水分子结构模式及液态固态水若干特征成因探讨

水是包括海洋大气在内的地球生态系统中极重要又有很多特殊性的物质。其特性的成因尚远非清晰。本文提出一种水分子(H_2O)结构及其固态液态水体的结构模式,探讨和模拟计算了其若干特征的成因,结果能较好符合实测值。(1)从氢(H)氧(O)原子结构和电子绕各原子核及相互绕行规律的等概率随机轨道中实现符合库伦力和开普勒运动规律的优势轨道耦合成平均状态稳定的准刚性的水分子结构。其核心是O原子与等距离分立其两侧的2个H原子构成的等腰三角形,其间距平方之比(H-H)_2/(H-O)_2=2.5;电子云活动空间为1个由4个等边三角形为面构成具有6个等长稜的正四面锥体结构水分子模式(可简称"水分子正锥体模式");该模式具有很大电偶极矩。(2)水分子的端点间在约0.27 nm距离内可以按"+""-"电荷吸引原则耦合。6个水分子将按正、负电荷对接耦合,连接成六边环形"壁"的"笼式隧道空间",可容纳其他物质,无电荷显示,电导率极地。(3)在空气中0℃以下凝结冰晶时三维不对称,"薄片"的雪花形成概率更大,其形态也按自相似原则体现了水分子结构的六角六边六针形的特征。(4)液态水分子维持固态水冰的"冰/水笼"结构模式,但由于2个氢原子上的电子同时到达1个"-"电荷端的概率为1/11,当0℃以上部份水分子能摆脱框架水分子束缚后,可以再耦合一个从框架上"脱落"的"自由水分子"使其进入水笼,从而水容积缩小;固体冰和液态水的密度之比为11/12=0.916 667。自由水分子和水笼框架上的水分子可以随时互换(在10-5s时间尺度上),并适应固体壁的形态,既是不可压缩,又有柔软、可变形特点;水在0~100℃时的空/占比达2.28,模式可解译高温高压的水汽中检测到2.16 g·cm-3,水热传导系数很大,比热容量很大,有"异常"的U形特点,且液态水的比热容量略大于固态水冰的热容量的1/2等特征。(5)讨论了水对O_2、H_2S、NaCl、KCl等的溶解度随温度变化的若干特征的成因和计算模式。通过NaCl饱和溶液实验,证实了本文模式。(6)与液态水体表面特征有关的特点及本文实际应用将在随后续文中讨论。     

利用TRMM卫星资料对青藏高原地区强对流天气特征分析

利用热带测雨卫星TRMM(Tropical Rainfall Measure Mission)多种探测结果,结合NCEP再分析资料,研究了发生在青藏高原地区的一次强对流天气特征,综合分析了高原地区对流云特殊的水平、垂直结构特征。结果表明:(1)该强对流降水系统由几个孤立、零散的块状降水云团组成,以深厚弱对流降水为主,微波亮温的低值区也呈孤立、零散的块状分布,并且整个对流系统的云顶高度一致偏高,深厚强对流降水的雨谱主要集中在1～20mm.h-1的范围内,90%以上的深厚弱对流降水样本数和降水量都集中在0～5mm.h-1范围内,在垂直方向上呈被"挤压"状态。除云冰粒子集中在6～18km高度外,可降冰、可降水和云水粒子都集中在低层8km以下,冰雹天气表现为可降冰粒子在低层含量偏高。(2)高原地区强对流天气的特征与其他地方的不同,表现为雨强较小,比平原地区明显偏弱,且对流云降雨样本在不同降雨率范围内分布不均匀,降水云团雨顶高度也远低于平原地区的对流云,地表降水率大值区与微波辐射亮温低值区呈不完全对称分布,潜热释放呈单峰型。(3)高原地区强对流系统发生时,垂直上升运动在400hPa达到最大,水汽主要集中在400hPa高度以下的范围内。     

Vertical Structures of Convective and Stratiform Clouds in Boreal Summer over the Tibetan Plateau and Its Neighboring Regions

Cloud is essential in the atmosphere, condensing water vapor and generating strong convective or large-scale persistent precipitation. In this work, the relationships between cloud vertical macro- or microphysical properties, radiative heating rate, and precipitation for convective and stratiform clouds in boreal summer over the Tibetan Plateau (TP) are analyzed and compared with its neighboring land and tropical oceans based on CloudSat/CALIPSO satellite measurements and TRMM precipitation data. The precipitation intensity caused by convective clouds is twofold stronger than that by stratiform clouds. The vertical macrophysics of both cloud types show similar features over the TP, with the region weakening the precipitation intensity and compressing the cloud vertical expansion and variation in cloud top height, but having an uplift effect on the average cloud top height. The vertical microphysics of both cloud types under conditions of no rain over the TP are characterized by lower-level ice water, ice particles with a relatively larger range of sizes, and a relatively lower occurrence of denser ice particles. The features are similar to other regions when precipitation enhances, but convective clouds gather denser and larger ice particles than stratiform clouds over the TP. The atmospheric shortwave (longwave) heating (cooling) rate strengthens with increased precipitation for both cloud types. The longwave cooling layer is thicker when the rainfall rate is less than 100 mm d^?1, but the net heating layer is typically compressed for the profiles of both cloud types over the TP. This study provides insights into the associations between clouds and precipitation, and an observational basis for improving the simulation of convective and stratiform clouds over the TP in climate models.     

福建推覆构造研究与找矿突破

阐述了福建推覆构造的研究成果,依据福建推覆构造的不同表现形式,划分为东部逆冲推覆构造带、中部逆冲褶皱推覆构造带、西部挤压推覆构造带。讨论了其构造特征形式,将推覆（滑脱）构造形式划分为二类五型及其控岩控矿的地质特征。总结了运用推覆构造研究成果在寻找隐伏煤矿及铁多金属矿的成功实例,提出了推覆构造理论对深部找矿指导作用和找矿方向。     

淮北采煤塌陷区小型湖泊轮虫群落结构的季节变化

2005年3月至2007年2月对淮北采煤塌陷区两个小型湖泊(南湖和乾隆湖)轮虫的群落结构进行了连续两年的调查.南湖共检测到轮虫9属14种,乾隆湖共计15属27种.乾隆湖轮虫年平均密度为1916 ind./L,约为南湖(198.4 ind./L)的近10倍.乾隆湖和南湖轮虫的最大密度分别为6915和1185 ind./L.在南湖和乾隆湖轮虫的季节动态中,冬、春季以前额犀轮虫为主,夏、秋季以多肢轮虫、异尾轮虫为主.在南湖,长肢多肢轮虫、暗小异尾轮虫和小链巨头轮虫分别占年平均密度的24.4％、24.0％和23.0％.在乾隆湖,暗小异尾轮虫、长肢多肢轮虫和裂痕龟纹轮虫分别占年平均密度的31.5％、27.2％和7.3％.南湖和乾隆湖轮虫的Shannon-Wiener指数范围分别为0～2.06和1.28 ～2.68,平均值分别为0.67和1.99.水温、营养盐和浮游植物生物量对淮北采煤塌陷区小型湖泊轮虫的群落结构具有重要影响.     

长江口盐沼滩面发育对有机碳深度分布的制约

通过对长江口崇明东滩高潮滩、中潮滩以及光滩柱状样的有机碳含量与碳稳定同位素组成（δ13C）、粒度组成等的测定,研究盐沼有机碳深度分布特征与形成机制。结果表明,盐沼土壤颗粒有机碳（POC）主要赋存于粒径小于0.016 mm的颗粒中,POC含量对粒径在0.002~0.004 mm区间的颗粒含量变化最敏感,说明盐沼POC主要来自长江径流悬移质,这与有机碳稳定同位素结果一致。土壤POC含量与不同粒径区间颗粒含量相关关系表明,高潮滩与中潮滩柱样的泥沙级配较为接近;光滩柱样POC含量与不同粒径区间颗粒含量相关关系特征与高、中潮滩柱样的基本类似,主要不同表现在粒径大于0.016 mm的粗颗粒,这很可能受控于盐沼不同高程部位动力沉积过程。盐沼植被对高、中潮滩柱样POC的贡献相当可观,个别层段高达55.6%;植被对土壤POC的贡献受到滩面过程的明显制约。滩面动力沉积过程形成盐沼垂向上独特的沙、泥纹层构造,其优良的封堵效能显著影响土壤有机碳的垂向分布。盐沼滩面动力沉积过程是塑造有机碳深度分布特征的关键因素。     

郯庐断裂带中南段重磁特征与深部构造

郯庐断裂带是中国东部地球物理场的分界线。它在磁场上呈现出一条NNE向线性正磁异常带,它的重力场特征表现为规模较大的布格重力异常梯度带。在断裂带的两侧,其区域磁场、区域重力场无论是场值大小,还是异常规模以及各异常的展布形态等诸方面都具有明显的区别。地球物理特征揭示郯庐断裂带深部构造,为研究重点矿产分布规律及地震灾害预报具有重要的实际意义。     

福建武夷山仙店—浦城渔梁逆冲构造带控矿作用

武夷山仙店—浦城渔梁逆冲构造带发育于崇安火山盆地东缘,呈北东向展布,由盆缘逆断层为主体,局部具推覆特征。断裂下盘以中新生代中酸性火山岩系为主,上盘主要分布前震旦系变质岩系和南北向中酸性侵入岩,构造性质与地层岩性的差异导致其成矿作用不同,逆冲断裂与火山岩系控制铀成矿作用,推覆构造与变质岩系影响铅锌多金属成矿作用。     

胶东地区郭家岭岩体岩石构造组合特征及地质意义

通过对前人就郭家岭花岗岩构造地质学、岩石化学、同位素年代学等地质信息资料的分析、研究,认为胶东地区郭家岭花岗闪长岩一花岗岩总体上归属于幔源岩浆与壳源岩浆混合后经分异作用而成的同熔深成型花岗岩类;主要形成于由洋壳俯冲引起的火山岛弧环境、大陆碰撞环境和弧后拉张性质的大陆边缘环境;其定位机制为：沿着NEE向挤压带从小面积到大面积频率式脉动或涌动热轻气球膨胀式定位;该岩石构造组合主体形成于早白垩世。从岩石构造组合的概念,将其定义为造山中期郭家岭弱片麻状花岗闪长岩～花岗岩组合。     

Theory And Measurements For Turbulence Spectra And Variances In The Atmospheric Neutral Surface Layer

Predictions from a new theory for high Reynolds number turbulent boundary layers during near-neutral conditions are shown to agree well with measurements of atmospheric surface-layer variances and spectra. The theory suggests surface-layer turbulence is determined by detached eddies that largely originate in the shearing motion immediately above the surface layer; as they descend into this layer, they are strongly distorted by the local shear and impinge onto the surface. Because the origin of these eddies is non-local, they are similar to those described in previous studies as `inactive' turbulence. However, they are, in fact, dynamically highly active, supplying the major mechanism for the momentum transport, including upward bursting on the time scale of the larger eddies. The vertical velocity results show that the variance and the low frequency parts of spectra increase with height in the surface layer, while in the self similar (k₁ ^-1) range the streamwise low frequency components are approximately constant with height. These large-scale longitudinal eddies extend to a length _s, which is equal to the boundary-layer height near the surface andincreases linearly to a maximum of about three times the boundary-layer height at roughly 15 m and decreases in the upper parts of the surface layer. This lower part of the surface layer, the eddy surface layer, is the region in which the eddies impinging from layers above are strongly distorted. This new result for the atmospheric boundary layer has practical application for calculating fluctuating wind loads on structures and lateral dispersion of pollution from local sources.