Effect of temperature on the dissolution and thermal alteration of combined amino acids fixed in natural sediment under simulated hydrothermal conditions

Seafloor sediment containing biogenic amino acids was heated with NaCl solutions at 50–200 °C for 240 h to investigate the dissolution process of amino acids and evaluate their stabilities under hydrothermal conditions. Dissolved amino acids in the combined phase (dissolved combined amino acids, DCAAs) and free phase (dissolved free amino acids, DFAAs) were rapidly released into the solution during heating. The amount of DCAAs in the solutions was 4–9 times higher than the amount of DFAAs at each temperature. When heated at ⩽ 100 °C, most of the total dissolved hydrolyzable amino acids (TDHAAs) were in the combined form (DCAAs/TDHAAs ratios > 0.9). The compositions of the DCAAs in solutions heated at ⩽ 100 °C were similar to that of the total hydrolyzable amino acids (THAAs) of the initial sediment, indicating that the DCAAs, which are derived from organisms and biodebris in the sediment, are barely altered during the hydrothermal reaction at these temperatures. On the other hand, the DCAAs/TDHAAs ratios were 0.72 and 0.57 at 150 and 200 °C, respectively, and the compositions of the DCAAs at 150 and 200 °C were significantly different from that of the initial THAAs. In addition, non-protein amino acids (β-alanine and γ-aminobutyric acid), which are sensitive biochemical indicators of the diagenetic alteration of natural organic matter, drastically increased to 80.9% of the DCAAs after heating at 200 °C. These results suggests that DCAAs are thermally unstable in the hydrothermal solutions at ⩾ 150 °C. These DCAA would be transformed into thermally stable geo-polymers such as humic-like substances and hydrolyzable kerogens.     

Assessment of Impact on Seafloor Features in INDEX Area

Observations on seafloor features from subbottom profiling and seabed photography data show that the undisturbed and natural conditions before the benthic disturbance undergo a substantial change after operation of the disturber. The effects can be seen in the form of deep trenches and grooves, formed by the action of the sleds and the pumping of the sediment along its path, as well as sediment piles on either side of the track. Biological traces such as fecal coils, casts, tubes, burrows, and trails get obliterated in the areas of disturbance and resedimentation. The smooth, uniform nature of the seafloor observed in predisturbance phase shows microtopographic changes in and around the disturbed area as a result of sediment excavation and resettlement. Vertical mixing as well as lateral transport of sediment alter the geological, biological, physical, and chemical conditions on the seafloor, which need to be monitored over time to assess the process and the time taken for restoration of environmental conditions.     

台湾东北部龟山岛附近海域自然硫烟囱体的铅同位素组成及地质意义

为了探讨龟山岛附近热液自然硫烟囱体的物质来源,通过测定烟囱体内铅同位素的组成特征,分析了该地区热液活动的铅元素物源.研究结果表明,龟山岛附近热液自然硫烟囱体中的铅同位素组成具有很小的变化范围和较均一的铅同位素组成特征,但是与其它深海热液沉积物的铅源不同,与北半球铅同位素的参考线(NHRL)相距甚远.虽然自然硫烟囱体出现在海水环境,但是海水对其不存在铅的贡献,烟囱体内的元素铅主要是陆壳来源.根据以上结果可以进一步推断,龟山岛热液活动区的下伏地层中,存在一定分布范围的陆壳,这对于研究该地区复杂的地质构造特征具有一定意义.     

Gas-hydrate promotion by smectite–bioproduct interactions

Gas hydrates accumulate on the Gulf of Mexico seafloor around hydrocarbon seeps in waters sufficiently deep to provide adequate pressure/temperature combinations. High microbial activities occur around the hydrate accumulations. To understand apparent catalytic effects of bioproducts on hydrate formation, the mechanism of sII hydrate nucleation in unconsolidated porous media was investigated in our laboratory. Because smectite clays interacting with biopolymers had been shown to promote laboratory hydrates by decreasing induction times, increasing formation rates and altering morphology, these materials commonly found in near-surface sediments were selected for study as possible nucleating agents. Dynamic light scattering (DLS) with a helium–neon laser was used to measure particle diameters down to about 2 nm. Scanning electron microscopy (SEM) was utilized to verify particle sizes and to give additional information on biopolymer–clay associations. This paper presents evidence that nanometer-sized particles of mineral–bioproduct associations of about 80 nm–450 nm diameter may act as nucleation sites for hydrate crystal initiations in sediments and then remain dispersed throughout the accumulated hydrate mass. Emulsan biopolymer was shown by SEM to apparently unfold and associate with the smectite (nontronite) in a backbone arrangement and to give multiple hydrate nucleation sites along a linear network. SEM and DLS measurements were in agreement on particle sizes and shapes. X-ray diffraction suggested that biopolymer intercalates the smectite interlayer, probably driven by clay associations with biopolymer hydrophilic groups. It is hypothesized that hydrocarbon gases attach to biopolymer hydrophobic fatty-acid branches protruding from clay interlayers and subsequently facilitate hydrate structure formation by interacting with nearby water associated with the hydrophilic segments of the biopolymer.     

声学方法进行海底沉积物遥测分类:综述

本文讨论利用声学遥测方法进行海底沉积物分类的目的、用途及该项技术的发展背景和现状。重点介绍目前主要的用于浅、表层沉积物分类的声学遥测方法，包括选通等幅脉冲、宽频带脉冲、连续线性扫频脉冲等正入射方法和侧扫声呐、多波束测深等斜入射方法。回顾它们的发展历史，评述它们的技术现状，并讨论它们的进一步发展     

Seafloor Classification of Multibeam Sonar Data Using Neural Network Approach

In this study, the self-organizing map (SOM), which is an unsupervised clustering algorithm, and a supervised proportional learning vector quantization (PLVQ), are employed to develop a combined method of seafloor classification using multibeam sonar backscatter data. The PLVQ is a generalized learning vector quantization based on the proportional learning law (PLL). The proposed method was evaluated in an area where there are four types of sediments. The results show that the performance of the proposed method is better than the SOM and a statistical classification method.     

Enhanced seamount location database for the western and central Pacific Ocean: Screening and cross-checking of 20 existing datasets

Seamounts are habitats of considerable interest in terms of conservation and biodiversity, and in terms of fisheries for bentho-pelagic and pelagic species. Twenty previously compiled datasets including seamount/underwater feature lists, bathymetric maps and emerged feature maps from different sources (ship-derived and satellite altimetry-derived) at different spatial scales (from individual cruise to worldwide satellite data) were gathered in order to compile an enhanced list of underwater features for parts of the western and central Pacific Ocean (WCPO). The KL04 dataset [Kitchingman, A., and Lai, S., 2004. Inferences on potential seamount locations from mid-resolution bathymetric data. Fisheries Centre Research Reports 12 (5), 7–12], listing seamount positions and depths as calculated from satellite altimetry-derived bathymetry, provided the baseline data for this study as it covered the entire region of interest and included summit depth information. All KL04 potential seamounts were cross-checked with other datasets to remove any atolls and islands that had been incorrectly classified as seamounts, to add seamounts undetected by KL04, to update the overall database (geolocation, depth, elevation, and name) and to compile a 12-class typology of the different types of underwater features. Of the 4626 potential seamounts identified in KL04, 719 were multiple identifications of the same large underwater features and 373 (10%) were actually emerged banks, atolls and islands, leaving 3534 actual underwater features. Conversely, 487 underwater features were documented in other datasets but not registered by KL04. The screening of all the potential WCPO seamounts produced a final list of 4021 underwater features with agreed upon position and information. This enhanced list should have many applications in oceanography, biodiversity conservation and studies of the influence of seamounts on pelagic ecosystems and fisheries.     

国际海底观测网络的发展及现状

海底观测网络是推动海洋科学技术发展,了解地球环境系统的重要基础,也是帮助人类了解海洋从而促进全球经济发展的重要方法。文章回顾了各国在海底观测系统发展过程中的研究计划和建设情况;介绍了当前各国海底观测网络及其投入业务应用后,在多学科综合观测、多网络交互融合、数据交换利用以及海洋科学应用等方面的发展方向,对我国海底观测探测网络建设,深海新型传感器发展,海底观测网标准化体系完善等方向进行了分析展望。     

Reconstructing seafloor age distributions in lost ocean basins

Reconstructions of past seafloor age make it possible to quantify how plate tectonic forces,surface heat flow,ocean basin volume and global sea level have varied through geological time.However,past ocean basins that have now been subducted cannot be uniquely reconstructed,and a significant challenge is how to explore a wide range of possible reconstructions.Here,we investigate possible distributions of seafloor ages from the late Paleozoic to present using published full-plate reconstructions and a new,efficient seafloor age reconstruction workflow,all developed using the open-source software GPlates.We test alternative reconstruction models and examine the influence of assumed spreading rates within the Panthalassa Ocean on the reconstructed history of mean seafloor age,oceanic heat flow,and the contribution of ocean basin volume to global sea level.The reconstructions suggest variations in mean seafloor age of~15 Myr during the late Paleozoic,similar to the amplitude of variations previously proposed for the Cretaceous to present.Our reconstructed oceanic age-area distributions are broadly compatible with a scenario in which the long-period fluctuations in global sea level since the late Paleozoic are largely driven by changes in mean seafloor age.Previous suggestions of a constant rate of seafloor production through time can be modelled using our workflow,but require that oceanic plates in the Paleozoic move slower than continents based on current reconstructions of continental motion,which is difficult to reconcile with geodynamic studies.     

Investigation of the stability of submarine sensitive clay slopes underwave-induced pressure

The exploration and exploitation of marine georesources ordinarily disturbs the submarine soft clay surrounding construction areas and leads to a significant decrease in the shear strength of structured and sensitive clayey soils in submarine slopes. Under wave action, local slides can even trigger large-scale submarine landslides, which pose a serious threat to offshore infrastructure such as pipelines and footings. Therefore, accurately evaluating the stability of submarine sensitive clay slopes under wave-induced pressure is one of the core issues of marine geotechnical engineering. In this paper, a kinematic approach of limit analysis combined with strength reduction technique is presented to accurately evaluate the real-time stability of submarine sensitive clay slopes based on the log-spiral failure mechanism, where external work rates produced by wave-induced pressure on slopes are obtained by the numerical integration technique and then are applied to the work-energy balance equations. The mathematical optimization method is employed to achieve the safety factors and the critical sliding surfaces of submarine slopes at different time in a wave cycle. On this basis, the stability of submarine sensitive clay slopes under various wave parameters is systematically investigated. In particular, extreme wave conditions and special cases of slope lengths no more than one wavelength are also discussed. The results indicate that waves have some negative effects on the stability of submarine sensitive clay slopes.