Gas generation and expulsion characteristics of Middle–Upper Triassic source rocks,eastern Kuqa Depression,Tarim Basin,China: implications for shale gas resource potential

Frontier exploration in the Kuqa Depression, western China, has identified the continuous tight-sand gas accumulation in the Lower Cretaceous and Lower Jurassic as a major unconventional gas pool. However, assessment of the shale gas resource in the Kuqa Depression is new. The shale succession in the Middle–Upper Triassic comprises the Taliqike Formation (T₃t), the Huangshanjie Formation (T₃h) and the middle–upper Karamay Formation (T_2–3k), with an average accumulated thickness of 260 m. The high-quality shale is dominated by type III kerogen with high maturity and an average original total organic carbon (TOC) of about 2.68 wt%. An improved hydrocarbon generation and expulsion model was applied to this self-contained source–reservoir system to reveal the gas generation and expulsion (intensity, efficiency and volume) characteristics of Middle–Upper Triassic source rocks. The maximum volume of shale gas in the source rocks was obtained by determining the difference between generation and expulsion volumes. The results indicate that source rocks reached the hydrocarbon expulsion threshold of 1.1% VR and the hydrocarbon generation and expulsion reached their peak at 1.0% VR and 1.28% VR, with the maximum rate of 56 mg HC/0.1% TOC and 62.8 mg HC/0.1% TOC, respectively. The volumes of gas generation and expulsion from Middle–Upper Triassic source rocks were 12.02 × 10¹² m³ and 5.98 × 10¹² m³, respectively, with the residual volume of 6.04 × 10¹² m³, giving an average gas expulsion efficiency of 44.38% and retention efficiency of 55.62%. Based on the gas generation and expulsion characteristics, the predicted shale gas potential volume is 6.04 × 10¹² m³, indicating a significant shale gas resource in the Middle–Upper Triassic in the eastern Kuqa Depression.     

Response of detrital zircon and monazite,and their U–Pb isotopic systems,to regional metamorphism and host‐rock partial melting,Cooma Complex,southeastern Australia

Progressive Early Silurian low‐pressure greenschist to granulite facies regional metamorphism of Ordovician flysch at Cooma, southeastern Australia, had different effects on detrital zircon and monazite and their U–Pb isotopic systems. Monazite began to dissolve at lower amphibolite facies, virtually disappearing by upper amphibolite facies, above which it began to regrow, becoming most coarsely grained in migmatite leucosome and the anatectic Cooma Granodiorite. Detrital monazite U–Pb ages survived through mid‐amphibolite facies, but not to higher grade. Monazite in the migmatite and granodiorite records only metamorphism and granite genesis at 432.8 ± 3.5 Ma. Detrital zircon was unaffected by metamorphism until the inception of partial melting, when platelets of new zircon precipitated in preferred orientations on the surface of the grains. These amalgamated to wholly enclose the grains in new growth, characterised by the development of {211} crystal faces, in the migmatite and granodiorite. New growth, although maximum in the leucosome, was best dated in the granodiorite at 435.2 ± 6.3 Ma. The combined best estimate for the age of metamorphism and granite genesis is 433.4 ± 3.1 Ma. Detrital zircon U–Pb ages were preserved unmodified throughout metamorphism and magma genesis and indicate derivation of the Cooma Granodiorite from Lower Palaeozoic source rocks with the same protolith as the Ordovician sediments, not Precambrian basement. Cooling of the metamorphic complex was relatively slow (average ～12°C/10⁶y from ～730 to ～170°C), more consistent with the unroofing of a regional thermal high than cooling of an igneous intrusion. The ages of detrital zircon and monazite from the Ordovician flysch (dominantly composite populations 600–500 Ma and 1.2–0.9 Ga old) indicate its derivation from a source remote from the Australian craton.     

Accounting for sparsely observed rainfall space—time variability in a rainfall—runoff model of a semiarid Tunisian basin/Prise en compte d'observations peu denses de la variabilité spatiotemporelle de la pluie dans une modélisation pluie—débit d'un bassin semi-aride Tunisien

Abstract

The management of water excesses and deficits is a major task in semiarid Mediterranean regions, where the variability of rainfall inputs is high at different time and space scales. Thus intense hydrometeorological events, which generate both potential resource and hazards, are of major interest. A simple method is proposed, with the example of the Skhira basin (192 km²) in central Tunisia, to account for the event space–time variability of rainfall in a rainfall–runoff model, in order to check its influence on the shape, magnitude and timing of resulting hydrographs. The transfer function used is a geomorphology-based unit hydrograph with an explicit territorial significance. Simulations made for highly variable events show the relevance of this method, seen as the first step of a downward approach, and its robustness with respect to the quality and the density of rainfall data.     

Genetic and ore-forming ages of the Fe–P–(Ti) oxide deposits associated with mafic–ultramafic–carbonatite complexes in the Kuluketage block,NW China

Abstract

During the past 50 years, many geological and ore-deposit investigations have led to the discovery of the Fe–P–(Ti)-oxide deposits associated with mafic–ultramafic–carbonatite complexes in the Kuluketage block, northeastern Tarim Craton. In this paper, we discuss the genetic and ore-forming ages, tectonic setting, and the genesis of these deposits (Kawuliuke, Qieganbulake and Duosike). LA-ICP-MS zircon U–Pb dating yielded a weighted mean ²⁰⁶Pb/²³⁸U ages of 811?±?5?Ma, 811?±?4?Ma, and 840?±?5?Ma for Kawuliuke ore-bearing pyroxenite, Qieganbulake gabbro and Duosike ore-bearing pyroxenite, respectively. The CL images of the Kawuliuke apatite grains show core–rim structure, suggesting multi-phase crystallisation, whereas the apatite grains from Qieganbulake and Dusike deposits do not show any core–rim texture, suggesting a single-stage crystallisation. LA-ICP-MS apatite ²⁰⁷Pb-corrected U–Pb dating provided weighted mean ²⁰⁶Pb/²³⁸U ages of 814?±?21?Ma and 771?±?8?Ma for the Kawuliuke ores, and 810?±?7?Ma and 841?±?7?Ma for Qieganbulake and Duosike ores, respectively. The core–rim texture in apatite by CL imaging as well as two different ore-forming ages in the core and rim of the apatite indicate two metallogenic events for the Kawuliuke deposit. The first metallogenic period was magmatic in origin, and the second period was hydrothermal in origin. The initial ore-forming age of the Kawuliuke Fe–P–Ti mineralisation was ca 814?Ma and the second one was ca 771?Ma. On the other hand, the ore-forming ages of the Qieganbulake and Duosike deposits were ca 810?Ma and ca 841?Ma, respectively. Qieganbulake and Duosike deposits were of magmatic origin. Combined with previous geochronological data and the research on the tectonic background, we infer that the Kawuliuke, Qieganbulake and Duosike Fe–P–(Ti)-oxide deposits were formed in a subduction-related tectonic setting and were the product of subduction-related magmatism.     

Wildfire preparedness,community cohesion and social–ecological systems

The consequences of wildfires are felt in susceptible communities around the globe on an annual basis. Climate change predictions in places like the south-east of Australia and western United States suggest that wildfires may become more frequent and more intense with global climate change. Compounding this issue is progressive urban development at the peri-urban fringe (wildland–urban interface), where continued infrastructure development and demographic changes are likely to expose more people and property to this potentially disastrous natural hazard. Preparing well in advance of the wildfire season is seen as a fundamental behaviour that can both reduce community wildfire vulnerability and increase hazard resilience – it is an important element of adaptive capacity that allows people to coexist with the hazardous environment in which they live. We use household interviews and surveys to build and test a substantive model that illustrates how social cohesion influences the decision to prepare for wildfire. We demonstrate that social cohesion, particularly community characteristics like ‘sense of community’ and ‘collective problem solving’, are community-based resources that support both the adoption of mechanical preparations, and the development of cognitive abilities and capacities that reduce vulnerability and enhance resilience to wildfire. We use the results of this work to highlight opportunities to transfer techniques and approaches from natural hazards research to climate change adaptation research to explore how the impacts attributed to the social components of social–ecological systems can be mitigated more effectively.     

Direct Observations of Atmospheric Transport and Stratosphere-Troposphere Exchange from High-Precision Carbon Dioxide and Carbon Monoxide Profile Measurements

The balloon-borne Aircore campaign was conducted in Inner Mongolia,China,on June 13 and 14 2018,which detected carbon dioxide(CO_2) and carbon monoxide(CO) profiles from surface to 24 km,showing strong positive and negative correlations between 8 km and 10 km on 13 and 14 June,respectively.Backward trajectories,meteorological analyses,and CO_2 horizontal distributions were combined to interpret this phenomenon.The results indicated that the source region experienced a stratospheric intrusion and exhibited a large horizontal CO_2 gradient;namely,lower CO concentrations corresponded to higher CO_2 concentrations and vice versa.The laminar structure with multiple origins resulted in the highly negative correlation between CO_2 and CO in the upper troposphere on 14 June.The contribution of stratospheric air mass to the upper troposphere and that of tropospheric air mass to the lower stratosphere were 26.7% and24.3%,respectively,based on a mass balance approach.Another interesting phenomenon is that CO_2 and CO concentrations increased substantially at approximately 8 km on 13 June.An analysis based on the backward trajectory implied that the air mass possibly came from anthropogenic sources.The slope of CO_2/CO representing the anthropogenic sources was 87.3 ppm ppm~(-1).In addition,the CO_2 profile showed that there was a large CO_2 gradient of 4 ppm km-1 within the boundary layer on 13 June,and this gradient disappeared on 14 June.     

Une dépression piézométrique naturelle en hausse au Sahel (Sud-Ouest du Niger)A rising piezometric depression in the Sahel (southwestern Niger)

In southwest Niger, the Continental Terminal water table displays a natural hollow shape about 10 m in depth over an area of 4000 km². A 10-year survey of this hollow aquifer has shown that current recharge is above $\text{20 }\text{mm}\text{yr}{}^{\mathrm{?1}}$. The water table has risen continuously since the 1950–1960s as a result of land clearance. This shows a disequilibrium in the aquifer balance. The long-term recharge rate is estimated by radioisotopes to be around $\text{1 }\text{mm}\text{yr}{}^{\mathrm{?1}}$. This figure fits with the only possible origin of the piezometric depression, i.e. evapotranspiration losses in its centre. To cite this article: G. Favreau et al., C. R. Geoscience 334 (2002) 395–401.     

Inconstancy in predator/prey ratios in Quaternary large mammal communities of Italy, with an appraisal of mechanisms

Constancy in predator/prey ratio (PPR) is a controversial issue in ecological research. Published reports support both constancy and inconstancy of the ratio in animal communities. Only a few studies, however, specifically address its course through time. Here we study the course of predator/prey ratio in communities of large Plio-Pleistocene mammals in Italy. After controlling for taphonomic biases, we find strong support for PPR inconstancy through time. Extinction, dispersal events, and differences in body size trends between predators and their prey were found to affect the ratio, which was distributed almost bimodally. We suggest that this stepwise dynamic in PPR indicates changes in ecosystem functioning. Prey richness was controlled by predation when PPR was high and by resources when PPR was low.     

A filtering approach for estimating lake water quality from remote sensing data

In this paper we consider the estimation of lake water quality constituent distributions from hyperspectral remote sensing data. We present a computational approach that can be used to assimilate information from mathematical evolution models into data processing. The method is based on a reduced order iterated extended Kalman filter, and a convection–diffusion model is used to describe the movement of the water quality constituents. The performance of the technique is evaluated in a simulation study. The results show that the filter approach with an appropriate evolution model yields estimates that have better spatial and temporal resolutions than those obtained with conventional methods. Furthermore, the use of a feasible evolution model may make it possible to obtain information also on the concentrations in the lower parts of the lake.     

Spatio-temporal characteristics of small-scale wave–current ripples on the Ameland ebb-tidal delta

Ebb-tidal deltas are highly dynamic environments affected by both waves and currents that approach the coast under various angles. Among other bedforms of various scales, these hydrodynamics create small-scale bedforms (ripples), which increase the bed roughness and will therefore affect hydrodynamics and sediment transport. In morphodynamic models, sediment transport predictions depend on the roughness height, but the accuracy of these predictors has not been tested for field conditions with strongly mixed (wave–current dominated) forcing. In this study, small-scale bedforms were observed in the field with a 3D Profiling Sonar at five locations on the Ameland ebb-tidal delta, the Netherlands. Hydrodynamic conditions ranged from wave dominated to current dominated, but were mixed most of the time. Small-scale ripples were found on all studied parts of the delta, superimposed on megaripples. Even though a large range of hydrodynamic conditions was encountered, the spatio-temporal variations in small-scale ripple dimensions were relatively small (height 0.015 m, length 0.11 m). Also, the ripples were always highly three-dimensional. These small dimensions are probably caused by the fact that the bed consists of relatively fine sediment. Five bedform height predictors were tested, but they all overestimated the ripple heights, partly because they were not created for small grain sizes. Furthermore, the predictors all have a strong dependence on wave- and current-related velocities, whereas the ripple heights measured here were only related to the near-bed orbital velocity. Therefore, ripple heights and lengths in wave–current-dominated, fine-grained coastal areas ( mm) may be best estimated by constant values rather than values dependent on the hydrodynamics. In the case of the Ameland ebb-tidal delta, these values were found to be m and m. ©2019 The Authors. Earth Surface Processes and Landforms published by John Wiley & Sons Ltd.