CH4-H2O体系流体包裹体拉曼光谱定量分析和计算方法

CH4—H2O体系流体包裹体研究对含油气盆地流体分析和成矿流体研究都有重要的意义。本文详细介绍了H2O、CH4和CH4—H2O体系的拉曼光谱特征及分子作用,分析了CH4—H2O体系热力学特征,同时对CH4—H2O体系流体包裹体拉曼光谱定量分析和计算的方法及步骤进行了叙述。利用人工合成流体包裹体建立甲烷浓度与拉曼特征峰面积比值之间的校正曲线是实现CH4—H2O体系流体包裹体定量分析的基础。盐度对包裹体定量分析的影响最为显著,在恒定甲烷浓度下,甲烷与水的拉曼峰面积比值随着盐度增加而减少。对于流体包裹体封闭体系,随温度升高,液相甲烷浓度增大。校正曲线必须包含对温度和盐度的校正。石英主矿物性质和方位对甲烷浓度定量分析的影响可以忽略。实验研究表明,原位拉曼光谱技术是准确获取流体包裹体中甲烷水合物生成条件的一种有效方法。因此,基于拉曼光谱分析和显微测温分析结果,采用热力学模型可以定量计算CH4—H2O体系流体包裹体的相关参数。     

具有二次服务、反馈、启动故障的M/G/1重试排队系统

考虑了一个具有二次服务、反馈和启动故障的M/G/1重试排队系统.在假定重试区域中只有队首的顾客允许重试的情况下,重试时间具有一般分布时,得到了系统稳态的充分必要条件.求得稳态时系统队长和重试区域中队长分布及相关指标.     

利用高频雷达海面回波中奇异峰估计浪高的方法

The popular methods to estimate wave height with high-frequency(HF) radar depend on the integration over the second-order spectral region and thus may come under from even not strong external interference. To improve the accuracy and increase the valid detection range of the wave height measurement, particularly by the smallaperture radar, it is turned to singular peaks which often exceed the power of other frequency components. The power of three kinds of singular peaks, i.e., those around ±1,±2~(1/2) and ±1(2~(1/2)) times the Bragg frequency, are retrieved from a one-month-long radar data set collected by an ocean state monitoring and analyzing radar,model S(OSMAR-S), and in situ buoy records are used to make some comparisons. The power response to a wave height is found to be described with a new model quite well, by which obvious improvement on the wave height estimation is achieved. With the buoy measurements as reference, a correlation coefficient is increased to 0.90 and a root mean square error(RMSE) is decreased to 0.35 m at the range of 7.5 km compared with the results by the second-order method. The further analysis of the fitting performance across range suggests that the peak has the best fit and maintains a good performance as far as 40 km. The correlation coefficient is 0.78 and the RMSE is 0.62 m at 40 km. These results show the effectiveness of the new empirical method, which opens a new way for the wave height estimation with the HF radar.     

鱼类在海洋碳循环中的作用及研究展望

碳中和是应对气候变化的必由之路,海洋负排放是实现碳中和的重要途经。海洋作为地球最大碳库,研究发现越来越多的海洋和海岸带生物参与碳循环,并对海洋碳汇产生重要贡献。鱼类作为海洋生态系统中最重要组成部分之一,其在海洋碳循环中的作用还没有引起足够的重视。最新研究表明海洋鱼类在无机碳循环中发挥了重要作用,深化对鱼类参与碳循环过程的认识、量化其固碳潜力将有助于丰富海洋碳循环研究。本文首先系统梳理了鱼类参与碳循环的过程和机制等研究进展。鱼类通过产生碳酸盐粪便、水平和垂直迁移运输、生物扰动、生物碳和“尸体”碳以及食物网消耗与传输等方式参与海洋碳循环。鱼类参与碳循环的证据和参与海洋碳循环的重要性逐渐凸显。其次,本文提出目前鱼类参与碳循环研究存在的问题与挑战,包括渔业捕捞源汇之争、水产养殖业的机遇和挑战以及准确量化鱼源碳酸盐的困难,仍有待理论和方法学的深化研究和技术的革新去解决。最后本文提出鱼类参与碳循环的研究展望,及其在全球气候变化背景下的潜在机遇,同时结合当前渔业碳汇的发展进程以及行业需求,提出渔业减排固碳发展路径建议。本文旨在提升鱼类在海洋碳循环贡献和服务生态系统的潜力的认识,为海洋碳汇和渔业碳汇研究提供新的视角。     

全球海岸带国家蓝碳资源价值与类型研究

海岸带蓝碳生态系统已成为应对气候变化重要的基于自然的解决方案。本研究梳理了全球海岸带蓝碳生态系统的分布、碳封存量和封存价值,并根据经济、科技、蓝碳封存量三个指标对各海岸带国家和地区进行分类。海岸带蓝碳生态系统分布最广的国家是澳大利亚、印度尼西亚、墨西哥和美国,而印度尼西亚、澳大利亚、马来西亚和巴西碳埋藏量最高。全球每年蓝碳埋藏价值在碳交易和碳税价格下分别为3.47×109美元和2.35×109美元。中国拥有丰富的海岸带蓝碳资源,生态系统面积排名第10,年封存量排名第21;然而蓝碳自然资源的赋存禀赋与现有碳价格体系下的价值匹配性较差,基于碳交易价格的中国海岸带蓝碳埋藏价值全球排名第27,基于碳税价格仅排名第39。碳价格低迷将会导致在国际蓝碳交易中处于劣势,中国后续应不断完善碳排放交易市场。中国具有在蓝碳研究以及修复投入与实践方面的优势,以及贝藻养殖、海洋牧场等特色蓝碳资源,可结合不同类型的蓝碳国家经济科技条件与自然条件制定多元合作策略。     

A SIMPLIFIED METHOD FOR PREDICTION OF KINEMATIC SOIL–FOUNDATION INTERACTION EFFECTS ON PEAK HORIZONTAL ACCELERATION OF A RIGID FOUNDATION

The kinematic soil–foundation interaction changes the free field ground motion to a different motion at the foundation of a structure. This interaction effect may be expressed by the ratio of the peak horizontal acceleration of a rigid and relatively lightweight foundation to the peak horizontal acceleration at the ground surface in the free field. It is found that the interaction effect can be defined by a simple function of the ratio of the peak horizontal ground velocity and ground acceleration in the free field, the length of the foundation and the shear wave velocity in the soil. Predictive equations for the kinematic soil foundation effect are derived using 350 strong motion records generated by 114 earthquakes world-wide. At the same time, an attenuation relationship is derived for the ratio of the peak horizontal ground velocity and acceleration from the same set of data. Ten case histories are studied; the interaction effects are calculated by using the predictive equations and then compared with measured field values. The results of the comparison illustrate the degree of predictive capability of the method when the foundation mass and the inertial soil–foundation interaction are not considered.     

秦皇岛市工程场地地面运动峰值加速度预测

工程场地地面运动峰值加速度是强震区城市发展规划、抗震防灾的重要依据,也是工程建筑抗震设计的基本参数。本文在研究秦皇岛市区域地震地质环境和地震活动规律的基础上,确定了区域潜在震源区及相应的地震活动性参数。将该市工程场地划分为规则网格,采用地震危险性分析的概率方法,计算出各场地在各不同年限内所遭受到的不同地震危险性概率水平。最后,编制出了供一般工业与民用建筑设计使用的,按50年10％给定概率水平的秦皇岛市地面运动加速度预测图。