A new look at an old unconformity: field and geochemical data from James Hutton's original unconformity on the Isle of Arran, Scotland

In the year 1787, while visiting the Isle of Arran in southwestern Scotland, James Hutton made the initial discovery of what is now called an angular unconformity. In his example, Dalradian (Neoproterozoic - Cambrian) metasedimentary rocks are overlain by Early Carboniferous (Dinantian) sedimentary rocks of fluvial origin. The exact position of the plane of unconformity has been uncertain because of the presence of a resistant carbonate-rich zone (cornstone) on the Dalradian paleosurface. Whereas the unconformity was previously placed in an erosional re-entrant beneath the prominent carbonate-rich layer, it should be located at the contact between the Dalradian metasedimentary rocks, including those affected by cornstone formation, and overlying Dinantian pebbly sandstones. A prominent set of joints in the Dalradian rocks is sub-parallel to bedding in the overlying Carboniferous rocks and has contributed to ambiguity concerning placement of the plane of unconformity. A second exposure of Hutton's unconformity, at the SW end of the same small Carboniferous outlier on the Arran coast, displays the contact relationships unambiguously. Geochemical investigation of samples from the new locality shows that the cornstones are enriched in CaO, volatiles (LOI), MgO, and MnO. Formation of the cornstone involved replacement of siliciclastic Dalradian metasediments by dolomite. Relative to the fresh Dalradian rocks, the cornstones are depleted in most trace elements, but display enrichment in Sr, Y, Cu, and REE. The cornstone is enriched in REE in a systematic fashion, with a particularly strong concentration of MREE. A mirror-image pattern in the associated Dalradian rocks suggests that the REE enrichment observed in the cornstone is a result of leaching from the country rocks by groundwater, followed by evaporative concentration.     

Quantifying sedimentation patterns of small landslide-dammed lakes in the central Oregon Coast Range

Understanding sedimentation patterns in small coastal watersheds due to landscape perturbations is critical for connecting hillslope and fluvial processes, in addition to managing aquatic habitats for anadromous fish and other aquatic species in the Oregon Coast Range (OCR). Changes in sedimentation patterns spanning the last 250 years are preserved in two landslide-dammed lakes in small watersheds (< 10 km²) underlain by the Tyee Formation in the central OCR. Dendrochronology of drowned Douglas-fir stumps in both lakes provided precise timing of the damming and formation of the lakes, with Klickitat Lake forming in winter ad 1751/52 and Wasson Lake in winter ad 1819/20. Perturbations from wildfires, logging and road development, and previously underappreciated snow events affect sedimentation rates in the lakes to different degrees, and are identified in the sediment record using cesium-137 (¹³⁷Cs), high-resolution charcoal stratigraphy, local fire records, and aerial photography. Each lake has variable sedimentation accumulation rates (0.05–4.4 cm yr⁻¹) and mass accumulation rates (0.02–1.42 g cm⁻² yr⁻¹). Sedimentation rates remained low from the landslide-damming events until the mid-19th century, when they increased following stand-replacing wildfires. Aside from a sediment remobilization triggered by human modification of the landslide dam at Klickitat Lake around 1960, the largest peaks in mass accumulation rates in the mid-20th century at both lakes in the early 1950s precede major road construction and logging activity in the watersheds. Subsequent sedimentation rates are lower, but variable, and possible effects of logging and road development might be exacerbated by abnormal precipitation and heavy snow events. A comparison of previous studies of landslide-dammed lakes in larger watershed of the OCR are consistent with our findings of increased sedimentation in the mid-20th century, as well as higher sedimentation rates in the debris-flow dominated southern Tyee Formation than in the lower-relief northern Tyee Formation.     

The Jurassic Coast Story Book: An approach to geoheritage interpretation from the Jurassic Coast World Heritage Site

The World Heritage status of the Jurassic Coast has important implications for how the geoheritage of the site is communicated to audiences. UNESCO defines World Heritage Sites as places with Outstanding Universal Value to all people that must be preserved for future generations. Building relationships between people and place is key to conservation and on the Jurassic Coast that is delivered by providing audiences with physical, intellectual and emotional access to the Site. Heritage interpretation offers an effective way to develop these connections and create diverse ways for people to engage with the unique Earth Science stories that underpin the World Heritage Status of the Dorset and East Devon Coast. This paper reflects on the approach to interpretation taken by the Jurassic Coast Team and explores the ways in which geoheritage is a challenging subject to interpret. Practitioners on the Jurassic Coast have more recently developed an interpretive approach to help overcome these difficulties. Three categories of geoheritage stories were identified (Landscape, Cultural geology and Earth History) and three interpretive principles were devised (perspective, intimacy and imagination) as a way of scoping out a relevant emotional context for interpretive content. This approach laid the foundation for the development of a new interpretation framework for the Jurassic Coast – The Jurassic Coast Story Book, which will be subject to ongoing testing and evaluation by the new organisation leading on the protection and promotion of the Jurassic Coast World Heritage Site; Jurassic Coast Trust.     

Phosphate removal from water by naturally occurring shale,sandstone, and laterite: The role of iron oxides and of soluble species

Aqueous phosphate removal by three geomaterials from Ivory Coast was evaluated to determine their potential application as low-cost phosphate adsorbents in wastewater treatment. Batch experiments showed that phosphate uptake strongly depended on pH. Laterite and sandstone dissolution was less pronounced compared to shale. A correlation between concentrations of aqueous cation species released from shale and phosphate uptake was observed. The kinetics were well described using the pseudo-second-order model. Isotherms displayed a saturation level on shale, while phosphate uptake continuously increased for laterite and sandstone. The removal efficiency decreased in the following ranking order: laterite > sandstone > shale. Laterite was also the most efficient adsorbent in column experiments. The high phosphate removal efficiency of laterite (8.3 mg PO₄ g^?1) was attributed to the presence of superparamagnetic low grain sizes of goethite. Laterite is a particularly promising material for further investigation in wastewater treatment technology such as constructed wetlands.     

Detrital zircon age spectra of middle and upper Eocene outcrop belts,U.S. Gulf Coast region

Recently reported detrital zircon (DZ) data help to associate the Paleogene strata of the Gulf of Mexico region to various provenance areas. By far, recent work has emphasised upper Paleocene‐lower Eocene and upper Oligocene strata that were deposited during the two episodes of the highest sediment supply in the Paleogene. The data reveal a dynamic drainage history, including (1) initial routing of western Cordilleran drainages towards the Gulf of Mexico in the Paleocene, (2) an eastward shift of the western continental divide, from the Jura‐Cretaceous cordilleran arc to the eastern edge of the Laramide province after the Paleocene and (3) a southward shift, along the eastern Laramide province, of the headwaters of river systems draining to the Mississippi and Houston embayments at some time between the early Eocene and Oligocene. However, DZ characterisation of most (~20 Myr) of the middle Eocene‐lower Oligocene section remains limited. We present 60 DZ age spectra, most of which are from the middle or upper Eocene outcrop belts, with 50–200‐km spacing. We define six to eight distinct groups of DZ age spectra for middle and upper Eocene strata. Data from this and other studies resolve at least six substantial temporal changes in age spectra at various positions along the continental margin. The evolving age spectra constrain the middle and upper Eocene drainage patterns of large parts of interior North America. The most well‐resolved aspects of these drainage patterns include (1) persistent rivers that flowed from erosional landscapes across the Paleozoic Appalachian orogen either into the low‐lying Mississippi embayment or directly into the eastern Gulf; (2) at least during marine regressions, a trunk channel that likely flowed southward along the axial part of Mississippi Embayment and integrated tributaries from the east and west; and (3) rivers that flowed to the Houston embayment in the middle Eocene that likely originated in the Laramide province in central Colorado and southern Wyoming, as Precambrian basement highs in those source areas were being unroofed.     

江苏小庙洪牡蛎礁的地貌-沉积特征

利用卫星影象和野外实地勘察资料对江苏小庙洪牡蛎礁的地貌-沉积特征进行分析。结果表明，该牡蛎礁发育在强潮淤泥质潮坪上，造礁牡蛎主要是近江牡蛎和长牡蛎，表层的鲜活牡蛎为褶牡蛎。牡蛎礁区海水属盐度较高(27—30)的半成水，含沙量较大，为0．2—0．3g／L。活体牡蛎堆积体顶面高于周围潮间下带滩面1．0—1．5m。潮流较强，多在0．5—2．0m／s。海岸剖面可分为4个带，即礁后潮间带、潮沟、礁体生长带及礁前斜坡带。由于处于海岸侵蚀段，礁后潮坪缺失潮上带和大部分的潮间上带。礁后潮坪主要以粗粉砂为主，礁后潮沟冲淤变化较大，故礁体生长带时而为一沙洲，时而又与岸滩相连。礁体生长带分布在潮间下带，可看到独立的斑状礁体、带状礁体和大面积环状礁体群。环状礁的微地貌可以划分为礁塘(泻湖)、塘口和塘沟、塘口三角洲、礁墙和礁平台等。     

Towards a quantitative model of downstream dilution of point source geochemical anomalies

The quantitative relation between point source soil geochemical anomalies and their response in stream sediments is linked through the concept of productivity (area × concentration). The equation proposed by Hawkes in 1976 is shown to be a subset of a wider range of equations proposed by Russian workers. These workers introduced two coefficients to account for the contrasting behaviour of different elements and the position of the soil anomaly within the drainage catchment. The calculation of these coefficients requires a series of samples downstream from the ending of anomalous soil input. The concept of productivity has particular application where multiple samples and anomalies are present in catchments. Plotting of productivity allows the discrimination of anomalous areas not detectable from raw element concentrations. The usefulness of these techniques is demonstrated from a small detailed stream sediment survey in NW Scotland. Dispersion from a gossan shows deviation from the Hawkes equation with the result that detailed sampling is required to detect soil anomalies. Plotting productivity allows the detection at the base of major slopes of anomalies that are diluted by upslope sediment.     

Particle‐size evidence of barrier estuary regime as a new proxy for ENSO climate variability

We investigate a new proxy for ENSO climate variability based on particle‐size data from long‐term, coastal sediment records preserved in a barrier estuary setting. Corresponding ~4–8 year periodicities identified from Wavelet analysis of particle‐size data from Pescadero Marsh in Central Coast California and rainfall data from San Francisco reflect established ENSO periodicity, as further evidenced in the Multivariate ENSO Index (MEI), and thus confirms an important ENSO control on both precipitation and barrier regime variability. Despite the fact that barrier estuary mean particle size is influenced by coastal erosion, precipitation and streamflow, balanced against barrier morphology and volume, it is encouraging that considerable correspondence can also be observed in the time series of MEI, regional rainfall and site‐based mean particle size over the period 1871–2008. This correspondence is, however, weakened after c.1970 by temporal variation in sedimentation rate and event‐based deposition. These confounding effects are more likely when: (i) accommodation space may be a limiting factor; and (ii) particularly strong El Niños, e.g. 1982/1983 and 1997/1998, deposit discrete >cm‐thick units during winter storms. The efficacy of the sediment record of climate variability appears not to be compromised by location within the back‐barrier setting, but it is limited to those El Niños that lead to barrier breakdown. For wider application of this particle size index of ENSO variability, it is important to establish a well‐resolved chronology and to sample the record at the appropriate interval to characterize deposition at a sub‐annual scale. Further, the sample site must be selected to limit the influence of decreasing accommodation space through time (infilling) and event‐based deposition. It is concluded that particle‐size data from back‐barrier sediment records have proven potential for preserving evidence of sub‐decadal climate variability, allowing researchers to explore temporal and spatial patterns in phenomena such as ENSO. Copyright © 2017 John Wiley & Sons, Ltd.     

Rapid adjustment of shoreline behavior to changing seasonality of storms: observations and modelling at an open‐coast beach

An 8‐year time series of weekly shoreline data collected at the Gold Coast, Australia, is used to examine the temporal evolution of a beach, focusing on the frequency response of the shoreline to time‐varying wave height and period. Intriguingly, during 2005 the movement of the shoreline at this site changed from a seasonally‐dominated mode (annual cycle) to a storm‐dominated (~monthly) mode. This unexpected observation provides the opportunity to explore the drivers of the observed shoreline response. Utilizing the calibration of an equilibrium shoreline model to explore the time‐scales of underlying beach behavior, the best‐fit frequency response (days^?1) is shown to be an order of magnitude higher post‐2004, suggesting that a relatively subtle change in wave forcing can drive a significant change in shoreline response. Analysis of available wave data reveals a statistically significant change in the seasonality of storms, from predominantly occurring at the start of the year pre‐2005 to being relatively consistent throughout the year after this time. The observed change from one mode of shoreline variability to another suggests that beaches can adapt relatively quickly to subtle changes in the intra‐annual distribution of wave energy. Copyright © 2016 John Wiley & Sons, Ltd.     

The glacial and interstadial sediments at the Burn of Benholm,Kincardineshire: evidence for onshore pre‐Devensian ice movement in northeast Scotland

Pebbly clays and diamictons containing marine shell fragments and peat lenses exposed beneath subglacially deposited Late Devensian till at the Burn of Benholm provide new insights into the glacial history of Quaternary sequences in eastern Scotland. The peat yielded pollen of interstadial affinity (including Bruckenthalia spiculifolia) and non‐finite radiocarbon dates. Comparisons with other pre‐Late Devensian pollen records in northern Scotland suggest that the peat lenses are remnants of an Early Devensian interstadial deposit, of Oxygen Isotope Substage 5c or 5a age. Reworked faunal assemblages in the shelly sediments include Quaternary marine molluscs of low boreal aspect, as well as Mesozoic and Palaeozoic microfossils. Amino acid ratios from fragments of Arctica islandica suggest that the shells are of Oxygen Isotope Stage 9 age or older. The fabric and composition of the shelly sediments are consistent with their emplacement as deformation till during the onshore movement of glacially transported rafts of marine sediment. Folded and sheared contacts between the shelly deposits, peat lenses and the overlying Late Devensian till indicate that the fossiliferous sediments were glacitectonised during the main Late Devensian glaciation, when ice moved from Strathmore and overrode the site from the southwest. British Geological Survey. © NERC 2000.