Arsenic accumulation in the roots of Helianthus annuus and Zea mays by irrigation with arsenic-rich groundwater: Insights from synchrotron X-ray fluorescence imaging

The aim of this study was to investigate the accumulation of arsenic (As) in and on roots of Zea mays (maize) and Helianthus annuus (sunflower) by means of synchrotron-based micro-focused X-ray fluorescence imaging (μ-XRF). Plant and soil samples were collected from two field sites in the Hetao Plain (Inner Mongolia, China) which have been regularly irrigated with As-rich groundwater. Detailed μ-XRF element distribution maps were generated at the Fluo-beamline of the Anka synchrotron facility (Karlsruhe Institute of Technology) to assess the spatial distribution of As in thin sections of plant roots and soil particles. The results showed that average As concentrations in the roots (14.5–27.4 mg kg⁻¹) covered a similar range as in the surrounding soil, but local maximum root As concentrations reached up to 424 mg kg⁻¹ (H. annuus) and 1280 mg kg⁻¹ (Z. mays), respectively. Importantly, the results revealed that As had mainly accumulated at the outer rhizodermis along with iron (Fe). We therefore conclude that thin crusts of Fe-(hydr)oxides cover the roots and act as an effective barrier to As, similar to the formation of Fe plaque in rice roots. In contrast to permanently flooded rice paddy fields, regular flood irrigation results in variable redox conditions within the silty and loamy soils at our study site and fosters the formation of Fe-(hydr)oxide plaque on the root surfaces.     

CFD modelling of a small–scale fixed multi–chamber OWC device

Wave Energy Converters (WECs) have excellent potential as a source of renewable energy that is yet to be commercially realised. Recent attention has focused on the installation of Oscillating Water Column (OWC) devices as a part of harbor walls to provide advantages of cost–sharing structures and proximity of power generation facilities to existing infrastructure. In this paper, an incompressible three–dimensional CFD model is constructed to simulate a fixed Multi–Chamber OWC (MC–OWC) device. The CFD model is validated; the simulation results are found to be in good agreement with experimental results obtained from a scale physical model tested in a wave tank. The validated CFD model is then used for a benchmark study of 96 numerical tests. These investigate the effects of the PTO damping caused by the power take–off (PTO) system on device performance. The performance is assessed for a range of regular wave heights and periods. The results demonstrate that a PTO system with an intermediate damping can be used for all chambers in the MC–OWC device for most wave period ranges, except for the long wave periods. These require a higher PTO damping. An increased incident wave height reduces the device capture width ratio, but there is a noticeable improvement for long wave periods.     

Searching for ancient gold mines in Filippoi area,Macedonia, Greece,using Worldview-2 satellite imagery

The study area is located near the town of Filippoi, north of the city of Kavala in northern Greece, known from ancient times for its rich gold mines, situated inside hydrothermal alteration zones (Fe–Mn oxide minerals). A Very High-Resolution (0.5 m pixel size) image of Worldview-2 satellite was digitally enhanced, yielding target areas of potential ore existence and lineaments. Ground-truth that followed digital image processing, revealed abandoned ancient mines, slags and ore occurrences. Also, a number of lineaments delineated on the satellite image were verified as faults.     

Simulation of streamflow with statistically downscaled daily rainfall using a hybrid of wavelet and GAMLSS models

ABSTRACT

A rainfall–streamflow model is proposed, in which a downscaled rainfall series and its wavelet-based decomposed sub-series at optimum lags were used as covariates in GAMLSS (Generalized Additive Model in Location, Scale and Shape). GAMLSS is applied in climate change impact assessment using CMIP5 general climate model to simulate daily streamflow in three sub-catchments of the Onkaparinga catchment, South Australia. The Spearman correlation and Nash-Sutcliffe efficiency between the observed and median simulated streamflow values were high and comparable for both the calibration and validation periods for each sub-catchment. We show that the GAMLSS has the capability to capture non-stationarity in the rainfall–streamflow process. It was also observed that the use of wavelet-based decomposed rainfall sub-series with optimum lags as covariates in the GAMLSS model captures the underlying physics of the rainfall–streamflow process. The development and application of an empirical rainfall–streamflow model that can be used to assess the impact of catchment-scale climate change on streamflow is demonstrated.     

Spatio-temporal characteristics of small-scale wave–current ripples on the Ameland ebb-tidal delta

Ebb-tidal deltas are highly dynamic environments affected by both waves and currents that approach the coast under various angles. Among other bedforms of various scales, these hydrodynamics create small-scale bedforms (ripples), which increase the bed roughness and will therefore affect hydrodynamics and sediment transport. In morphodynamic models, sediment transport predictions depend on the roughness height, but the accuracy of these predictors has not been tested for field conditions with strongly mixed (wave–current dominated) forcing. In this study, small-scale bedforms were observed in the field with a 3D Profiling Sonar at five locations on the Ameland ebb-tidal delta, the Netherlands. Hydrodynamic conditions ranged from wave dominated to current dominated, but were mixed most of the time. Small-scale ripples were found on all studied parts of the delta, superimposed on megaripples. Even though a large range of hydrodynamic conditions was encountered, the spatio-temporal variations in small-scale ripple dimensions were relatively small (height 0.015 m, length 0.11 m). Also, the ripples were always highly three-dimensional. These small dimensions are probably caused by the fact that the bed consists of relatively fine sediment. Five bedform height predictors were tested, but they all overestimated the ripple heights, partly because they were not created for small grain sizes. Furthermore, the predictors all have a strong dependence on wave- and current-related velocities, whereas the ripple heights measured here were only related to the near-bed orbital velocity. Therefore, ripple heights and lengths in wave–current-dominated, fine-grained coastal areas ( mm) may be best estimated by constant values rather than values dependent on the hydrodynamics. In the case of the Ameland ebb-tidal delta, these values were found to be m and m. ©2019 The Authors. Earth Surface Processes and Landforms published by John Wiley & Sons Ltd.     

Cartographic Symbol Design Considerations for the Space–Time Cube

The cartographic representation of geographic phenomena in the space–time cube comes with special challenges and opportunities when compared with two-dimensional maps. While the added dimension allows the display of attributes that vary with time, it is difficult to display rapidly varying temporal data given the limited display height. In this study, we adapt 2D cyclic point symbols to construct 3D surfaces designed along a helical path for the space–time cube. We demonstrate how these complex?3D helical surfaces can display detailed data, including data reported daily over 100 years and data reported in four-hour intervals over a year. To create the point symbols, each value is plotted along the curve of a helix, with each turn of the helix representing one year or week, respectively. The model is modified by varying the radii from the time axis to all points using the attribute value, in these cases maximum daily temperature and four-hourly ridership, and then creating a triangulated surface from the resulting points. Using techniques common to terrain representation, we apply hue and saturation to the surface based on attribute values, and lightness based on relief shading. Multiple surfaces can be displayed in a space–time cube with a consistent time interval facing the viewer, and the surfaces or viewer perspective can be rotated to display synchronized variations. We see this method as one example of how cartographic design can refine or enhance operations in the space–time cube.     

Provenance and origins of a Late Paleozoic accretionary complex within the Khangai–Khentei belt in the Central Asian Orogenic Belt,central Mongolia

We have investigated the petrography, geochemistry, and detrital zircon U–Pb LA-ICPMS dating of sandstone from the Gorkhi Formation of the Khangai–Khentei belt in the Ulaanbaatar area, central Mongolia. These data are used to constrain the provenance and source rock composition of the accretionary complex, which is linked to subduction of the Paleo-Asian Ocean within the Central Asian Orogenic Belt during the Middle Devonian to Early Carboniferous. Field and microscopic observations of the modal composition of sandstone and constituent mineral chemistry indicate that the sandstone of the Gorkhi Formation is feldspathic arenite, enriched in saussuritized plagioclase. Geochemical data show that most of the sandstone and shale were derived from a continental margin to continental island arc setting, with plutonic rocks being the source rocks. Detrital zircon ²⁰⁶Pb/²³⁸U ages of two sandstones yields age peaks of 322 ± 3 and 346 ± 3 Ma. The zircon ²⁰⁶Pb/²³⁸U age of a quartz–pumpellyite vein that cuts sandstone has a weighted mean age of 339 ± 3 Ma. Based on these zircon ages, we infer that the depositional age of sandstone within the Gorkhi Formation ranges from 320 to 340 Ma (i.e., Early Carboniferous). The provenance and depositional age of the Gorkhi Formation suggest that the evolution of the accretionary complex was influenced by the intrusion and erosion of plutonic rocks during the Early Carboniferous. We also suggest that spatial and temporal changes in the provenance of the accretionary complex in the Khangai–Khentei belt, which developed aound the southern continental margin of the Siberian Craton in relation to island arc activity, were influenced by northward subduction of the Paleo-Asian Ocean plate.     

Methodological comparison for quantitative analysis of fossil and recently derived carbon in mine soils with high content of aliphatic kerogen

In mine soil, quantification of soil organic carbon (OC) derived recently from biomass decomposition is complicated by the presence of fossil (geogenic) C derived from coal, oil shale, or similar material in the overburden. The only reliable method for such measurement is ¹⁴C analysis (i.e. radiocarbon dating) using instrumentation such as accelerator mass spectrometry, which is too expensive for routine laboratory analysis. We tested two previously used and two new methods for recent C quantification and compared them with ¹⁴C AMS radiocarbon dating as a reference using a set of soil samples (n = 14) from Sokolov, Czech Republic: (i) ¹³C isotope ratio composition, (ii) cross polarization magic angle spinning ¹³C nuclear magnetic resonance (CPMAS ¹³C NMR) spectroscopy, (iii) near infrared spectroscopy (NIRS) coupled with partial least squares regression and (iv) Rock–Eval pyrolysis. Conventional methods for OC determination (dry combustion, wet dichromate oxidation, loss-on-ignition) were also compared to quantify any bias connected with their use. All the methods provided acceptable recent carbon estimates in the presence of mostly aliphatic fossil C from kerogen. However, the most accurate predictions were obtained with two approaches using Rock–Eval pyrolysis parameters as predictors, namely (i) S₂ curve components and (ii) oxygen index (OI). The S₂ curve approach is based on the lower thermal stability of recent vs. fossil organic matter. The OI approach corresponded well with ¹³C NMR spectra, which showed that samples rich in recent C were richer in carboxyl C and O-alkyl C. These two methods showed the greatest potential as routine methods for recent C quantification.     

A new algorithm for distance cartogram construction

A distance cartogram is a diagram that visualizes the proximity indices between points in a network, such as time–distances between cities. The Euclidean distances between the points on the distance cartogram represent the given proximity indices. This is a useful visualization tool for the level of service of transport, e.g. difference in the level of service between regions or points in a network and its improvement in the course of time. The two previously proposed methods—multidimensional scaling (MDS) and network time–space mapping—have certain advantages and disadvantages. However, we observe that these methods are essentially the same, and the merits of both these methods can be combined to formulate a generalized solution. In this study, we first formulate the time–space mapping problem, which includes the key features of both of the above stated methods, and propose a generalized solution. We then apply this solution to the time–distances of Japan's railway networks to confirm its applicability.     

Formation of elongated granite–migmatite domes as isostatic accommodation structures in collisional orogens

The mid-Carboniferous Pelhřimov core complex, Bohemian Massif, is a crustal-scale elongated granite–migmatite dome interpreted to have formed by gravity-driven diapiric upwelling of the metapelitic middle crust. The vertical diapiric flow is evidenced by outward-dipping foliation and lineation patterns, deformation coeval with the widespread presence of melt, rapid exhumation of the dome center from depths corresponding to pressure of about 0.6 GPa to shallow levels (pressure less than 0.2 GPa) within 2 M.y., and kinematic indicators of downward return flow of the mantling rocks. As compared to common diapirs, however, the Pelhřimov complex exhibits a more complicated inferred strain pattern with two perpendicular, irregularly alternating directions of horizontal extension in what is interpreted as the diapir head. Comparison of structural data from migmatites with anisotropy of magnetic susceptibility (AMS) data in granites also reveals that only final increments of strain are recorded in the granites. The map dimensions and gravity image of the complex suggest that the diapiric upwelling affected a large portion of the orogen's interior between two microplates brought together during continental collision. The northwesterly microplate (the upper-crustal Teplá–Barrandian unit) collapsed vertically as an ‘elevator’ at around 346–337 Ma whereas the easterly microplate (Brunia) was underthrust beneath the Moldanubian rocks during ∼346–330 Ma (the indentor). It is suggested that these microplates then acted as cold and rigid margins localizing mid-crustal diapirism and associated voluminous S-type granite plutons inbetween, parallel to the edge of the Brunia indentor.We conclude that bringing together soft metapelitic middle crust with two rigid lithospheric blocks during collision resulted in significant lateral temperature and strength variations across the orogen's interior. A general conclusion from these inferences is that granite–migmatite domes delineating margins of collided microplates may form as crustal-scale structures accommodating late-orogenic isostatic reequilibration.