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991.
Isotope geochemistry of the Tieluping silver-lead deposit, Henan, China: A case study of orogenic silver-dominated deposits and related tectonic setting 总被引:22,自引:0,他引:22
The Tieluping silver deposit, which is sited along NE-trending faults within the high-grade metamorphic basement of the Xionger Terrane in the Qinling orogenic belt, is part of an important, recently discovered Mesozoic orogenic-type Ag-Pb belt. Ore formation includes three stages: an early barren quartz-pyrite stage (E), an intermediate polymetallic sulfide ore stage (M), and a late barren carbonate stage (L). Carbon, sulfur and lead isotope systematics indicate that the E-stage fluids are deeply sourced; the L-stage fluids are shallow-sourced meteoric water; whereas the M-stage fluids are a mix of deep-sourced and shallow-sourced fluids. Sulfur and lead isotope data show that the ore-forming fluids must have originated from a source with elevated radiogenic lead and low 34S values, that differs significantly from exposed geologic units in the Xionger Terrane, the lower crust and the mantle. This supports the view that the carbonate-shale-chert sequences of the Guandaokou and Luanchuan Groups south of the Machaoying fault might be the favorable sources, although little is known about their isotopic compositions. A tectonic model that combines collisional orogeny, metallogeny and hydrothermal fluid flow is proposed to explain the formation of the Tieluping silver deposit. During the Mesozoic collision between the North China Craton and South China Block (Early-Mid Triassic Indosinian Orogeny), crustal slabs containing the carbonate-shale-chert sequences of the Guandaokou and Luanchuan Groups, locally rich in organic matter (carbonaceous shale), were thrust northwards beneath the Xionger Terrane along the Machaoying fault. Metamorphic devolatilisation of this underthrust slab probably provided the ore-forming fluids to develop the Ag-Pb ore belt, which includes the Tieluping silver deposit. Fluids and magmas were emplaced during extensional stages related to the Jurassic-Cretaceous Yanshanian Orogeny.Editorial Handling: B. Lehmann 相似文献
992.
The Baula-Nuasahi Complex, on the southern flank of the Singhbhum Archaean nucleus in north-eastern India, exposes a series of Mesoarchaean igneous suites. These are (1) a gabbro–anorthosite unit, which is petrographically homogeneous, although mineral-chemistry data hint at a subtle eastward differentiation; (2) a peridotite unit (with three chromitite layers) together with (3) a pyroxenite unit which display cumulate textures, modal layering, and (for the peridotite unit) differentiation trends in both mineralogy and mineral chemistry; and (4) the Bangur gabbro (~3.1 Ga), which defines an oblong intrusion, crosscutting the older igneous suites in the southern part of the complex, with a curvilinear NW-trending apophysis, 2 km long and up to 40 m wide. Magmatic breccia comprising ultramafic and chromitite wall-rock clasts in a gabbro matrix is exposed at the contact of the main Bangur gabbro body and also forms the entire Bangur gabbro apophysis. Concentrations of platinum-group minerals (PGMs) are found where the breccia contains abundant chromitite clasts, and two types of platinum-group-element (PGE) mineralisation are recognised. Type 1 (Pt 1.1–14.2, Pd 0.1–2.1 ppm, with an average Pt/Pd=8–9) is a contact-type mineralisation which occurs in the breccia at the contact between the Bangur intrusion and its ultramafic host. The PGMs—Pt alloys (isoferroplatinum) and sulphides (braggite, malanite)—are enclosed by pyroxene and plagioclase, reflecting a magmatic origin. Significant wall-rock assimilation by the magma (giving rise to the Bangur gabbro) is indicated by changes in pyroxene composition and by the presence of relicts of chromite (from the host) now altered to secondary ferritchromite in the contact zone. Type 2 PGE mineralisation (Pt 0.3–1.6, Pd 1.8–6.0 ppm, with Pt/Pd~0.5–3.0) is restricted to the breccia apophysis of the Bangur gabbro where it occurs in the breccia matrix, associated with an intense hydrothermal alteration which does not exist in the contact zone. PGMs (PGE arsenides, tellurides, bismuthides and antimonides) and, where present, base-metal sulphides (BMSs) form intergrowths with hydrous silicates, reflecting a hydrothermal origin. Oxygen isotope geothermometry documents the main stages of hydrothermal alteration within a decreasing temperature range between 700–1,000 and 500–600 °C, and oxygen, hydrogen and sulphur isotopes show that the hydrothermal fluids were derived from the magma rather than an external source. Pervasive hydrothermal alteration in the breccia apophysis likely represents upward channelling of late-magmatic fluids along a narrow, near-vertical, subplanar conduit which led away from the main magma chamber. We suggest that Type 2 mineralisation was produced by late-magmatic hydrothermal remobilisation and reconcentration of Type 1 PGE mineralisation, and that the composition of the hydrothermal fluids controlled whether BMSs were enriched along with the PGMs.Editorial handling: P. Lightfoot 相似文献
993.
Y. ?KudohEmail author T. ?Kuribayashi A. ?Suzuki E. ?Ohtani T. ?Kamada 《Physics and Chemistry of Minerals》2004,31(6):360-364
The space group and hydrogen positions of -(Al0.84Mg0.07Si0.09)OOH are investigated using a single crystal synthesized using a multi-anvil apparatus under conditions of 1000 °C and 21 GPa. The space group determined by single-crystal X-ray diffraction is to Pnn2, with unit-cell parameters of a=4.6975(8) Å, b= 4.2060(6) Å, c=2.8327(4) Å, and V=55.97(1) Å3. Partial occupancy of the Al site by Mg and Si suggests the possibility of a limited solid solution between -AlOOH, stishovite, and a hypothetical CaCl2-type Mg(OH)2 that is 16% denser than brucite. Difference-Fourier maps reveal two small but significant Fourier peaks attributable to hydrogen atoms. Atomic distances and angles around the first peak indicate a hydrogen bond with O···O distances of 2.511 Å, while those around the second peak are suggestive of a bifurcated hydrogen bond with O···O distances of 2.743 and 2.743 Å. 相似文献
994.
Influence of Heterogeneity of Mechanical Properties on Hydraulic Fracturing in Permeable Rocks 总被引:11,自引:4,他引:7
T. H. Yang L. G. Tham C. A. Tang Z. Z. Liang Y. Tsui 《Rock Mechanics and Rock Engineering》2004,37(4):251-275
Summary Numerical simulations of circular holes under internal hydraulic pressure are carried out to investigate the hydraulic fracture initiation, propagation and breakdown behavior in rocks. The hydraulic pressure increases at a constant rate. The heterogeneity of the rocks is taken into account in the study by varying the homogeneity index. In addition, the permeability is varied with the states of stress and fracture. The simulations are conducted by using a finite element code, F-RFPA2D, which couples the flow, stress and damage analyses. The simulation results suggest that the fracture initiation and propagation, the roughness of the fracture path and the breakdown pressure are influenced considerably by the heterogeneity of rocks. The hole diameter elongation and the stress field evolution around the fracture tip during the fracture propagation can also provide useful information for the interpretation of the hydraulic fracturing behaviour. 相似文献
995.
This study deals with the methodical aspects of k
–2(Bernard et al., 1996) kinematic strong motions modelling: (1) it is shown how to incorporate the k-dependent rise time for 2D fault geometry in the strong motion synthesis according to the representation theorem, (2) it is suggested how to produce realistic k
–2 slip models including asperity(ies), (3) modifications are introduced concerning the typeof used slip velocity function and the corner wave number in the slip distribution. High frequency effects of these generalized models are discussed.It is shown that, assuming the rise time proportional to the spatial slip wavelength at high wave numbers, the spectral decay of displacement at frequencies higher than the corner frequency is given just by the decay ofthe slip distribution spectrum, regardless of the type of slip velocity function. It is shown numerically that this model provides -squared source spectrum even in a vicinity of a 2D normal fault buried in 1D structure, which is an agreement with previous studies. 相似文献
996.
The aim of this paper is to study the vadose zone dynamics during a hydrological cycle. The application of the Time Domain Reflectometry (TDR) method to determine the water content of porous rock has been widely investigated. More than 657 point measurements of rock water content observed during a hydrological cycle and distributed among three abandoned underground quarries in Gironde, France show a permanently undersaturated limestone. Two periods of maximum water content correspond to two occurring effective precipitations. The dephasing and amplitude attenuation of the hydraulic wave with the depth can be modelled and explained by the physical properties of the porous medium. Maps of the spatial distribution of water content show the heterogeneity of water flow in a vadose zone. 相似文献
997.
998.
H.?Liu W. A.?Caldwell L. R.?Benedetti W.?Panero R.?JeanlozEmail author 《Physics and Chemistry of Minerals》2003,30(9):582-588
The high-pressure behavior of -Fe2O3 has been studied under static compression up to 60 GPa, using a laser-heated diamond anvil cell. Synchrotron-based angular-dispersive X-ray diffraction shows that the sample remains in the corundum structure up to 50 GPa, but with the appearance of coexisting diffraction lines from a high-pressure phase at pressures above 45 GPa. A least-squares fit of low-pressure phase data to an Eulerian finite-strain equation of state yields linear incompressibilities of K
a
0=749.5 (± 18.4) GPa and K
c
0= 455.7 (± 21.4) GPa, differing by a factor of 1.6 along the two directions. The enhanced compressibility of the c axis may lead to breaking of vertex- or edge-sharing bonds between octahedra, inducing the high-pressure phase transformation at 50 GPa. Analysis of linear compressibilities suggests that the high-pressure phase above 50 GPa is of the Rh2O3 (II) structure. Continuous laser heating reveals a new structural phase transformation of -Fe2O3 at 22 GPa, to an orthorhombic structure with a=7.305(3) Å, b=7.850(3) Å, and c=12.877(14) Å, different from the Rh2O3 (II) structure. 相似文献
999.
A computational study of oxygen diffusion in olivine 总被引:1,自引:1,他引:0
Atomistic modelling techniques are used to study the rate-determining steps that limit diffusion of oxygen in forsterite. The activation energies for diffusion parallel to all three crystallographic axes by the vacancy and interstitial mechanisms are calculated. The activation energy for extrinsic vacancy diffusion is predicted to be isotropic with a barrier height of 119 kJ mol–1. Conversely, in the interstitial case it is found to be anisotropic, with extrinsic activation energies that range between 94 and 178 kJ mol–1. The effect of intrinsic defects and two typical impurities, iron and hydrogen, upon diffusion is also considered. We find that the migration energy is slightly higher in iron-rich fayalite compared with forsterite and that the presence of hydrogen defects will not affect the diffusion mechanism. These observations lead us to reinterpret existing experimental results on oxygen diffusion in natural olivine. We suggest that at low oxygen partial pressure the mechanism observed is a vacancy mechanism, while at high oxygen partial pressure the mechanism is interstitial. We believe that this change in mechanism is mediated by iron redox reactions. Taking this process into account, we derive activation energies in excellent agreement with those found experimentally in natural samples of olivine. The anisotropy of activation barriers and hence the change in diffusion rates with temperature could be used to distinguish between the two mechanisms in future experimental work. 相似文献
1000.
M.?ZhangEmail author H.?Xu E. K. H.?Salje P. J.?Heaney 《Physics and Chemistry of Minerals》2003,30(8):457-462
The structural behavior of -eucryptite (LiAlSiO4) has been investigated using infrared (IR) spectroscopy over a temperature range of 20 to 900 K and FT-Raman spectroscopy at room temperature. IR reflectance measurements show that -eucryptite possesses high reflectivity in the far-IR region, as is consistent with its reported superionic conductivity along the c-axis. On heating, the Li-related IR bands near 246 and 300 cm–1 (with A2 symmetry) broadened and weakened dramatically, presumably as a result of Li+ positional disordering along the structural channels parallel to c. The disordering process appears to induce a framework distortion, as is evidenced by the broadening of some vibrations of Si(Al)–O with increasing temperature. A change in slope in the temperature dependence of the phonon frequency near 300 cm–1 and the linewidth of the 760 cm–1 band at 715 K indicates that Li becomes completely disordered above this temperature. In addition, the temperature dependence of the linewidth for the 760 cm–1 band exhibits an additional change in slope at 780 K, implying the existence of an intermediate state within this temperature range. The detailed structure of this intermediate phase, however, needs further study. Our IR data provide no indication of structural changes between room temperature and 20 K. 相似文献