元素活动态提取条件和分析方法的应用研究

元素活动态分析作为深穿透地球化学的新方法,得到了广泛的应用。实验对水提取态、黏土吸附态、有机结合态和铁锰氧化物结合态四种元素活动态的提取条件进行了系统研究,分别考察了提取时间、液固比、离心转速、提取液放置时间对提取效果的影响,确定了元素活动态的最佳提取条件:提取时间为24h,液固比为10:1,离心转速4000rpm;提取液采用新型的高分辨率等离子体质谱法(HR-ICP-MS)测定,该仪器具有强大的动态线性范围(10^-12～10¹²)和高灵敏度,使可同时测定的元素拓展至50余种,可以大大提高工作效率。对HR-ICPMS的主要工作条件:辅助气流量、样品气流量和采样深度等利用响应面法进行了优化。本法将传统的过滤法改为离心法,避免了滤纸或穿滤引入的误差;将新型的高分辨率等离子体质谱法(HR-ICP-MS)应用到提取液的测定,提升了多元素同时分析能力,大大提高工作效率,同时也降低了该方法的检出限,改善了测定结果的精密度。依据实验结果,建立了HR-ICP-MS对四种元素活动态的分析方法,分别得到了四种活动态中各元素的方法检出限和方法精密度,水提取态、黏土...     

Bounding greybody and deflection angle of improved Schwarzschild black hole

In this paper, we study the weak deflection angle in the spacetime of improved Schwarzschild black hole using the method derived by Gibbons and Werner. To do so, we derive the optical curvature from the optical metric and calculate deflection angle in weak field limits by using the Gauss–Bonnet theorem. Moreover, we study the effect of the plasma medium on the weak gravitational lensing using the Gauss–Bonnet theorem. Furthermore, we also study the graphical analysis of the deflection angle in both the plasma and non-plasma mediums. Moreover, we obtain the bound on greybody for improved Schwarzschild black hole.     

12种射电爆发及其辐射机制

系统地研究了太阳活动区上空闭合磁场域和开放磁场域俘获的高能电子的运动特性,所产生的自然波属性及观测特性。探讨了１２种射电爆发的辐射机制。     

等离子质谱(ICP-MS)对高含量元素硫样品中的微量元素分析前处理方法初探

用等离子质谱(ICP-MS)分析一些特殊样品的时候,前处理方法成为分析样品成功与否的关键,对于高基质含量的样品测量其微量元素含量更是如此。元素硫超过99%的自然硫样品中微量元素的测定一般使用燃烧的方法去除自然硫,但是一些易挥发性的元素也因此失去而测不出来。作者试图采用硫升华的方法去除硫基质,通过在原样品中加入内标,分析测定后计算内标的回收率确定出元素Be,Sn,Sc,U和稀土元素(REE)的回收率都在90%以上,可以用升华硫方法很好地测定,而元素Tl,Hf,W,Nb,Zr,Ta等的回收率则在75%以下,不适合用该种方法测定。     

顺序扫描 ICP-AES法测定高纯石墨灰分中14种杂质金属元素的方法研究

本文研究了快速测定石墨灰分中14种杂质元素Al,Ca,Cd,Co,Cr,Cu,Fe,Mg,Mn,Mo,Ni,Ti,V,Zn的分析方法,以满足提纯石墨研究工作对快速了解石墨提纯效果的要求.依据测定样品中各元素的含量情况,实验选择14种元素的分析线.运用ICP-AES谱线轮廓图功能,消除常量元素产生的基体背景干扰.运用干扰系数法进行测定结果校正,并对ICP-AES测定灰分中14种元素的检出线、精密度、准确度进行了测定.结果显示,本方法分析石墨灰分中杂质元素能够满足提纯石墨研究工作的要求.     

Double-Pulse Laser-Driven Jets on OMEGA

A double-pulse laser drive is used to create episodic supersonic plasma jets that propagate into a low density ambient medium. These are among the first laser experiments to generate pulsed outflow. The temporal laser-intensity profile consists of two 1-ns square pulses separated by 9.6 ns. The laser is focused on a truncated conical plug made of medium Z material inserted into a high-Z washer. Unloading material from the plug is collimated within the cylindrical washer hole, then propagates into the low-Z foam medium. The resulting jet is denser than the ambient medium. Double-pulse jet evolution is compared to that driven by a single laser pulse. The total drive energy is the same for both jets, as if a source with fixed energy generated a jet from either one or two bursts. Radiographs taken at 100 ns show that a single-pulse jet was broader than the double-pulse jet, as predicted by hydrodynamic simulations. Since the initial shock creating the jet is stronger when all the energy arrives in a single pulse, the jet material impacts the ambient medium with higher initial velocity. Detailed comparisons between single- and double-pulsed jet rheology and shock structure are presented. 2-D hydrodynamic simulations are compared to the experimental radiographs. PACS: 52.30.−q 41.75.Jv 42.62.−b 42.68.Sq 47.40.−x 47.56.+r     

ICP—光量计测定地质样品中的Sc

本方法是用ＩＣＰ—光量计测定地质样品中的Ｓｃ，用氢氟酸—盐酸溶解样品，对几个国家级标样进行测定，结果与推荐值一致。方法检出限为Ｓｃ：０．２２μｇ／ｇ，本方法简单、快速、准确     

等离子直读光谱分析测定地质样品中10个造岩元素

在聚四氟乙烯密封溶样罐中，岩石样品经盐酸，硝酸，氢氟酸，高氯酸加热溶解，保存了易挥发组分ＳｉＦ４用热沸盐酸溶解Ａｌ，Ｃａ，Ｍｇ的氟化物再生沉淀，用饱和硼酸溶液充分配合氟离子，制成的样品溶液在等离子直读光谱仪上，可快速同时测定了Ｓｉ，Ｆｅ，Ａｌ，Ｃａ，Ｍｇ，Ｋ，Ｎａ，Ｍｎ，Ｔｉ，Ｐ等１０个造岩元素，方法准确可靠，已在日常检测工作中应用。     

Charging and motion of dust grains near the terminator of the moon

We discuss the formation of strong local electric fields near minicraters or hills in the vicinity of the terminator. Electrons, having large thermal velocity compared to the solar wind speed can easily penetrate into the shadowed part of a minicrater. At the same time only protons with velocities much higher than their thermal speed can reach such regions. This results in the formation of a strong local negative potential whose magnitude depends on the steepness of the shadowed slope of the minicrater. The extremely small conductivity of the lunar regolith at the shadowed side of the crater prevents any significant electric discharge and thus supports the formation of a strong potential difference at scales much smaller than the Debye radius. Our estimates show that the created local electric fields are sufficiently strong enough to elevate dust grains with the sizes of the order of above the surface. The suggested mechanism is efficient only after sunset rather close to the terminator. Far away from the terminator at the dark side the fluxes of charged particles hitting the surface are so small that the process of dust elevation becomes too weak.     

Kinetic Alfven waves in plasma sheet boundary layer—particle aspect analysis

The particle aspect approach is adopted to investigate the trajectories of charged particles in the electromagnetic field of kinetic Alfven wave. Expressions are found for the dispersion relation, damping rate and associated currents in homogenous plasma. Kinetic effects of electrons and ions are included to study kinetic Alfven wave because both are important in the transition region. It is found that the ratio β of electron thermal energy density to magnetic field energy density and the ratio of ion to electron thermal temperature (T_i/T_e) affect the dispersion relation, damping-rate and associated currents in both cases (warm and cold electron limits). The treatment of kinetic Alfven wave instability is based on the assumption that the plasma consists of resonant and non-resonant particles. The resonant particles participate in an energy exchange process, whereas the non-resonant particles support the oscillatory motion of the wave.