Methylmercury production in sediments of Chesapeake Bay and the mid-Atlantic continental margin

Methylmercury (MeHg) concentration and production rates were studied in bottom sediments along the mainstem of Chesapeake Bay and on the adjoining continental shelf and slope. Our objectives were to 1) observe spatial and temporal changes in total mercury (HgT) and MeHg concentrations in the mid-Atlantic coastal region, 2) investigate biogeochemical factors that affect MeHg production, and 3) examine the potential of these sediments as sources of MeHg to coastal and open waters. Estuarine, shelf and slope sediments contained on average 0.5 to 1.5% Hg as MeHg (% MeHg), which increased significantly with salinity across our study site, with weak seasonal trends. Methylation rate constants (k_meth), estimated using enriched stable mercury isotope spikes to intact cores, showed a similar, but weaker, salinity trend, but strong seasonality, and was highly correlated with % MeHg. Together, these patterns suggest that some fraction of MeHg is preserved thru seasons, as found by others [Orihel, D.M., Paterson, M.J., Blanchfield, P.J., Bodaly, R.A., Gilmour, C.C., Hintelmann, H., 2008. Temporal changes in the distribution, methylation, and bioaccumulation of newly deposited mercury in an aquatic ecosystem. Environmental Pollution 154, 77] Similar to other ecosystems, methylation was most favored in sediment depth horizons where sulfate was available, but sulfide concentrations were low (between 0.1 and 10 μM). MeHg production was maximal at the sediment surface in the organic sediments of the upper and mid Bay where oxygen penetration was small, but was found at increasingly deeper depths, and across a wider vertical range, as salinity increased, where oxygen penetration was deeper. Vertical trends in MeHg production mirrored the deeper, vertically expanded redox boundary layers in these offshore sediments. The organic content of the sediments had a strong impact on the sediment:water partitioning of Hg, and therefore, on methylation rates. However, the HgT distribution coefficient (K_D) normalized to organic matter varied by more than an order of magnitude across the study area, suggesting an important role of organic matter quality in Hg sequestration. We hypothesize that the lower sulfur content organic matter of shelf and slope sediments has a lower binding capacity for Hg resulting in higher MeHg production, relative to sediments in the estuary. Substantially higher MeHg concentrations in pore water relative to the water column indicate all sites are sources of MeHg to the water column throughout the seasons studied. Calculated diffusional fluxes for MeHg averaged  1 pmol m^− 2 day^− 1. It is likely that the total MeHg flux in sediments of the lower Bay and continental margin are significantly higher than their estimated diffusive fluxes due to enhanced MeHg mobilization by biological and/or physical processes. Our flux estimates across the full salinity gradient of Chesapeake Bay and its adjacent slope and shelf strongly suggest that the flux from coastal sediments is of the same order as other sources and contributes substantially to the coastal MeHg budget.     

Using iron speciation in authigenic carbonates from hydrocarbon seeps to trace variable redox conditions

Seepage of hydrocarbon-rich fluids out of the marine sedimentary column is characterized by temporal changes of flow intensity and resultant spatially variable redox conditions. Authigenic carbonates at marine hydrocarbon seeps provide excellent geological and geochemical archives that serve to explore seepage dynamics over time. In this study, we investigated the potential of Mössbuaer spectroscopy and Fe contents of seep-related authigenic carbonates from the Congo Fan, the Gulf of Mexico, and the Black Sea for reconstructing past redox conditions and fluid seepage activity at cold seeps. The Fe speciation observed by Mössbauer spectroscopy and Fe contents suggest that (1) the Congo Fan carbonates precipitated in a sulfidic environment, (2) the formation conditions of seep carbonates were variable at the Gulf of Mexico seep site, ranging from oxic to suboxic and anoxic and even spanning into the methanogenic zone, and (3) the stratified water column of the Black Sea or suboxic condition resulted in low Fe contents of Black Sea carbonates. The study reveals that Fe speciation can provide constraints on the wide range of redox conditions that imprinted seep carbonates during the life span of seepage. Similarly, Mössbauer spectroscopy – particularly when used in combination with the analysis of redox-sensitive elements – is a promising tool to trace variable redox conditions in marine paleoenvironments other than seeps.     

Paleo-redox depositional conditions inferred from trace metal accumulation in two Cretaceous-Paleocene organic-rich sequences from Central Egypt

Cretaceous-Paleocene organic-rich sediments in Egypt occur as an east-west trending belt extending from the Quseir-Safaga district (Red Sea) to the Kharga-Dakhla (Western Desert) region. They are associated with the Duwi Formation (phosphate-bearing) and the overlying Dakhla Formation (deeper epicontinental shale/marl). This study aims to reconstruct the paleo-redox conditions during deposition of these thermally immature organic-rich sediments using carbon-sulfur-iron systematics and trace metal proxies in two cores, one each from the Quseir and Abu Tartur areas. Paleoproductivity, based on P content, seems to have been higher in the Quseir section than in the Abu Tartur section. The Quseir section also records a relatively greater occurrence of anoxic conditions during the accumulation of these sediments than the Abu Tartur section. This difference is indicated by its markedly higher total organic carbon (TOC) content as well as higher contributions of redox-sensitive and sulfide-forming metals (Mo, U, Ni, V, and Co). A weak correlation exists between S and TOC, and a positive S intercept (>1) was observed in most of the rock units of the study sections. A high consistency between the TOC-S-Fe relations and trace metals findings was found. The uppermost Duwi and the lowermost Dakhla strata, which have the highest TOC and represent a maximum sea transgression during the Late Cretaceous, have the highest contents of redox-sensitive trace metals. The carbonate-dominated transgressive Baris and Beida members of the Dakhla Formation record relatively stronger oxygen-depleted conditions during their accumulation than others, which led to relatively higher TOC contents and redox-sensitive metal accumulations. A scenario for the environmental conditions that existed during the deposition of these organic-rich successions, based on compiled trace metals and TOC-S-Fe implications, is reconstructed here.     

Relationships between radium and radon occurrence and hydrochemistry in fresh groundwater from fractured crystalline rocks, North Carolina (USA)

Naturally-occurring radionuclides (uranium, radium, and radon), major dissolved constituents, and trace elements were investigated in fresh groundwater in 117 wells in fractured crystalline rocks from the Piedmont region (North Carolina, USA). Chemical variations show a general transition between two water types: (1) slightly acidic (pH 5.0–6.0), oxic, low-total dissolved solids (TDS) waters, and (2) near neutral, oxic to anoxic, higher-TDS waters. The uranium, radium, and radon levels in groundwater associated with granite (Rolesville Granite) are systematically higher than other rock types (gneiss, metasedimentary, and metavolcanic rocks). Water chemistry plays a secondary role on radium and radon distributions as the ²²²Rn/²²⁶Ra activity ratio is correlated with redox-sensitive solutes such as dissolved oxygen and Mn concentrations, as well as overall dissolved solids content including major divalent cations and Ba. Since ²²⁴Ra/²²⁸Ra activity ratios in groundwater are close to 1, we suggest that mobilization of Ra and Rn is controlled by alpha recoil processes from parent nuclides on fracture surfaces, ruling out Ra sources from mineral dissolution or significant long-distance Ra transport. Alpha recoil is balanced by Ra adsorption that is influenced by redox conditions and/or ion concentrations, resulting in an approximately one order of magnitude decrease (~ 20,000 to ~ 2000) in the apparent Ra distribution coefficient between oxygen-saturated and anoxic conditions and also across the range of dissolved ion concentrations (up to ~ 7 mM). Thus, the U and Th content of rocks is the primary control on observed Ra and Rn activities in groundwater in fractured crystalline rocks, and in addition, linked dissolved solids concentrations and redox conditions impart a secondary control.     

弱磁场及甚强磁场下奇异夸克物质Urca过程的中微子能量损失率

研究了磁场对奇异星模型中夸克直接Urca过程的中微子能量损失率的影响,首先改进了弱场条件下的近似计算方法,这一方法可以推广到其他弱作用过程．在甚强磁场下,严格地计算Urca过程的中微子能量损失率,结果显示辐射率强烈地依赖于磁场,与磁场的二次方成正比,更重要的是对温度的依赖关系不同于弱场及没有磁场时的情形．     

Constraints on the176Lu cosmochronometer

In an endeavour to resolve reported discrepancies in the value of the branching ratio of¹⁷⁶Lu at astrophysical energies, a new determineation of the¹⁷⁵Lu (nγ)^176mLu capture cross section has been measured as 958 ± 58 mb. This gives a value of the branching ratio of 0.21 ±0.05. This result indicates that some reequilibration of the ground and isomeric states of¹⁷⁶Lu occurs in stellar environments undergoing s-process nucleosynthesis, and confirms that¹⁷⁶Lu is not a reliable cosmochronometer. However the very existence of¹⁷⁶Lu in the solar system implies that the ground state of¹⁷⁶Lu was not completely depopulated, and provides the possibility of using this nuclide as a sensitive thermometer for stellar processes.     

Gamma-ray emission from individual classical novae

Classical novae are important producers of radioactive nuclei, such as ⁷Be, ¹³N, ¹⁸F, ²²Na and ²⁶Al. The disintegration of these nuclei produces positrons (except for ⁷Be) that through annihilation with electrons produce photons of energies 511 keV and below. Furthermore, ⁷Be and ²²Na decay producing photons with energies of 478 and 1275 keV, respectively, well in the γ-ray domain. Therefore, novae are potential sources of γ-ray emission. We have developed two codes in order to analyse carefully the γ-ray emission of individual classical novae: a hydrodynamical one, which follows both the accretion and the explosion stages, and a Monte Carlo one, able to treat both production and transfer of γ-ray photons. Both codes have been coupled in order to simulate realistic explosions. The properties of γ-ray spectra and γ-ray light curves (for the continuum and for the lines at 511, 478 and 1275 keV) have been analysed, with a special emphasis on the difference between carbon–oxygen and oxygen–neon novae. Predictions of detectability of individual novae by the future SPI spectrometer on board the INTEGRAL satellite are made. Concerning ²⁶Al, its decay produces photons of 1809 keV but this occurs on a time-scale much longer than the typical time interval between nova outbursts in the Galaxy, making it undetectable in individual novae. The accumulated emission of ²⁶Al from many Galactic novae has not been modelled in this paper.     

I_a型超新星爆发理论(Ⅱ):理论研究中的重要疑难问题

介绍与评述了I_a型超新星理论研究中最为突出的8个尚未解决的重要疑难问题,并简单介绍了国内围绕SNI_a开展的某些物理探讨研究．     

A Study on the Abundance Distribution of Heavy Elements in Metal-poor Stars by the Parameterization Method

Based on a large amount of observed data of element abundances in metal-poor stars, taking the abundance distribution of heavy elements in the solar system as a standard, and selecting Sr, Ba and Eu as the typical elements of the three nucleosynthetic processes in metal-poor stars, namely the weak sprocess, main s-process and r-process, we have studied the contributions of the three kinds of neutron-capture processes to the abundance distribution of heavy elements in metal-poor stars, with the parameterization method. It is found that the higher the metal abundance, the greater the contributions of the weak s-process and the chief s-process to the abundances of lighter neutron-capture elements. The heavier neutron-capture elements are mainly produced by the r-process and the chief s-process; and that at low metallicity, the abundances of heavy neutron-capture elements are mainly produced by the r-process. In the early Galaxy, the weak s-process has almost no contribution to the element abundance.     

Stable Isotope and Element Geochemistry of Saline Springs in Evaporite-bearing Mengla Basin,South Yunnan,China

正1 Introduction Mengla Basin is a sub-basin in southern evaporitebearing Lanping-Simao Basin.There are many salt springs in the basin.In 2012,11 spring samples were collected for analyses of chemistry and boron,hydrogen and oxygen