水泥聚苯模壳格构式混凝土墙体抗震性能的芯孔尺寸影响试验研究

为研究芯孔尺寸对传统型水泥聚苯模壳(EPSC)格构式混凝土墙体抗震性能的影响,对2个传统型EPSC格构式混凝土墙体原型试件进行低周往复荷载试验,2个试件芯孔直径分别为160 mm和120 mm;对比分析了2个试件的破坏特征和承载力、滞回曲线、骨架曲线、刚度退化等抗震性能。结果表明:芯孔直径大的复合墙体具有更优良的抗震性能;芯孔直径增加,复合墙体的承载力、抗侧刚度和耗能能力均有不同程度的提高。     

The Role of Seal and Source Rocks in Fluid-rock Interactions and their Reservoir Effects within the Carbonate Deep Burial Realm

Discoveries of deep high-quality carbonate reservoirs challenged the general understanding on the evolution of porosity decreasing with depth. New mechanisms of pore generation and preservation in the deep realm require to be proposed. Dolostones in the Feixianguan and Dengying Formations experienced maximum depths in excess of 8000 m, but still retained high porosity. Petrographic observation and homogenization temperatures help to identify products of deep fluid-rock interactions, visual and experimental porosity were used to quantify reservoir effects, the distribution of products finally being plotted to unravel the mechanisms. Th data reveal that thermochemical sulfate reduction (TSR), burial dissolution and quartz cementation are typical deep fluid-rock interactions. The SO42? of residual porewater sourced from the evaporative dolomitizing fluid was supplied for TSR in the hydrocarbon column, the TSR-inducing calcite cements were homogeneously dispersed in the hydrocarbon column. Quartz cementation was caused by the increasing acidity and Si-rich residual porewater in the oil column. Burial dissolution is forced by organic acid and limited in oil–water contact. This study suggests that seal and source rocks not only play important roles in hydrocarbon accumulation, but also have a general control on the deep fluid-rock interactions and porosity evolution in the deep burial realm.     

Distribution Patterns of Calcite Cement in the Turbidite Sandstones of the Shahejie Formation in the Dongying Depression, Eastern China

Calcite cements are volumetrically dominant among the most diagenetic constituents in turbidite sandstones of the Paleogene Shahejie Formation in the Dongying Depression. The results show carbonate cements mainly occur in three phases: Calcite I (pre-compaction), Calcite II (post-compaction) and ankerite in the turbidite sandstone. The isotopic composition of Calcite I and Calcite II range from ?4.3‰ to 4.4‰, ?3.5‰ to 4.3‰ PDB, respectively, suggesting that the calcite cements are mainly derived from the interbedded shales. The early calcite cement precipitated from the mixing of lacustrine and meteoric waters at 38–69°C. The late-phase calcite precipitated from pore waters modified by water-rock interactions at 64–126°C. Two distribution patterns of calcite cements can be identified, depending on their position within the sandstone. The peripheral cementation of the sandstones is near the sand-shale contact. The development of cement is controlled by sandstone thickness and the properties of the interbedded shale. For scattered cementation, the distribution of the calcite cement is not controlled by the sand-shale contact. Calcite cement was preferentially distributed in coarse-grained sandstones, indicating that sandstones with high original permeability are the preferred pathway for the migration of early diagenetic fluids.     

Variations in the sensitivity of the optically stimulated luminescence from quartz in the Xifeng section: A spatiotemporal comparison across the Chinese Loess Plateau since the last interglaciation

The sensitivity of the optically stimulated luminescence (OSL) from quartz is thought to be mainly influenced by source rock (crystallization temperature and quartz defect types) and depositional history (irradiation/bleaching cycles). In this study, the OSL sensitivity of quartz of different grain sizes from loess (L1) and paleosol (S1) layers at the Xifeng section of the Chinese Loess Plateau was analyzed. The OSL sensitivity of the samples from the Xifeng section shows a distinct difference between glacial and interglacial cycles, which is consistent with the patterns observed from magnetic susceptibility (MS) and grain sizes. The highest OSL sensitivity is observed in S1, which is twelve times the lowest sensitivity observed in L1. Moreover, the contribution of the fast component of quartz OSL from the paleosol accounts for more than 90% of the total OSL signal. In contrast, the middle and slow components contribute more in loess, and a significant variation among different aliquots was observed.Comparison of the data obtained from loess sections from different regions, including Xifeng, Luochuan, Jingyuan and Shimao, show significant differences in the magnitudes of OSL sensitivity but a similar pattern between glacial and interglacial periods. The results of this study suggest that, except for the wildfire model proposed to interpret the high OSL sensitivity in paleosol (Zhang, 2018), the shift of wind pattern of westerly wind (i.e., transporting “dim” source from North Tibetan Plateau and northwesterly wind (i.e., transporting “bright” source from Alxa Arid Lands and the subsequent mixture from the different sources may partially contribute to the different OSL sensitivities observed for Xifeng and Luochuan. In contrast, the OSL sensitivity of Shimao samples from L1 was affected by the input from the Mu Us Desert, and those of Jingyuan may affected by the contribution from the Yellow River.     

Luminescence and ESR dating of the sedimentary infill from the multi-level cave system of Alkerdi-Zelaieta (Navarre,N Spain)

The finding of Upper Paleolithic engravings in 2016 triggered a multidisciplinary investigation of the Alkerdi cave system (Urdazubi, N Spain). The study of the speleogenetic processes led to the identification of at least 6 paragenetic cave levels with associated sedimentary infill. In order to unravel the timing of changes in the karst dynamics and to get some insights about sediment origin, two sediment samples were collected from cave levels 4 and 1 for numerical dating purpose, using both Optically Stimulated Luminescence (OSL) and Electron Spin Resonance (ESR) methods. One additional modern-age sample was also taken from the entrance of the karst to evaluate the magnitude of the optical bleaching achieved by the quartz grains before entering the cave system. Last, one sample was collected from a flowstone for U-series dating, providing independent age control.OSL measurements were carried out using small quartz multi-grain (MG) and single-grain (SG) Single Aliquot Regenerative-dose (SAR) protocol. Initial Equivalent Dose (D_e) results show evidence of saturated OSL signal for the sample of the higher level (with ∼60% of saturated aliquots). Unlike SA data, SG analyses do not meet the usual quality criteria (e.g., relatively high recuperation ratios, only a few grains with useable signal), suggesting that corresponding dating results should be treated with caution.Hence, both MG and SG TT-OSL and MG ESR methods were subsequently employed, as the corresponding signals are known to have higher saturation levels than OSL ones. ESR analyses were based on the Multiple Centre (MC) approach using the standard multi-grain multi-aliquot additive (MAA) dose method, while TT-OSL measurements were performed following Demuro et al. (2020). The latter, however, did not return any useful results for both samples. MC ESR data show the usual D_e pattern (D_e(Al)>D_e(Ti op. D)>D_e(Ti–H)) indicating that among the three ESR signals analyzed, the Ti–H most likely provides the closest estimate to the true burial age. However, low measurement repeatability and goodness-of-of fit indicate that the reliability of the ESR results may be reasonably questioned.Results derived from this multi-technique dating approach provide the first chronological constraints for the sedimentary infill of the Alkerdi cave system. In particular, they suggest that sediment deposition in Cave Level 4 (ALK-OSL01) occurred around 130 ka, which is in good agreement with the minimum age constraint given by the speleothem (80.5 ± 9.0 ka). In comparison, the young age obtained for sample ALK-OSL02 (5.0 ± 0.9 ka) suggests recent Holocene formation of the lowest cave level 1.Finally, the MG De value obtained for the modern sample is close to zero (<1 Gy), indicating that the OSL signal is almost fully reset at a multi-grain level before entering the cave. Additionally, despite the large De overdispersion measured in this modern sample, the De values are one to two order of magnitude lower than those obtained with the same model in the other two samples. Therefore, the large OSL D_e overdispersion (OD) values of up to 64% obtained for the two samples from Cave Level 4 and 1 are most likely related to re-sedimentation processes inside the cave system.     

Revisiting natural and laboratory electron spin resonance (ESR) dose response curves of quartz from Chinese loess

Natural and laboratory ESR dose response curves (DRCs) of [AlO₄/h]⁰ and [TiO₄/M⁺]⁰ were investigated for samples of quartz from the Luochuan loess-palaeosol master section, Chinese Loess Plateau. The natural and laboratory DRCs show a clear divergence above ∼1000 Gy, with much lower D₀ values and saturation levels observed for the natural DRCs, which is in agreement with the previous study by Tsukamoto et al. (2018). Young (<15 ka) samples from Luochuan and Jingbian – another site of the Chinese Loess Plateau, together with two modern samples of Chinese loess, were used to investigate the residual signals of [AlO₄/h]⁰ and [TiO₄/M⁺]⁰ centres. Our results are in line with published studies and show that the significant residual signals corresponding to several tens to hundreds of Gy are present in both Al and Ti centres. These need to be taken into account before laboratory DRC construction. ESR pulse annealing experiments performed on samples irradiated with different doses show an apparent dose-dependent thermal instability of [AlO₄/h]⁰ and [TiO₄/M⁺]⁰, with the signals for higher doses decaying faster with increasing temperature. We attribute the change in D₀ with preheat reported in Tsukamoto et al.2018, as well as the difference between laboratory and natural DRCs, to this apparent dose-dependent thermal instability of the signals. The saturation level of the natural DRC, being the result of reaching the equilibrium between filling of the traps and emptying them due to thermal decay, is therefore additionally affected at higher doses, due to the increased thermal instability. The inability to recreate in the laboratory the same response to irradiation as the one observed in nature questions the accuracy of dating samples beyond ∼1000 Gy.     

山西干热岩GR1井高温固井技术研究与实践

固井质量对干热岩后期开发利用具有重要意义。针对山西大同盆地干热岩勘查井GR1井温度高、高温固井水泥浆技术体系不完善等问题,通过研究勘查区地质特征,提出了高温固井水泥浆技术体系开发思路。研究表明：干热岩高温固井水泥浆水胶比控制为0.45,优选添加剂高温降失水剂CG82L、高温缓凝剂H40L、高温稳定剂CF40L、消泡剂GX-1、硅粉及HV-PAC,形成一套适用于山西干热岩井的高温固井水泥浆技术体系。该水泥浆体系在GR1井成功应用,现场固井质量良好,研究成果为今后同类型高温固井工作提供了宝贵经验和技术支撑。     

红层泥质胶结物干缩裂缝深度与间距预测模型

红层泥质胶结物在干燥条件下会因含水率变化产生开裂,裂缝进一步发展贯通最终导致红层泥岩崩解破坏。目前对红层泥岩崩解机制的研究多为定性描述,缺乏定量分析方法。因此,定量研究红层泥质胶结物开裂的产生及扩展对深化红层泥岩崩解理论研究具有重要意义。基于线弹性断裂力学及非饱和土力学,建立了考虑含水率变化的红层泥质胶结物裂缝深度及间距计算公式,并对公式参数敏感性进行了分析。应用CT试验数据对PFC2D数值模型进行了校准,并基于干缩开裂数值试验结果,对裂缝深度及间距计算公式进行了对比验证。结果表明：提出的计算公式能较好地预测红层泥质胶结物的开裂深度及间距,裂缝深度随含水率减小呈先快速增加再缓慢增长的特点。研究成果有助于加深对红层泥岩崩解的量化理论分析,并为预测工程中红层泥岩的开裂程度提供参考。     

水泥偏高岭土复合稳定粉砂土渗透特性试验研究

水泥稳定粉砂土抗渗性能受粉砂土自身渗透性能、水泥用量、水灰比等因素影响显著,如何在提升其抗渗性能的同时降低水泥用量是提升工程经济效益的关键。通过开展不同水泥偏高岭土掺比、初始用水量、水泥偏高岭土总掺量以及养护龄期条件下的室内渗透试验,研究了上述因素对水泥偏高岭土复合稳定粉砂土抗渗性能的影响规律,探讨了上述因素及无侧限抗压强度与渗透系数之间的经验关系。结果表明：水泥与偏高岭土掺比为5:1时,水泥偏高岭土复合稳定粉砂土抗渗性能最佳,且该掺比不随水泥偏高岭土总掺量的改变而变化;水泥偏高岭土复合稳定粉砂土渗透系数随初始用水量增加呈非线性递增,随水泥偏高岭土总掺量增加和养护龄期发展呈先快后慢降低;基于试验结果归纳提出了4个关于初始用水量、水泥偏高岭土总掺量、养护龄期和无侧限抗压强度的水泥偏高岭土复合稳定粉砂土渗透系数经验模型。研究成果可为水泥稳定粉砂土抗渗性能提升提供理论参考与借鉴。