The catchment of the river Adour (SW France) has been examined in order to analyse spatio-temporal variations in a number of key variables (flow, suspended matter, nitrate and dissolved orthophosphate concentrations) over a 25-year period (1972–1996).
Within the catchment area, it has been possible to discern how hydroclimatic fluctuations have affected the watershed, with dry periods in 1972–1976 and 1983–1993 alternating with wetter phases in 1977–1982 and 1994–1995. The anthropogenic activity, primarily, involving the use of water for agricultural purposes, has also had a major impact during this period, particularly in the downstream areas of the catchment.
Suspended matter fluxes display regular downstream increases with significant erosion being evident in the mountainous region contrasting with retention in the floodplains area downstream. These fluxes exhibit temporal and spatial variations with peaks occurring every 3–5 years, 1975–1977, 1979, 1982, 1985, 1987 and 1992. Some of these peaks are suggested to be related to anthropogenic activity involving river management, including the cutting of meanders and the construction of dykes for flood prevention.
Nitrate concentrations evince a similar pattern to the suspended matter fluxes with enhanced levels of downstream. The confluence of the Adour with the Midouze appears not to have any major impact on the nitrate concentration. In the downstream areas, an uptake of nitrate is registered indicating the activity of the riparian vegetation. For the entire catchment, maximal nitrate concentrations are observed in 1979, 1982, 1987, 1991–1992 and 1995. 相似文献
This study describes the biogeochemical cycling of seston in Grand Traverse Bay, Lake Michigan. Seston was characterized by carbon and nitrogen elemental and isotopic abundances. Fluorescence, temperature, light transmittance, and concentrations of dissolved inorganic nitrogen were also determined. PCBs were analyzed from surface (10 m) seston and ΣPCB was calculated by summing all of the congeners quantified in each sample. The vertical and seasonal trends in the δ13C values of seston exhibited a broad range from −30.7 to −23.9‰. Low δ13C values that occur concurrently with a peak in fluorescence below the thermocline reflect uptake of 13C depleted respiratory CO2 and/or the accumulation of 13C depleted lipids by phytoplankton. High δ13C values late in the season likely result from a reduction in photosynthetic fractionation associated with a decrease in the CO2 pool. Seasonal δ15N values of seston were high in the spring and declined through August. The δ15N values of seston reflect a balance between fractionation during assimilation of NH4+ or NO3− and degradative processes. The seston ΣPCB and fluorescence were both high in the spring and subsequently declined, suggesting that the concentrations of PCBs in seston were associated with labile material derived from primary productivity. The strong seasonal trends in the organic geochemical characteristics of seston and concentrations of PCBs emphasize the complex nature of particle cycling in aquatic environments. 相似文献
Immediately after the flood event in summer 1997 at the Odra river, samples of flood sediments were taken for a complex phase analysis. The realized investigations show that the sampled flood sediments are very inhomogeneous. The main reasons for this substantial condition are surely different states of flow during the flood event. It is possible to characterize the investigated material as middle to fine sands with variable phase compositions. The mineral content of the fraction <2 μm shows a complex composition of amorphous matter, quartz, feldspars, and a different composed clay mineral matter. A high distribution of several mixed layers in the clay mineral phase is detectable. Within the scope of the taken analyses the following minerals were detected: kaolinite (disordered), kaolinite/smectite-mixed layer, chlorite/smectite-mixed layer, montmorillonite, illite/smectite-mixed layer, celadonite. The investigation of the heavy fraction shows heavy minerals and heavy particles of different geneses. Mainly these are geogenic, transparent heavy minerals like zircon, amphibole, garnet, pyroxene, apatite, rutile, and epidote. Furthermore there were analysed geogenic, opaque heavy minerals (magnetite and ilmenite), anthropogenic, opaque heavy particles (fly ashes and slags), and biogenic components (pyrite framboids). The substantial character of the investigated flood sediments (e.g. content of organic matter, content of clay minerals) shows that this material is able to act as a fixation medium of contaminants. 相似文献
This paper reports on total organic carbon (TOC) and its fractions dissolved organic carbon (DOC) and particulate organic carbon (POC) studied in different Polish rivers. The samples investigated came from the Vistula, Odra, and Warta rivers, and were compared with similar data on river waters available in the literature. The DOC concentrations ranged from 10.0 to 14.2 mg/L and did not vary during the vegetative season. The POC values considerably increased from May through September and reached a maximum in summer. Results for the years 1991τ1996 evidenced a significant increase in the POC value for the Polish rivers from 10.8 to 24.5 mg/L, in comparison with analogous values for West European rivers and North American ones. The enhanced values of TOC and POC were interpreted as being due to anthropogenic pollution. 相似文献
Basin floor fans contain some of the largest deep-water hydrocarbon accumulations discovered, however they also demonstrate extremely complex stratigraphic architecture, understanding of which is crucial for maximum recovery. Here we develop a new method, based upon palynofacies analysis, for the distinction of the different depositional environments that are commonly associated with basin floor fans. Previous studies and our sedimentological analysis allow good confidence in the discrimination of the different depositional environments of the outcropping Marnoso-Arenacea Formation fan system. One hundred and thirty-five samples were collected from mudstones in conjunction with sedimentary logging of 871 m of outcrops. Six lithofacies associations are described and interpreted to represent lobe axis, lobe fringe, fan fringe, contained interlobe, basin plain, and starved high depositional sub-environments. Palynofacies of these elements demonstrate turbidites to be rich in terrestrial organic matter, with sixteen categories of matter recognised. The abundances and proportions of particles varies between sub-environments, with lobe axis deposits containing the largest, densest particles, with a transition to ever smaller and lighter particles moving toward the basin plain. Fuzzy C-means statistical analysis was used to explore this trend. Distribution of organic matter is not random, but is dominated by hydrodynamic sorting and sequential fall-out of particles as turbidity currents passed across the basin. This allows a palynofacies classification scheme to be constructed to assist the identification of depositional environments of submarine fans, which may be combined with subsurface data to assist reservoir characterisation. 相似文献