治理地下水有机污染抽出处理技术影响因素分析

抽出处理技术是治理地下水有机污染简便易行的方法,文中的简要介绍抽出处理方法去除污染机制之后,着重分析了讨论了导致该方法去除地下水有机污染耗时及运行费用高昂的原因,在此基础上,对地下水有机污染抽出处理技术作出全面详尽的评述。     

Agroecological measures and circular economy strategies to ensure sufficient nitrogen for sustainable farming

Sustainable food systems face trade-offs between demands of low environmental pressures per unit area and requirements of increasing production. Organic farming has lower yields than conventional agriculture and requires the introduction of nitrogen (N) fixing legumes in crop rotations. Here we perform an integrated assessment of the feasibility of future food systems in terms of land and N availability and the potential for reducing greenhouse gas (GHG) emissions. Results show that switching to 100% organic farming without additional measures results in N deficiency. Dietary change towards a reduced share of animal products can aggravate N limitations, which can be overcome through the implementation of a combination of agroecological, circular economy and decarbonization strategies. These measures help to recycle and transfer N from grassland. A vegan diet from fully decarbonized conventional production performs similarly as the optimized organic scenario. Sustainable food systems hence require measures beyond the agricultural sector.     

Monitoring of organic pollutants in coastal waters of the Gulf of Gdańsk, Southern Baltic

This paper presents an overview of changes in organic pollution of coastal waters of the Gulf of Gdańsk (Baltic Sea). Toxic pollutants including volatile organic compounds (VOC), volatile organohalogen compounds (VOX), chlorophenols, phenoxyacids, polychlorinated biphenyls (PCBs) and polycyclic aromatic hydrocarbons (PAHs) were determined in seawater from the Gulf of Gdańsk coastal waters in the period 1996-2001. In the case of the Gulf of Gdańsk, non-conservative behaviour of VOC was observed due to random temporal and spatial of inputs along the Vistula estuary and to the dilution of VOC-enriched river water with seawater. The concentrations of VOX in seawater decreased throughout the period and the concentrations of VOX were in the range of few ng dm(-3) up to 250 ng dm(-3), similar to estuaries elsewhere. The average concentrations of chlorophenols and phenoxyacids were between 0.1 and 6.0 and 0.05 and 2.2 microg dm(-3), respectively. However, remarkably high concentrations of 2,4-dichlorophenol (6 microg dm(-3)) were obtained in samples collected from the Vistula River. Generally concentrations of PCBs did not exceed few ng dm(-3) with the exception of 1999, when all samples exhibited elevated concentrations of PCBs. In addition, higher concentrations of PCBs in the open sea compared to river waters suggested localised inputs. Due to the ability of most organic pollutants to bioaccumulate and biomagnify, especially the persistent organic pollutants, continued monitoring is of crucial importance for the health of marine life in the Gulf of Gdańsk.     

Synoptic Situations and Pollutant Concentrations in Fog Water Samples from the Milešovka Mt.

This contribution presents the results of chemical analyses of the fog and/or cloud water samples, which were collected at the Mileovka Mt. during the years 2000 and 2001. The study aims mainly at proving the dependence of pollutant concentration on the direction of the atmospheric steering flow. It is evident that the highest mean pollutant concentration in fog water appeared at the steering flow from south or at the flow with an east component. The lowest pollutant concentrations were reported during the synoptic situations with considerable west component of the steering flow. Furthermore, we compare the characteristic values of pollutant concentrations from the Mileovka Mt. with similar results from other sites abroad.     

Fauna of whale falls: systematics and ecology of a new polychaete (Annelida: Chrysopetalidae) from the deep Pacific Ocean

Vigtorniella flokati, a new species of polychaete worm associated with decaying whale remains, is described. Three separate V. flokati populations were sampled using submersibles: two associated with implanted gray whale carcasses in the San Diego Trough (1240 m depth) and the Santa Cruz Basin (1670 m) off California, and one from sperm whale and balaeanopterid bones implanted on the slope of Oahu, Hawaii at 1000 m. Extraordinarily large numbers of live specimens were observed and videotaped in situ using submersibles in the San Diego Trough and the Santa Cruz Basin. The populations on the carcass implanted for 4 months in San Diego Trough, and on the bones implanted for 2 years off Oahu, were composed only of small sized individuals (including juveniles). V. flokati most closely resembles the poorly known V. zaikai Kiseleva, 1992, described from the Black Sea. Forty-six morphological characters were used in a phylogenetic analysis of selected nereidiform polychaetes. The resulting most-parsimonious trees indicate sister taxon status between V. flokati and V. zaikai, and that this clade is sister to the putatively ancient polychaete clade Chrysopetalidae. Whale falls, which are intense point sources of organic enrichment at the deep-sea floor, pass through three successional stages. V. flokati appears to colonize the middle, “enrichment opportunist” stage, inhabiting organic-rich bones and sediments 4–24 months after carcass arrival. V. flokati exhibits remarkable behavior, clinging posteriorly to whale bones or nearby sediments to form a writhing carpet at densities exceeding 8000 m⁻². Its extraordinary abundance on whale falls, and apparent absence from other habitats, suggests it to be a whale-fall specialist. The precise feeding mechanism of the worm remains unknown, but we hypothesize that it may utilize dissolved organic carbon derived from the organic-rich setting of whale falls. The widespread occurrence of V. flokati on ephemeral, food-rich habitat islands in the Pacific suggests life-history strategies analogous to those for hydrothermal-vent and cold-seep species.     

风暴作用下渤海中污染物(COD)输运的研究

本文利用三维POM模式,分别就潮汐作用下和风暴作用下污染物输运进行了数值模拟;比较了两种驱动下渤海内污染物输运的差异。通过比较发现:风暴潮(尤其是寒潮)平均每年使渤海污染物总量的减少量是潮汐作用的3~4倍;每次风暴潮过程对渤海内污染物重新分布的作用与潮汐30天的作用是同量级的。所以,在研究渤海的污染物输运时,必须考虑风暴潮的作用,否则,会产生很大的误差。     

水文过程对河流悬移质化学组成的影响——以珠江流域为例

用等离子体原子发射光谱法（ICP-AES）分析了珠江马口站和三水站1997-1998年度3个典型水文时段径流悬移质中部分金属元素的含量，同时用元素分析仪测定了其中的有机碳、氮的含量，结果表明，在不同性质的水文动力条件下，流域侵蚀产出的河流悬移质的化学组成发生了变化，这主要缘于有机质在悬移质中所占质量分数的差别。汛期增强的水文动力主要表现为对流域土壤矿物的优先侵蚀，虽然有机质的总侵蚀量也同时增加，但在悬移质中的质量分数却相对减少，而在枯水期较弱的水文动力条件下，河流悬移质中有机质的质量分数增加，悬移质中的有机质对液相中的部分重金属元素产生较矿物更大的吸附作用。     

福建省海岛生物体的污染物含量及其评价

通过对福建省海岛的鱼类、贝类、甲壳类和藻类生物体中的Hg，Cu，Pb，Zn，Cd，六六六和DDT的测定，结果表明：福建省海岛周围海域的生物体没有受到Hg，Zn和六六六的污染；只有少量的鱼类受到Cu的污染；少量的鱼类和甲壳类受到Cd的污染；一部分甲壳类和贝类受到DDT的污染；甲壳类、鱼类受到Pb的污染较严重。     

Particulate barium fluxes on the continental margin: a study from the Alboran Sea (Western Mediterranean)

Particulate biogenic barium (bio-Ba) fluxes obtained from three instrumented arrays moored in the Alboran Sea, the westernmost basin in the Mediterranean Sea, are presented in this study. The mooring lines were deployed over almost 1 year, from July 1997 to May 1998, and were equipped with sediment traps at 500–700 m depth, 1000–1200 m depth and 30 m above the seafloor (1000–2200 m). The results obtained support the growing body of evidence that the relationship between particulate bio-Ba and Corg throughout the water column in margin systems is clearly different from this relation in the open ocean. In the Alboran Sea, the annual averaged bio-Ba fluxes range from 0.39 to 1.07 μmol m⁻² day⁻¹, with mean concentrations of 1.31–1.69 μmol g⁻¹ and bio-Ba/Corg ratios lower than in the open ocean. The low bio-Ba values obtained also indicate that calculating bio-Ba is extremely sensitive to the detrital Ba/Al ratio of each sample. The lithogenic Ba fraction in the Alboran Sea continental margin area contributes between 24% and 85% of the total Ba. Increased bio-Ba export efficiency was observed after periods of high primary productivity and suggests that the processes limiting the bio-Ba formation in the study area relate to settling dynamics of organic matter aggregates. Furthermore, the ballasting effect of the abundant lithogenic and carbonate particles may limit decomposition of organic matter aggregates and enhance the transfer of particles rich in Corg and relatively poor in bio-Ba to the deep seafloor. Lateral input of freshly sedimented biogenic material, including particulate bio-Ba, has been observed on the lower continental slope in the western Alboran Sea. These observations emphasize that the use of the bio-Ba as a proxy of export productivity from the surface ocean must be used cautiously in highly dynamic environments such as those in the Alboran Sea.     

A model study of influence of circulation on the pollutant transport in the Zhujiang River Estuary and adjacent coastal waters

A tracer model with random diffusion coupled to the hydrodynamic model for the Zhujiang River Estuary (Pearl River Estuary, PRE) is to examine the effect of circulations on the transport of completely conservative pollutants. It is focused on answering the following questions: (1) What role does the estuarine plume front in the winter play in affecting the pollutants transport and its distribution in the PRE? (2) What effect do the coastal currents driven by the monsoon have on the pollutants transport? The tracer experiment results show that: (1) the pollutant transport paths strongly depend on the circulation structures and plume frontal dynamics of the PRE and coastal waters; (2) during the summer when a southwesterly monsoon prevails, the pollutants from the four easterly river inlets and those from the bottom layer of offshore stations will greatly influence the water quality in Hong Kong waters, however, the pollutants released from the four westerly river-inlets will seldom affect the water quality of Hong Kong waters due to their transport away from Hong Kong; (3) during the winter when a northeasterly monsoon prevails, all pollutants released from the eight river gates will be laterally transported seaward inside the estuary and transport westward in the coastal waters along the river plume frontal zone. However, pollutants released from the surface layer of offshore stations near or east of the Dangan Channel will be carried into the coastal waters of Hong Kong by the landward component of the westward coastal current driven by the winter northeasterly monsoon. But the pollutants from the bottom layer of the offshore stations will be carried away from the offshore by the bottom flow driven by the northeasterly monsoon. This implies that only surface-released matter from offshore stations will affect the water quality of the coastal waters around Hong Kong during the winter when a northeasterly monsoon prevails.