Structural and vibrational behaviour of fluorapatite with pressure. Part I: in situ single-crystal X-ray diffraction investigation

Using single-crystal X-ray diffraction from a diamond anvil cell, the compressibility of a synthetic fluorapatite was determined up to about 7?GPa. The compression pattern was anisotropic, with greater change along a than c. Unit cell parameters varied linearly with β _a =3.32(8)?10^?3 and β _c =2.40(5)?10^?3 GPa^?1, giving a ratio β _a :β _c =1.38:1. Data fitted with a third-order Birch-Murnaghan EOS yielded a bulk modulus of K ₀=93(4)?GPa with K′=5.8(1.8). The evolution of the crystal structure of fluorapatite was analysed using data collected at room pressure, at 3.04 and 4.72?GPa. The bulk modulus of phosphate tetrahedron is about three times greater than the bulk modulus of calcium polyhedra. The values were 270(10), 100(4) and 86(3) GPa for P, Ca1 (nine-coordinated) and Ca2 (seven-coordinated) respectively. While the calcium polyhedra became more regular with pressure, the distortion of the phosphate tetrahedron remained unchanged. The size of the channel extending along the [001] direction represented the most compressible direction. The Ca2–Ca2 distance decreased from 3.982 to 3.897?Å on compression from 0.0001 to 4.72?GPa. The anisotropic compressional pattern may be understood in terms of the greater compressibility of the channel size over the polyhedral units. The reduction of the channel volume was measured by the evolution of the trigonal prism, having the Ca2–Ca2–Ca2 triangle as its base and the c lattice parameter as its height. This prism volume changed from 47.3?ų at room pressure to 44.78?ų at 4.72?GPa. Its relatively high bulk moduli, 86(3) GPa, indicated that the channel did not collapse with pressure and the apatite structure could remain stable at very high pressure.     

GPS工程控制网的若干特殊问题

根据ＧＰＳ定位技术的优点，讨论了建立ＧＰＳ工程控制网在踏勘、设计、观测及数据处理方面的若干特殊问题，并提出高精度工程控制网ＧＰＳ数据处理方案。     

SPECTRUM期间目标台风移动的数值试验

在目标台风Ｙａｎｃｙ的移动过程中，选择４个时段进行预报数值试验。模式初始场系根据ＳＰＥＣＴＲＵＭ和ＴＣＭ－９０加强观测资料确定。结果表明：实际大气中目标台风移动的若干特征在模式大气中能够显示出来，如Ｙａｎｃｙ在１９９０年８月２０日００时移向的转折现象等；台风非对称结构的低频振荡是产生移向转折现象的一个重要原因。     

菏泽5.9级地震前后水准测量与承压水变化关系的研究

利用深层承压水头观测结果,对东明——菏泽长水准测线8——9号测段的高差变化进行了回归计算和相关分析。认为菏泽市城区9号测点下沉的主要原因是受深层承压水头变化的影响。排除地下水影响因素后证实,1983年11月7日菏泽5.9级地震前后仅3mm左右的升降变化,表明9号测点对这次中强地震仅能反映微弱的形变信息量。     

Field compaction control studies on road bases in a new settlement area in Ghana

Summary Among the major causes for failure of roads in the tropics is inadequate compaction during construction. There is, therefore, the need to strictly control the compaction of the pavement layers if the design life of the road is to be attained; thereby eliminating large maintenance costs.This note reports on pavement compaction control studies undertaken on the road bases of service roads in a new settlement area in Ghana. These roads were to be provided with bituminous surfacing immediately after compaction. Studies concerning particle breakdown during field compaction by two contractors executing the works under the same conditions have been made, together with an assessment of contractor efficiency.It was found that the placement moisture contents varied greatly from the optimum. One contractor was compacting the gravels on the dry side of optimum, consequently achieving relatively high densities. The other contractor was compacting on the wet side and achieving lower density levels. This was still the case even after initial test sections were found to have been undercompacted.Compaction levels achieved in the crowns were generally found to be higher than those at the shoulders of the road test sections. The breakdown of coarse particles due to compaction was quite significant. There is therefore the need for highway material engineers to ensure that in addition to meeting the grading requirements, road base materials must adequately meet the requirements on weathering and mechanical strength properties.     

通过对调查数据的趋势和多变量分析确定宏观场

通过多变(相关分析)和趋势分析等统计方法对宏观调查数据进行了解释.这种方法使我们通过评定不同宏观效应叠加的程度、估计调查数据的不确定性更客观地评定烈度.通过滤波确定烈度场的区域分量,使我们消除观测中的局部变化.给出了选取适当滤波参数的准则.本文应用这一方法对发生在意大利的一次地震的调查数据进行了处理.     

兰州—天水地区三维重力反演及其地质解释

本文利用重力资料对兰州—天水地区的深部构造进行了研究。在计算中,采用Parker-Oldenbarg三维位场反演方法,反演前对重力资料进行了地形改正和中新生代沉积层校正。根据反演结果,综合分析了有关资料,认为该区为青藏块体过渡带,并且提出了陇中盆地为断块型构造盆地的新认识。     

高温高压下上地幔岩石电导率实验研究

为了建立具有普遍适用性的上地幔电性结构,本文利用Kawai-1000t压机和Solartron IS-1260阻抗/增益-相位分析仪,在4.0~14.0 GPa、873~1673 K的条件下,采用交流阻抗谱法（频率范围10^-1~10⁶Hz）测量了不含水的地幔岩电导率.实验结果显示,岩石的电导率随温度升高而大幅度的增大;在较大的温度范围内岩石的导电机制发生了变化,中低温时为小极化子导电,此时激活焓为0.94 eV （±0.13） eV,激活体积为0.11（±0.92） cm³·mol^-1,高温时为和镁空穴相关的离子导电,此时激活焓为1.6~3.17 eV,激活体积为6.75（±7.43） cm³·mol^-1;本次测量的电导率比低压下岩石的电导率要高,比矿物的电导率也要高.用本次的实验结果回归计算得到Fennoscandian地区的上地幔的一维电导率剖面,发现200 km以上本次实验计算的结果和大地电磁测深的电导率剖面吻合的比较好,在200 km以下本次实验得到的要比野外测量的电导率稍稍高一点,可能是因为实验过程中没有完全避免水的影响.本次的实验结果比用有效均匀介质方法计算得到的pyrolite矿物模型的电导率要高出两个数量级,这样的结果显示只用一种矿物的电导率或是几种矿物理论计算的结果有一定的不合理性.     

Evaluation of pre-CHAMP gravity models `GRIM5-S1' and `GRIM5-C1' with satellite crossover altimetry

 The new GFZ/GRGS gravity field models GRIM5-S1 and GRIM5-C1, currently used as initial models for the CHAMP mission, have been compared with other recent models (JGM 3, EGM 96) for radial orbit accuracy (by means of latitude lumped coefficients) in computations on altimetry satellite orbits. The bases for accuracy judgements are multi-year averages of crossover sea height differences from Geosat and ERS 1/2 missions. This radially sensitive data is fully independent of the data used to develop these gravity models. There is good agreement between the observed differences in all of the world's oceans and projections of the same errors from the scaled covariance matrix of their harmonic geopotential coefficients. It was found that the tentative scale factor of five for the formal standard deviations of the harmonic coefficients of the new GRIM fields is justified, i.e. the accuracy estimates, provided together with the GRIM geopotential coefficients, are realistic. Received: 20 February 2001 / Accepted: 24 October 2001     

Wavelet filter analysis of atmospheric pressure effects in the long-period seismic mode band

The importance of the reduction of atmospheric pressure effects becomes very clear when investigating seismic normal-mode spectra below 1.5 mHz. The usual simple correction method consists in subtracting a term converted from local atmospheric pressure (pressure multiplied by a frequency-independent admittance) from the gravity record in time domain. Thus, estimating an efficient admittance is the key for an improved correction. Band-pass filters derived from dyadic orthogonal wavelet transform, having narrow pass-bands with good frequency response but without Gibbs phenomenon and causing no phase lag, are very helpful to estimate an efficient admittance, which is both time and frequency-dependent. Processing of high quality superconducting gravimeter (SG) records for the great Sumatra earthquake (Mw = 9.3, Dec 26, 2004) with wavelet filters reveal the three very well resolved splitting singlets of overtone ₂S₁ with a single gravity record after correction with time-dependent and frequency-dependent admittances. We also observe all coupled toroidal modes below 1.5 mHz, except ₀T₅, ₀T₇ and ₁T₁, with good signal-to-noise ratio (SNR); moreover, toroidal modes ₁T₂ and ₁T₃ are for the first time unambiguously revealed in vertical components.