Experimental and theoretical study of stability of dense hydrous magnesium silicates in the deep upper mantle

Fluid-undersaturated experiments were conducted to determine the phase relations in the simplified peridotite system MgO-SiO₂-H₂O (MSH) at 11.0-14.5 GPa and 800-1400 °C. Stability relations of dense hydrous magnesium silicates (DHMSs) under fluid-undersaturated conditions were experimentally examined. From the fluid-absent experimental results, we retrieved thermodynamic data for clinohumite, phase A, phase E, and hydrous wadsleyite, consistent with the published data set for dry mantle minerals. With this new data set, we have calculated phase equilibria in the MSH system including dehydration reactions. The dehydration reactions calculated with lower water activities of 0.68-0.60 match the fluid-present experiments of this study above 11.0 GPa and 1000 °C, indicating that considerable amounts of silicate component were dissolved into the fluid phase. The calculated phase equilibria illustrate the stability of the post-antigorite phase A-bearing assemblages. In the cold subducting slab peridotite, phase A + enstatite assemblage survives into the transition zone, whereas phase A + forsterite + enstatite assemblage forms hydrous wadsleyite at a much shallower depth of about 360-km. The slab is subducted with no dehydration reactions occurring when entering the transition zone. The phase equilibria also show the high temperature stability of phase E. Phase E is stable up to 1200 °C at 13.5 GPa, a plausible condition in the mantle of relatively low temperature, i.e., beneath subduction zones. Phase E is a possible water reservoir in the mantle as well as wadsleyite and ringwoodite.     

快速交通导向下我国特大城市有机疏散的响应机制与路径

快速交通在发展过程中产生的时空收敛效应、产业人口迁往效应以及引致节点城镇有机生长和空间轴线发展,使得特大城市有机疏散的距离、形式发生了相应的调整和变化,开始从内部地域空间依次向外部地域空间进行平面型和立体型有机疏散,而且促进了城镇体系和城乡系统各种要素的流动和整合。由此,不仅实现了特大城市资源要素供给与需求的动态平衡,并且加快了城镇体系的优化和城乡一体化进程。     

中国煤炭资源供应格局演变及流动路径分析

利用1949—2008年的相关统计数据,分析中国煤炭资源供应格局和流动路径,结果表明:(1)国家政策变动对中国煤炭资源消费规模影响深刻,每一次政策变化都会造成能源消费规模的波动,近年来强烈的能源需求使得我国煤炭供应不得不面临进口的现实;(2)受能源需求和资源禀赋的双重压力,大规模、跨区域、长距离的煤炭运输成为我国能源运输体系的重要特征;(3)尽管煤炭运输方式在向铁路、水路和公路组合并用的多元化发展,但仍然不能满足旺盛的能源需求,煤炭运输瓶颈始终存在,变输煤为输电是缓解当前煤炭运输困难的一个途径。     

各种大气水汽输送气候计算方法的比较和讨论

比较瞬时法，平均法和逐层平均法３种水汽输送气候计算方案，发现它们的输送方向大致相同，输送量差异显著。瞬时法最准确；逐层平均法次之，但误差的年际波动较大，平均法虽然简单然而误差大。     

The transport-geographical location of Siberia's microregions: techniques and assessment results

It is established that the methodological tools for quantitative measurement of the transport-geographical location is insufficiently advanced. We suggest the algorithm for the technique of its cost assessment based on determining the “economic” distances and adapted to the peculiarities of the transport system of Siberia. We calculated the costs of the transport-geographical location of Siberian microregions (within administrative districts) with respect to the most important year-round sea ports for the current (the year 2005) and future (the year 2030) levels.     

长三角地区交通优势度的空间格局

通过公路网络密度、综合交通可达性以及关键节点联系便捷性三要素的综合集成,探讨了长江三角洲地区交通优势度的空间格局。长三角地区公路路网密度居于全国前列,北部地区明显高于南部;综合交通可达性较好的单元相对集中于沪宁-沪杭-杭甬沿线地区,由此区域向南、向北可达性逐渐降低;各地域单元与关键节点的联系均较为便捷,上海及其临近地区...     

Preservation of coal-waste geochemical markers in vegetation and soil on self-heating coal-waste dumps in Silesia,Poland

Occurrence and distributions of geochemical markers on vegetation and in soils covering two self-heating coal waste dumps were investigated with gas chromatography-mass spectrometry (GC–MS) and compared with those of bitumen expelled on the coal waste dump surface. Presence of biomarkers, alkyl aromatic hydrocarbons, polycyclic aromatic hydrocarbons (PAHs), and such polar compounds as phenols indicate that components of self-heating coal wastes indeed migrate to soils and plants surface and their characteristic fingerprints can be applied in passive monitoring to investigate migration of contaminants from self-heating coal wastes. Moreover, results allow to discriminate between the Upper- and Lower Silesian coal basins, notwithstanding value shifts caused by heating. Mechanisms enabling the migration of geochemical compounds into soils include mixing with weathered coal-waste material, transport in gases emitted due to self-heating and, indirectly, by deposition of biomass containing geochemical substances. Transport in gases involves mostly lighter compounds such as phenols, methylnaphthalenes, methylbiphenyls, etc. Distributions and values of geochemical ratios are related to differences in their boiling temperatures in the case of lighter compounds but preserve geochemical features in the case of heavier compounds such as pentacyclic trierpanes.     

旅行分布的重力模式与交通模型的关系

从交通问题的对偶规划出发, 引入由Beckmann 和Wallance, Golob 和Beckman 等提出的不确定性效用方法, 建立交通问题和双约束重力模型的关系。证明当旅行者效用概率分布密度函数的标准差趋于零时, 双约束重力模型中的距离摩擦系数趋于正无穷, 由双约束重力模型确定的旅行分布使得总的交通成本达到最小。在这种关系中, 双约束重力模型中平衡因子的作用是市场调整旅行终点服务价格进而调整旅行者消费者剩余的结果。通过建立的分 析方法对北京、上海、广州、西安、武汉、成都和昆明等七个城市间航空交通的应用, 发现多数航线的模拟较好。结果表明各终点的差异性、消费者偏好的不同、交通工具的替代性和旅行目的之差异性等可以导致一些较大的误差, 这些差异性可以采用对起终点对的单位交通费用的调整来体现, 从而达到较好的模拟和分析效果。     

三维配管软件在储运设计中的应用

以宁波瑞福特气体储运有限公司20,000m3低温乙烯终端和配套公用工程项目的设计为例,介绍了PDSOFT三维配管软件在石油化工储运中的应用。通过项目对该软件的使用过程进行较深入的描述分析、同时对该软件在石油化工储运设计中应用前景和应注意的问题进行了说明。     

西气东输管道工程中卫黄河穿越隧道场地工程地质条件评价

西气东输工程中卫黄河穿越隧道长1197.77m,高4.3m,宽5.6m。隧道入口高于黄河水位28m,出口高于黄河水位45m。隧道顶板高程为1130m。位于黄河水下100m。隧道场地围岩为寒武系磨盘井组灰绿色、银灰色浅变质中厚层细粒长石石英砂岩、千枚状板岩、绢云母化千枚岩。围岩为弱风化Ⅲ～Ⅳ类岩石。透水率为4～67Lu,纵波波速为500～3300m.s-1。BQ为300～400。变形模量为6.11～9.22GPa。泊松比（）0.14～0.24。内摩擦角（）为42.1～44.7。地下水为基岩裂隙水。含水层为寒武系浅变质岩,受大气降水渗入补给,单井涌水量为1.0～50m3.d-1。隧道轴线穿越区岩体较完整较破碎,未有全新活动断层。隧道位置选择和开挖深度设计是可行的。施工和长期运营是安全的。