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51.
硝酸盐氮氧同位素反硝化细菌法测试研究 总被引:2,自引:0,他引:2
进入21世纪,硝酸盐氮氧同位素测试技术的显著进展是反硝化细菌法测试技术的建立。反硝化细菌法具有可同时分析浓度低至μg/L的硝酸盐氮氧同位素组成、免去复杂的样品预处理、分析时间大大缩短以及从复杂溶液中只转化NO3-为N2O等优点。实验过程由细菌挑选和培养、样品NO3-转化为N2O、N2O提取纯化、同位素测试以及同位素测试结果校正等几个关键步骤组成。国外研究结果显示该技术不仅可用于海水和淡水中硝酸盐同位素测试,而且还可用于土壤样品,并得到不断的完善和应用;国内建立了这一技术,在包气带和地下水硝酸盐污染研究中取得重要进展。由于该技术诸多优点,建议大力促进这一技术在我国的研究和应用,希望有关部门加大支持力度,进一步完善该技术并推广应用。 相似文献
52.
利用氮氧同位素研究桂林寨底地下河硝酸盐来源 总被引:3,自引:0,他引:3
工农业生产的迅速发展使地下水硝酸盐氮(NO3-—N)污染成为世界性的环境问题。地下水中硝酸盐的来源研究在水文地质结构特殊的西南岩溶地区就显得尤为重要。稳定氮同位素和氧同位素在地下水硝酸盐的来源示踪研究中有着广泛的应用。本研究选取岩溶地区典型地下河——广西桂林寨底地下河为研究对象,通过氮氧同位素数据,判断寨底地下河硝酸盐来源是以动物粪便为主的农家肥,为该区地下水的保护和利用提供科学依据。 相似文献
53.
54.
Remotely and accurately quantifying the canopy nitrogen status in crops is essential for regional studies of N budgets and N balances. In this study, we optimised three-band spectral algorithms to estimate the N status of winter wheat. This study extends previous work to optimise the band combinations further and identifies the optimised central bands and suitable bandwidths of the three-band nitrogen planar domain index (NPDI) for estimating the aerial N uptake, N concentration and aboveground biomass. Analysis of the influence of bandwidth change on the accuracy of estimating the canopy N status and aboveground biomass indicated that the suitable bandwidths for optimised central bands were 37 nm at 846 nm, 13 nm at 738 nm and 57 nm at 560 nm for assessing the aerial N uptake and were 37 nm at 958 nm, 21 nm at 696 nm and 73 nm at 578 nm for the assessment of the aerial N concentration and were 49 nm at 806 nm, 17 nm at 738 nm and 57 nm at 560 nm for the estimation of aboveground biomass. The optimised three-band NPDI could consistently and stably estimate the aerial N uptake and aboveground biomass of winter wheat in the vegetative stage and the aerial N concentration in the reproductive stage compared to the fixed band combinations. With suitable bandwidths, the broadband NPDI demonstrated excellent performance in estimating the aerial N concentration, N uptake and biomass. We conclude that the band-optimised algorithm represents a promising tool to measure the improved performance of the NPDI in estimating the aerial N uptake and biomass in the vegetative stage and the aerial N concentration in the reproductive stage, which will be useful for designing improved nitrogen diagnosis systems and for enhancing the applications of ground- and satellite-based sensors. 相似文献
55.
2011年11月10-14日苏州地区发生了一次严重灰霾天气过程,利用气象观测资料、探空资料及大气成分站监测资料对苏州三个站点的受污染情况进行了综合分析。结果表明:灰霾期间地面受弱气压场控制,风力较小,且有接地逆温的持续存在,大气水平和垂直输送都很弱,导致大量污染物在近地面堆积,能见度恶化;三站中昆山站灰霾持续时间最长,共计104时次,影响程度最重,重度灰霾占总数的39 %,中度和重度灰霾超过灰霾总数的一半;灰霾时各粒径颗粒物浓度均维持在较高水平,细粒子在可吸入颗粒物中占有较大比重,说明细粒子对灰霾贡献作用大,14日凌晨昆山及太仓出现大雾天气时细粒子比重甚至超过了灰霾时,而相对湿度峰值只有94 %,因此将该段天气定性为雾霾共存或者湿性霾更妥;秸秆焚烧污染期间,BC浓度明显上升,其绝对浓度要高出正常情况的3倍左右;通过CO/SO2及PM10/SO2对比发现昆山站受秸秆焚烧污染程度要严重的多,因此推测昆山本地郊区可能也存在零星秸秆露天焚烧点。 相似文献
56.
利用2015年1月至2017年6月桂林国家基本气象站能见度、相对湿度、气温、气压、降水等气象要素和PM10、PM2.5、PM1.0颗粒物质量浓度资料,分析桂林城区大气能见度与颗粒物浓度和气象因子之间关系。结果表明:桂林城区大气能见度和PM10、PM2.5、PM1.0呈对数关系,相关系数分别为-0.341、-0.461、-0.509,颗粒物对大气能见度影响在相对湿度为60%—70%时最为显著。在各气象因子中,大气能见度与风速的相关性最好,其次为相对湿度,与风速呈二次函数关系,与相对湿度呈幂指数关系,与温度相关性较小,与气压在秋冬季节呈正相关,相关系数冬季可达0.301,但在春、夏季节相关性不显著;利用颗粒物浓度和气象要素建立8种大气能见度非线性统计回归模型,比较后发现利用PM1.0、风速、相对湿度、气温等因子建立的不同季节大气能见度拟合公式在实际检验中效果最优,能较好地模拟桂林地区大气能见度的变化。 相似文献
57.
Surface area, porosity and water adsorption properties of fine volcanic ash particles 总被引:1,自引:1,他引:0
Our understanding on how ash particles in volcanic plumes react with coexisting gases and aerosols is still rudimentary, despite the importance of these reactions in influencing the chemistry and dynamics of a plume. In this study, six samples of fine ash (<100 m) from different volcanoes were measured for their specific surface area, as, porosity and water adsorption properties with the aim to provide insights into the capacity of silicate ash particles to react with gases, including water vapour. To do so, we performed high-resolution nitrogen and water vapour adsorption/desorption experiments at 77 K and 303 K, respectively. The nitrogen data indicated as values in the range 1.1–2.1 m2/g, except in one case where a as of 10 m2/g was measured. This high value is attributed to incorporation of hydrothermal phases, such as clay minerals, in the ash surface composition. The data also revealed that the ash samples are essentially non-porous, or have a porosity dominated by macropores with widths >500 Å. All the specimens had similar pore size distributions, with a small peak centered around 50 Å. These findings suggest that fine ash particles have relatively undifferentiated surface textures, irrespective of the chemical composition and eruption type. Adsorption isotherms for water vapour revealed that the capacity of the ash samples for water adsorption is systematically larger than predicted from the nitrogen adsorption as values. Enhanced reactivity of the ash surface towards water may result from (i) hydration of bulk ash constituents; (ii) hydration of surface compounds; and/or (iii) hydroxylation of the surface of the ash. The later mechanism may lead to irreversible retention of water. Based on these experiments, we predict that volcanic ash is covered by a complete monolayer of water under ambient atmospheric conditions. In addition, capillary condensation within ash pores should allow for deposition of condensed water on to ash particles before water reaches saturation in the plume. The total mass of water vapour retained by 1 g of fine ash at 0.95 relative water vapour pressure is calculated to be ~10–2 g. Some volcanic implications of this study are discussed.Editorial responsibility: J. Gilbert 相似文献
58.
Geochemical signals of bulk sedimentary organic matter from three cores from Lake Tanganyika provided information about both internal processes and terrestrial inputs to the lake. Indications of land use change were detected in the geochemical records of the watersheds, and the timing of these changes was consistent with historical records of population demographics. While C:N ratios suggested that the distance from shore might be important in influencing the relative amount of allochthonous vs. autochthonous material, all cores were dominated by autochthonous organic matter. In general, nitrogen isotopes were more positive at disturbed sites, indicating inputs of enriched soil nitrate that was subsequently taken up by phytoplankton. In contrast, carbon isotopes did not reflect land use patterns, and a post-1950s decline in carbon isotope ratios found in all cores may indicate a lake-wide decrease in productivity. These interpretations were consistent with pollen and climate records. 相似文献
59.
The nitrogen relations of Enteromorpha spp. growing on intertidal mud flats have been examined over a twelve-month period. Nitrogen assimilation rates using 15N have been used to calculate the production of the alga and were between 0·046 and 0·217 mg (g dry wt alga)?1 h?1 A considerable quantity of the alga was buried beneath the sediment over the growth season and was calculated to be equivalent to an input of up to 9·52 g N m?2 per month and 32 g N m?2 over one complete growth season. Based on carbon, this latter value represented an input of approximately 320 g C m?2 annually. Low rates of nitrogenase activity (acetylene reduction) were found to be associated with the Enteromorpha. The organisms responsible for the nitrogenase activity were probably heterotrophic bacteria but they did not contribute significant quantities of nitrogen to the alga. 相似文献
60.
Patterns and processes involved in litter breakdown on desert river floodplains are not well understood. We used leafpacks containing Fremont cottonwood (Populus deltoides subsp. wislizenii) leaf litter to investigate the roles of weather and microclimate, flooding (immersion), and macroinvertebrates on litter organic matter (OM) and nitrogen (N) loss on a floodplain in a cool-temperate semi-arid environment (Yampa River, northwestern Colorado, USA). Total mass of N in fresh autumn litter fell by 20% over winter and spring, but in most cases there was no further N loss prior to termination of the study after 653 days exposure, including up to 20 days immersion during the spring flood pulse. Final OM mass was 10–40% of initial values. The pattern of OM and N losses suggested most N would be released outside the flood season, when retention within the floodplain would be likely. The exclusion of macroinvertebrates modestly reduced the rate of OM loss (by about 10%) but had no effect on N dynamics over nine months. Immersion in floodwater accelerated OM loss, but modest variation in litter quality did not affect the breakdown rate. These results are consistent with the concept that decomposition on desert floodplains progresses much as does litter processing in desert uplands, but with periodic bouts of processing typical of aquatic environments when litter is inundated by floodwaters. The strong dependence of litter breakdown rate on weather and floods means that climate change or river flow management can easily disrupt floodplain nutrient dynamics. 相似文献