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以章丘地区土壤为对象,系统分析了表层、深层土壤及8条剖面土壤中Se元素的含量水平,研究了土壤中Se的分布特征及其与土壤类型、成土母质、地形地貌和土壤理化性质及组分的关系。结果表明:章丘地区表层土壤中Se含量在0.1~0.8mg/kg之间,以中硒土壤为主,富硒土壤面积173km2。土壤类型中,水稻土Se平均含量水平最高,为0.55mg/kg;成土母质中以石炭—二叠纪泥页岩发育的土壤Se含量最高;剖面土壤中的Se主要在表层富集。影响章丘地区土壤Se含量分布的主要因素是成土母质、地形地貌、土壤pH、有机质及土壤中硫、铁铝氧化物等组分。 相似文献
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Problems of sustainable development in connection with the change of biogeochemical cycle of selenium and overcoming its deficiency in Russia, Serbia, Belarus and other countries are reported. The history of the biological role of selenium as an essential trace element is discussed. A special program of «Overcoming of selenium deficiency» has been developed by researches of Russia, Serbia and Belarus in view of high morbidity rates for cardiovascular, tumor and endemic diseases affecting the population of both the above and some other countries, including children, prevalence of selenium deficiency among livestock species and aggravation of the environmental situation as a result of man-made processes. 相似文献
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The geochemistry of selenium associated with coal waste in the Elk River Valley,Canada 总被引:1,自引:0,他引:1
Selenium (Se) concentrations more than 12 times greater than the provincial freshwater quality guideline (2 µg/L) were detected in the Elk River downstream from the five open-pit coal mines in southeastern British Columbia's Elk River Valley. To identify possible sources of Se to the Elk River, samples from the coal-bearing Mist Mountain Formation were studied using X-ray diffraction, elemental and oxide analyses, sequential extractions and heavy liquid separation. Between 2.5 and 21.3% of the total Se in the five types of materials studied is water-soluble and 1.0 to 10.6% is associated with hydrous ferric and manganese oxides. Se associated with sulphides and organic material varies between 60 and 84% of the total Se and Se in the silicate structure varies from 5.9 to 24.7%. The ratio of sulphides to the total of organic carbon is well-correlated with the amount of Se in materials closely associated with coal seams containing less than 6 mg/kg of Se (r=0.916). This may suggest that the amount of organic matter present during deposition affects the amount of Se incorporated into sulphides. 相似文献
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Agronomic impact of tephra fallout from the 1995 and 1996 Ruapehu Volcano eruptions, New Zealand 总被引:2,自引:0,他引:2
Eruptions from Ruapehu Volcano on 11 and 14 October 1995 and 17 June 1996 distributed at least 36×106 m3 of sulphur(S)-rich tephra over the central and eastern North Island of New Zealand. The tephras added between 30–1500 kg
ha–1 S to at least 25 000 km2 of land in primary production. Smaller but beneficial amounts of selenium (Se) and in some areas potassium and magnesium
were also supplied. Addition of S to the soils in the form of sulphate and elemental S resulted in a drop in soil pH and an
increase in pasture S contents within seven weeks of the eruptions. The soils affected by the tephra are naturally low in
S and Se, but following the eruptions S was not required in fertilizer applications in many areas. The strongest and longest
lasting effects of S and Se deposition were in high anion-retention soils particularly Hapludands (moist, moderately weathered
soils, derived from volcanic ash). Soluble fluorine concentrations within the tephras were low compared to historic Icelandic
and Chilean examples. However, pastoral livestock deaths were apparently caused by fluorosis in addition to starvation when
tephra covered feed. The Ruapehu tephra contained very low concentrations of other soluble toxic elements.
Received: 17 January 1997 · Accepted: 31 March 1997 相似文献
26.
氢化物原子荧光法测定含铀岩石中微量硒 总被引:4,自引:0,他引:4
本文介绍了氢化物原子荧光法测定含铀岩石中微量硒的方法。测定下限为0.01μg/g,测量精度(2×10-7)RSD为6.63%。方法灵敏度高、快速、操作简便。本方法也适用于一般岩石样品中微量硒的测定。 相似文献
27.
Clausthalite in coal 总被引:2,自引:0,他引:2
A lead selenide mineral, tentatively identified as clausthalite (PbSe) based on optical microscopy, scanning electron microscopy with energy-dispersive X-ray (EDAX), electron microprobe, and scanning proton microprobe (SPM), has been described in a number of coals. While clausthalite has been mentioned as a possible source of Se in coal, it is present in such small quantities and sizes, that the mineral identification has not been absolutely confirmed. The mineral specimens examined in this study would contribute, not only to the Pb and Se concentrations in the coal, but also, in at least one case, to Hg concentrations. 相似文献
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【目的】探索富硒长茎葡萄蕨藻(Caulerpalentillifera)的培养条件。【方法】以亚硒酸钠(Na_2SeO_3)为硒源,采用单因素实验,研究不同硒浓度对长茎葡萄蕨藻的生长、光合色素和硒富集量的影响,通过正交实验,找出适宜长茎葡萄蕨藻富硒的最佳温度、照度和氮磷比组合条件。【结果】在亚硒酸钠0、0.5、1.0、2.0、4.0、8.0mg/L条件下,随亚硒酸钠添加量增加,藻体硒质量分数(干基)从1.70μg/g增加至50.10μg/g,且各组间差异均有统计学意义(P<0.05);亚硒酸钠添加量2.0 mg/L时,藻体硒质量分数达到11.7μg/g;添加量大于2.0 mg/L时,显著抑制藻体的生长(P<0.05),藻体叶绿素a和叶绿素b含量显著性降低(P<0.05);添加量低于2.0 mg/L时,藻体的生长、叶绿素a和叶绿素b含量均无显著性差异;类胡萝卜素含量各组间无明显变化。在培养液亚硒酸钠质量浓度为2.0 mg/L的条件下,藻体最适的生长条件组合是温度28℃、照度2 000 lx、氮磷比10∶1,藻体的最优富硒条件是温度24℃、照度2 000 lx、氮磷比8∶1。【结论】长茎葡萄蕨藻在开发含硒安全性功能海藻食品方面有较大应用潜力。 相似文献
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