High-precision analysis of carbon isotopic composition for individual CO2 inclusions via Raman spectroscopy to reveal the multiple-stages evolution of CO2- bearing fluids and melts

The carbon isotopic composition of CO₂ inclusions trapped in minerals reflects the origin and evolution of CO₂-bearing fluids and melts, and records the multiple-stages carbon geodynamic cycle, as CO₂ took part in various geological processes widely. However, the practical method for determination isotope composition of individual CO₂ inclusion is still lacking. Developing a microanalytical technique with spatial resolution in micrometers to precisely determinate the δ¹³C value of individual CO₂ inclusion, will make it possible to analyze a tiny portion of a zoning mineral crystal, distinguish the differences in micro-scale, and possible to find many useful information that could not be obtained with the bulk extraction and analysis techniques. In this study, we systematically collected Raman spectra of CO₂ standards with different δ¹³C values (?34.9 ‰ to 3.58 ‰) at 32.0 °C and from ～7.0 MPa to 120.0 MPa, and developed a new procedure to precisely determinate the δ¹³C value of individual CO₂ inclusion. We investigated the relationship among the Raman peak intensity ratio, δ¹³C value, and CO₂ density, and established a calibration model with high accuracy (0.5 ‰?1.5 ‰), sufficient for geological application to distinguish different source of CO₂ with varying δ¹³CO₂. As a demonstration, we measured the δ¹³C values and the density of CO₂ inclusions in the growth zones of alkali basalt-hosted corundum megacrysts from Changle, Shandong Province. We found the significant differences of density and δ¹³C between the CO₂ inclusions in the core of corundum and those inclusions in the outer growth zones, the δ¹³C value decreases from core to rim with decreasing density: δ¹³C values are from ?7.5 ‰ to ?9.2 ‰ for the inclusions in the core, indicating the corundum core was crystallized from mantle-derived magmas; from ?13.5 ‰ to ?18.5 ‰ for CO₂ inclusions in zone 1 and from ?16.5 ‰ to –22.0 ‰ for inclusions in zone 2, indicating the outer zones of corundum grew in a low δ¹³C value environment, resulted from an infilling of low δ¹³C value fluid and/or degassing of the ascending basaltic magma.     

随机Petri网在地震应急协同能力定量评价与动态分析中的应用

地震应急是一个复杂动态的过程,需要各部门协同配合方能高效开展应急工作。本文通过调研分析历史地震应急处置案例,提出了Ⅰ、Ⅱ级应急响应下多主体地震应急协同的一般流程,构建了相应的随机Petri网模型,并基于Petri网可能出现的状态集同构马尔科夫链,在计算各应急状态稳定概率的基础上,定量评价应急协同能力。同时,将应急过程中利用率高的变迁所对应的应急行为,作为应急处置的关键环节。通过调整各关键环节的应急速率,进一步对应急协同能力进行动态分析,进而提出有效提高应急协同联动能力的相关建议,为科学开展地震应急处置工作提供支持。     

Origin and quantitative source assessment of deep oils in the Tazhong Uplift,Tarim Basin

A large amount of deep oil has been discovered in the Tazhong Uplift, Tarim Basin whereas the oil source is still controversial. An integrated geochemical approach was utilized to unravel the characteristics, origin and alteration of the deep oils. This study showed that the Lower Cambrian oil from well ZS1C (

_1x) was featured by small or trace amounts of biomarkers, unusually high concentration of dibenzothiophenes (DBTs), high δ³⁴S of DBTs and high δ¹³C value of n-alkanes. These suggest a close genetic relationship with the Cambrian source rocks and TSR alteration. On the contrary, the Middle Cambrian oils from well ZS1 (

_2a) were characterized by low δ¹³C of n-alkanes and relatively high δ³⁴S of individual sulfur compounds and a general “V” shape of steranes, indicating a good genetic affinity with the Middle–Upper Ordovician source rocks. The middle Cambrian salt rock separating the oils was suggested to be one of the factors responsible for the differentiation. It was suggested that most of the deep oils in the Tazhong Uplift were mixed source based on biomarkers and carbon isotope, which contain TSR altered oil in varied degree. The percentage of the oils contributed by the Cambrian–Lower Ordovician was in the range of 19–100% (average 57%) controlled by several geological and geochemical events. Significant variations in the δ³⁴S values for individual compounds in the oils were observed suggesting a combination of different extent of TSR and thermal maturation alterations. The unusually high DBTs concentrations in the Tazhong-4 oilfield suggested as a result of mixing with the ZS1C oil (

_1x) and Lower Ordovician oils based on δ³⁴S values of DBT. This study will enhance our understanding of both deep and shallow oil sources in the Tazhong Uplift and clarify the formation mechanisms of the unusually high DBTs oils in the region.     

Clean development mechanism: leverage for development?

Abstract

The objective of this paper is to show that the investments through the clean development mechanism (CDM) can exert a leverage effect to (i) make attractive to developing countries non-binding commitments and the adoption of national policies and measures; this comes as a guarantee of non-conditionally of the mechanism to strictly environmental concerns and (ii) create a flow of additional investments and technological transfer from Annex B countries to non-Annex B countries.

The Indian power sector has been chosen as an example of a sector where institutional barriers, market imperfections, and tariff distortions create a great space for Pareto improvements and leave an important potential for no-regret measures: technological transfer, air conditioned systems, transport infrastructures and removal of subsidies on consumption.

This paper presents a micro-economic formalisation on (i) the evolution of profitability of current emitting technologies used in the power sector under the adoption of national policies and measures and (ii) the impact on renewable energy technologies competitiveness of emission credits in the context of CDM. This formalisation has been developed to enable quantitative simulation. A first exercise using the Markal model (used in 77 countries) on the electric sector in India enabled us to simulate the leverage effect of emission credits on additional incomes taken as a proxy for development.     

THE FREE-WILSON PARADIGM REDUX:SIGNIFICANCE OF THE FREE-WILSON COEFFICIENTS,INSIGNIFICANCE OF COEFFICIENT ‘UNCERTAINTIES’ AND STATISTICAL SINS

The Free-Wilson paradigm is an established and powerful tool for quantitatively relating activity withchemical structure.Current implementations of the paradigm,however,are flawed both conceptually andin execution.As part of an attempt to more fully realize the promise of the paradigm,it was necessaryto examine these limitations in detail.This report introduces a robust,theory-founded Free-Wilson implementation:stepwise principalcomponents regression analysis(SPCRA).SPCRA is computationally superior to previousimplementations but does not in itself correct their conceptual flaws.The development of SPCRA did,however,facilitate derivation of a simple and chemically significantinterpretation of the Free-Wilson structure-activity model.A number of statistical aspects of this modelcommonly misused in previous applications are discussed at length.These discussions provide criticalbackground for the development of an alternative implementation of the Free-Wilson paradigm.     

叶面积指数的快速测定方法——植被定量遥感的地面标定技术

本文论述了用“底视法”测量叶面积指数的基本原理,并在中国科学院禹城综合试验站遥感试验场以“冠层分析仪”对该方法进行了试验,提出了刺柏针叶叶面积指数的新估算方法。通过计算证明,测定值和估算值具有较好的一致性。这种以“底视法”为基础的冠层分析仪可以用于植被定量遥感的快速地面定标。     

小尺度断层定量预测及对注水开发的影响——以渤中34油田为例

大尺度断层往往控制了沉积盆地的形成和油气成藏,而小尺度断层则影响着注水开发效果和剩余油分布.大尺度断层可以通过二维或三维地震资料识别,而小尺度断层的识别则特别困难.本文提出了一种基于断层分形生长模式和三维地质力学模拟相结合来确定小尺度断层的数量、发育位置和方位的方法,并根据油田开发动态资料来确定小尺度断层对注水开发和剩余油分布的影响.将地震上识别的大尺度断层引入到三维数值力学模型中,模拟大尺度断层形成时期断裂带附近的应力扰动作用,然后结合破裂准则来建立最易发生破裂的方位和最大库伦剪切应力网格,以这两套网格和断层尺度的幂律分布确定的小尺度断层数量为约束条件来确定随机模型,对小尺度断层的密度、产状和发育位置进行定量预测.研究表明:利用分形理论和三维地质力学模拟可以对大尺度断层伴生小尺度断层进行有效预测;小尺度断层对注水开发效果和剩余油分布的影响取决于小尺度断层的规模(断距)以及小尺度断层方位和注采方向的关系.     

图形分形理论在沙漠化定量研究中的应用

以Mandelbrot的分形理论为基础,较详细地推算了图形面积与周长的分数维公式,并以农牧交错带典型沙漠化区内蒙古奈曼旗尧勒甸子村沙区土壤图为例,对沙漠化的现状及发展趋势进行了分数维分析,得到了较好的效果,认为该理论在沙漠化定量研究中具有很大的应用潜力。     

太平洋CC区沉积物陆源物质时空分布与大气环流的关系

在玉平洋ＣＣ区沉积物陆源组分定量分离基础之上,研究陆源物质时空分布规律与大气环流的关系。     

ETM+(TM)蚀变遥感异常提取方法研究与应用——方法选择和技术流程

从原理、模型试验及实际数据处理等方面分析对比了比值法、光谱角法及主分量分析法的优劣;选择了以主分量分析为主、光谱角法为辅进行蚀变遥感异常的提取;引用了误差理论某些基本概念,以标准离差σ作为遥感异常切割的尺度;建立了"去干扰异常主分量门限化技术流程"。以西藏驱龙—甲马蚀变遥感异常群为例,展示了此技术的效果,并与高光谱研究结果进行了比较。