectiveness of this model in estimating the values of geomorphic variables and in explaining and predicting geomorphic relationships is illustrated by several examples. The data required for these examples were obtained from map studies of 30 channel networks, comprising a total of about 8700 links, in eastern Kentucky. A common factor in the success of all three applications of the model is the way in which the planimetric features of drainage basins are determined by their underlying topologic structure. 相似文献
48.
Ken J. Gregory 《地球表面变化过程与地形》1976,1(3):273-285
The identification of channel capacity associated with a particular frequency of peak discharges is necessary for discharge estimation for planning purposes at ungauged sites. Although lichen limits have been suggested to be useful for this purpose, previous studies have not elaborated their hydrological significance. Lichen limits are clearly defined on the sides of rock channels in New England. Australia and they are analyzed in relation to discharge at 6 gauging stations with up to 52 years of continuous record. It is demonstrated that the lowest lichen limit is maintained by peak discharges which occur on average at least once or twice each year. Recurrence intervals based on Annual Series and on Annual Exceedance Series are calculated and for the annual series are fairly consistent for the lowest lichen limit and range from 1·14 to 1·37 years. Lichenometry can be applied to the analysis of river channels in relation to the frequency of peak discharges. By reference to growth curves based upon lichens on Armidale tombstones it is shown that lichenometry may be employed to indicate dates for channel modification due to the removal of blocks and to dam construction and also to date the rock surface between lichen limits. Detailed analysis of the record from gauging stations indicates that where several lichen limits occur in a channel cross section each limit is related to periods when peak discharges exceeded the limits on at least 5 occasions. The lichen-free surfaces were then recolonized by Parmelia spp. and the size of the lichen thalli indicates the time elapsing since these frequent high discharges. 相似文献
49.
K. S. Richards 《地球表面变化过程与地形》1977,2(1):87-92
The nature and strength of the correlation between stream gradient and valley side slope angle are seen to vary according to the order of the stream segment. In addition, it is suggested that the relationship will depend on the efficiency of slope processes, and that this may contribute to tye different from of relationship obtained in different regions. 相似文献
50.
为探讨长江口南港的水动力结构及悬沙侧向输运特征,本文从解析解的角度构建了潮汐河口水沙输运数学模型,并将其应用到长江口南港某横断面上。南港水动力主控于半日潮流,余流主要由陆相径流及本地非线性对流项驱动,悬沙分布上北侧副槽远大于南侧主槽,水沙分布的计算结果与实测结果在结构上基本一致。通过输沙函数进一步分析表明,潮流输沙和余流输沙是南港侧向输沙函数的两个主要部分。南港中强劲径流削弱了涨潮流,增强了落潮流,使得向河槽南侧的涨潮流输沙小于向河槽北侧的落潮流输沙,潮流输沙指向河槽北侧。径流驱动的南港侧向余流在涨潮流方向上为一逆时针环流结构,余流输沙指向河槽北侧。扩散输沙指向南侧主槽,因其总是指向悬沙浓度梯度的负方向。在各输沙因子的综合作用下,南港中大量悬沙捕集于河槽北侧,使得河槽北部底层潮平均含沙量值达到最大值。 相似文献