臭氧及臭氧类高级氧化技术降解甲基对硫磷的效能

文章研究了臭氧及臭氧类高级氧化技术(AOPs-O3)在不同pH条件下降解甲基对硫磷(MP)的效能。结果表明,在pH 3~10的条件下(反应过程控制pH),单独臭氧化5min即可完全降解MP,但不同pH下化学耗氧量(COD)和有机磷的释放率差异明显。在pH为3.3,7.5和9.4的条件下单独臭氧30min后COD的去除率分别为55.17%,89.64%和93.10%,有机磷的释放率分别为16.33%,95.00%和99.99%。考虑酸性条件下可以规避碳酸盐的负面影响(特别是高浓度废水),利用O3/H2O2/Ti(IV)在pH 3.3条件下处理MP溶液,COD去除率和有机磷释放率分别达到89.64%和81.57%。相对法计算求得MP与O3和羟基自由基(·OH)的速率常数分别为31.98L·(mol·s)-1和7.488×109 L·(mol·s)-1。活性污泥法的测试结果表明,MP经O3/Ti(IV)/H2O2(pH=3.3)和O3(pH=9.4)可提升含MP废水的可生化性,但与培养液体系相比仍具有一定的毒性。     

活动构造研究中相关速率的原地宇宙成因核素年代学约束

活动构造研究中获得的相关速率是解释活动构造运动方式和幅度的重要基础,同时也能够提供检验和建立有关运动学和动力学模型的必要参数。原地宇宙成因核素年代学是近几十年来随着加速质谱的出现而逐渐发展并不断广泛应用于地学,特别是地表过程以及活动构造研究中来的。由于仪器测试费用高以及处理流程比较复杂,国内早期相关研究没有得以广泛开展,然而目前正呈现逐渐升温的趋势。在样品采集以及精细野外地质调查测量的基础上,活动构造研究中的活动断裂运动速率,活动构造区的河流水系侵蚀下切速率以及古地震事件,活动火山喷发事件等均可以通过原地宇宙成因核素年代学定量约束。文中在概述原地宇宙成因核素年代学基本原理的基础上,总结了国内外有关该年代学在活动构造研究应用中的最新成果和资料,重点介绍了基于原地宇宙成因核素年代学方法获取和解释活动构造研究中相关速率的成果     

孔隙压变化对岩石错动面滑动行为影响的实验研究

应用摩擦实验装置，在法向压力σ＿ｎ＝１０～１２０ＭＰａ下研究了孔隙压变化速率对岩石错动面滑动行为的影响。当孔隙压增压速率较大时，具粘滑振荡特性的岩石错动面仍将发生粘滑振荡，当孔隙压增压速率较小时，错动面发生稳定滑动，当增压速率介于上述两者之间时，错动面则呈粘滑－稳滑转化。以上结果对地震前兆和地震控制研究有重要意义     

地下水位升降对某场地地基土承载力的影响

通过工程实例，分析了对比地下水位升降对地基土的物理力学性质的影响，定量地总结了地下水位上升对地基土承载力的削弱情况。     

Integer estimation in the presence of biases

 Carrier phase ambiguity resolution is the key to fast and high-precision GNSS (Global Navigation Satellite System) kinematic positioning. Critical in the application of ambiguity resolution is the quality of the computed integer ambiguities. Unsuccessful ambiguity resolution, when passed unnoticed, will too often lead to unacceptable errors in the positioning results. Very high success rates are therefore required for ambiguity resolution to be reliable. Biases which are unaccounted for will lower the success rate and thus increase the chance of unsuccessful ambiguity resolution. The performance of integer ambiguity estimation in the presence of such biases is studied. Particular attention is given to integer rounding, integer bootstrapping and integer least squares. Lower and upper bounds, as well as an exact and easy-to-compute formula for the bias-affected success rate, are presented. These results will enable the evaluation of the bias robustness of ambiguity resolution. Received: 28 September 2000 / Accepted: 29 March 2001     

同仁双朋西金矿浮选尾矿中提铜扩大试验的研究

在小试的工艺基础上 ,对双朋西金矿浮选后的尾矿进行铜、金回收扩大试验。对铜的浸取试验结果表明 ,本工艺对该尾矿具有较高的铜浸取率和回收率     

不同林龄抑螺防病林林分内钉螺种群分布特点的研究——以安庆市大观区沿江滩地为例

对安庆沿江滩地杨树林地、江滩草地、芦苇丛等5个植被类型区的钉螺分布状况进行了调查,研究了不同植被类型区钉螺的形态指标和阳性率。结果表明:①成熟杨树林地、中龄杨树林地均无钉螺分布;杨树幼林地、江滩草地、芦苇丛螺口密度分别为4只/0.11m2、5只/0.11m2、7只/0.11m2。②杨树幼林地、江滩草地、芦苇丛所获钉螺样本的阴阳性检测,没有被血吸虫感染,均为阴性。③江滩营造抑螺防病林是改变钉螺孳生环境及人工控制钉螺种群密度的最有效途径之一。     

2020年新疆于田MS6.4地震前地磁谐波振幅比变化特征分析

以2020年6月26日于田M_S6.4地震为例, 采用地磁谐波振幅比法, 选用距震中370 km和360 km范围内的且末台、 狮泉河台所记录到的秒值连续波形数据, 对震前地磁异常进行了提取和回溯性分析, 发现地磁谐波振幅比反映了观测点深部电阻率变化, 2020年于田M_S6.4地震前且末台和狮泉河台地磁谐波振幅比出现了较明显的异常现象。 异常特征有: ① 地磁谐波振幅比Y_ZHx和Y_ZHy主要表现为“下降—转折—恢复”的形态, 地震发生在下降型变化恢复之后上升阶段; ② 震前约2年起, 且末台和狮泉河台谐波振幅比表现长短周期变化不同步或NS向与EW向变化不同步的现象; ③ 且末台Y_ZHx(NS)和狮泉河台Y_ZHy(EW)谐波振幅比异常变化中的转折上升形态具有自较长周期向较短周期的迁移现象; ④ 狮泉河台谐波振幅比趋势性异常起始时间早于且末台, 持续时间平均2年左右, 最大异常幅度达到0.04; ⑤ 且末台Y_ZHx(NS)和狮泉河台Y_ZHy(EW)异常相比对应其他分量更为显著, 这也许震中和台站所在位置有关系; ⑥ 地震前和田大地电场(距震中约265 km)岩体裂隙优势方位角(α)也显示异常变化, 可见该地震前多地球物理探测参量的异常响应, 呈现多地球物理量耦合, 增加了异常可信度。     

Inter- and intra-annual trend analysis of water level and flow in the middle and lower reaches of the Ganjiang River,China

ABSTRACT

The Ganjiang River is the largest tributary of Poyang Lake in China, and its hydrological regime variation greatly affects the utilization of regional water resources and the ecological environment of the lake. In this study, a novel trend analysis method, the Moving Average over Shifting Horizon (MASH), was applied to investigate the inter- and intra-annual trends of flow and water level from 1976 to 2016 at the Xiajiang and the Waizhou hydrological stations in the Ganjiang River. The Significant Change Rate Method (SCRM) was proposed to determine the MASH averaging parameters. The trend analysis results show a statistically significant decrease in water level series throughout the year and the relationship of flow and water level have changed greatly at the Waizhou station. The sediment load reduction, large-scale sand mining and water level decrease of Poyang Lake are identified as the main causes for the water level decrease.     

Chromium(VI) reduction by sulphur(IV) in aqueous solutions

The rates of the reduction of Cr(VI) with S(IV) were measured in deaerated NaCl solution as a function of pH, temperature and ionic strength. The rates of the reaction were found to be first order with respect to Cr(VI) and second order with respect to S(IV), in agreement with previous results obtained at concentrations two order higher than the present study. The reaction also showed a first-order dependence of the rates on the concentration of the proton and a small influence of temperature with an apparent energy of activation ΔH_app of 22.8 ± 3.4 kJ/mol. The rates were independent of ionic strength from 0.01 to 1 M. The rate of Cr(VI) reduction is described by the general expression

−d[Cr(VI)]/dt=k[Cr(VI)][S(IV)]²