Mobilisierbarkeit von hydrophoben organischen Schadstoffen in belasteten Böden und Abfällen. Teil I: Mobilisierbarkeit von PCB,PAK und n-Alkanen durch Lösungsvermittler

Mobilization Potential of Hydrophobic Organic Compounds (HOCs) in Contaminated Soils and Waste Materials. Part I: Mobilization Potential of PCBs, PAHs, and Aliphatic Hydrocarbons in the Presence of Solubilizing Substances When using an elution procedure for organic pollutants to estimate the leaching behaviour of contamined soils and waste deposits, the influence of organic matter in solids and eluates adequately has to be considered. In batch tests with a solid/liquid ratio of 1:10, various aqueous solutions were composed, the solubilizing effect of which can be attributed to ubiquitous natural compounds (e. g., phospholipids, humic and carbonic acids). These solutions were evaluated in regard to the mobilization of PAHs, PCBs, and aliphatic hydrocarbons in soil and waste samples. The results were compared with batch tests containing sodium dodecyl sulfate (SDS), the properties and applications of which are selected and optimized in order to simulate the chemical interactions between pollutant and solubilizing substances of natural sources. Under alkaline conditions, the part of eluated pollutants was high because of the release of humic substances indigenous to the sample. Low concentrations of phospholipids and humic acid could decrease the mobility of aliphatic hydrocarbons. The extend of HOC mobilization is affected by specific interdependences between solubilizing substances and reactive matter of the samples. For most samples, 5.0 g/L concentrated SDS solution was able to simulate the most effective natural solutizer potential in regard to the mobilization of PAHs, PCBs, and aliphatic hydrocarbons within the system of batch tests. Whereas elution with pure water caused significant deviations in pollutant composition and too low yields, the use of SDS effected à good conformity. Modified in such a manner, the elution procedure can follow DIN 38414 part 4, when loss of pollutants will be minimized; e. g., centrifugation is needed to separate phases.     

Effects of peat content,rainfall duration and aggregate size on soil crust strength

The effect of peat on crust strength was investigated using ten soils with organic matter levels ranging from 1-50 to 18-23 per cent. As peat content increased, the crust strength reduced. This occurred in spite of the inability of peat to increase the stability of soil aggregates. Peat reduced crust strength by acting as a mulch on the soil surface, thereby reducing breakdown of soil aggregates. Peat also formed a source of weakness on the soil, reducing crust formation. Using a factorial experiment involving a further seven soils with different levels of peat treatment, exposed to four rainfall durations and with two aggregate sizes, crust strength was described in terms of the direct effects and the interactions of these factors. Most of the crust strength values reduced with increasing peat content. For each soil, crust strength increased significantly with increasing rainfall duration. Crust strength was greater for the smaller aggregate size. The most significant interactions affecting crust strength were between soil and aggregate size, rainfall duration and aggregate size, and soil and rainfall duration in that order. These interactions were used to describe the effect of organic matter in form of peat on crust strength. For each soil and aggregate size, polynomial relationships were established to relate crust strength to total kinetic energy of rainfall.     

有机岩石学及其在油气评价中的应用

  简要介绍了有机岩石学研究方法的发展与特.点，系统的论述了这门新兴学科用于确定烃源岩成熟度、有机质类型，研究油气生成、运移与聚集等方面所取得的进展。
        

CaCO3生物矿化的研究进展——有机质的控制作用

生物CaCO₃是自然界分布最广泛的一类生物矿物,其组成除了无机相的CaCO₃外,还含有少量的有机质,包括水可溶(SM)和水不可溶有机质(IM),SM富含阴离子基团,是控制CaCO₃结晶的重要因素之一。通过有机—无机界面分子识别,有机质选择性地与CaCO₃晶体特定方向的面网相互作用,从而对CaCO₃的生长、形貌、多型及结晶学定向等产生明显的控制作用。有机—无机界面的分子识别机制包括静电、晶格几何匹配和立体化学互补等。仿生矿化的研究为进一步深入了解生物矿化的机理及制造高级复合材料提供了新的方法。     

京津冀地区冬半年污染传输特征及传输指数的改进

文章通过轨迹聚类、潜在源区分析等方法对京津冀地区冬半年污染物传输特征进行了分析,在此基础上对传输指数的构建方法进行了改进,并结合一次重污染天气过程分析了其作用。结果表明,对于北京、天津和石家庄,其重污染轨迹出现概率从高到低均为偏南路径、偏西路径、偏东路径和西北路径;在近地面高度上,西南和东南风的增强在大多时候成为北京的污染物传输通道,其中东南方向的污染物来源主要集中在大气低层;改进后的传输指数能够更好地反映外来传输作用对本地污染物浓度的影响,京津冀及周边地区的传输作用对北京、天津和石家庄等大城市的污染物浓度影响较明显,其中城郊及周边地区的近距离传输影响最为显著;合理应用传输指数可以对重污染天气的成因进行初步判断。     

Contribution of the Bacterial and Microphytobenthic Microflora in the Energetic Demand of the Meiobenthos in an Intertidal Muddy Sediment (Kerguelen Archipelago)

Abstract. An intertidal mud sediment in the Kerguelen Archipelago was sampled weekly from January 1982 to March 1983. Measurements were taken for organic matter (carbon and nitrogen) and biological (bacteria, microphytobenthos, and mciofauna) parameters. The sediment is rich in organic matter, with a mean organic carbon content of 130gC- m-². Benthic living components yield low mean biomasscs in relation to the total organic pool. Besides some marine inputs, the main allochthonous source was identified as terrestrial inputs. Benthic activities seemed strongly governed by food availability and not by temperature. Obvious seasonal changes in bacterial abundances (direct counts), primary production, and mciofauna distributions were observed. Photosynthctic production reached high values (up to 2275 mg C-m^-2-d^-1), reflecting the presence of a dense microphytobenthos. Preliminary energy budgets for two seasons (spring and winter) have been constructed. In both periods, the measured primary production can support the high mciofauna production.     

Fluxes of iron and manganese across the sediment–water interface under various redox conditions

Fluxes of dissolved forms of iron and manganese across the sediment–water interface were studied in situ in the Gulf of Finland and the Vistula Lagoon (Baltic Sea), and in the Golubaya Bay (Black Sea) from 2001 to 2005. Fluxes were measured using chamber incubations, and sediment cores were collected and sliced to assess the porewater and solid phase metal distribution at different depths. Measured and calculated benthic fluxes of manganese and iron were directed out of sediment for all sites and were found to vary between 70–4450 and 5–1000 µmole m^− 2 day^− 1 for manganese and iron, respectively. The behavior of the studied metals at various redox conditions in the near-bottom water and in the sediment was the main focus in this study. Our results show the importance of bottom water redox conditions for iron fluxes. We measured no fluxes at oxic conditions, intermediate fluxes at anoxic conditions (up to 200 μmole m^− 2 day^− 1) and high fluxes at suboxic conditions (up to 1000 μmole m^− 2 day^− 1). Total dissolved iron fluxes were generally dominated by iron(II). Contribution of iron(III) to the total iron flux did not exceed 20%. Obtained fluxes of manganese at all studied regions showed a linear correlation (r² = 0.97) to its concentration in the porewater of the top sediment layer (0–5 mm) and did not depend on dissolved oxygen concentrations of bottom water. Organically complexed iron and manganese were in most cases not involved in the benthic exchange processes.     

Effect of biodeposits from mussel culture on macroinvertebrate assemblages at sites of different hydrodynamic regime

The present study examined for differences in macroinvertebrate assemblage composition inside and outside of mussel farm sites experiencing different hydrodynamic regimes. Multivariate analysis revealed that there were significant differences in macroinvertebrate assemblage composition (averaged across seasons) between samples taken inside and outside of the two relatively low energy sites, whilst no such difference was observed for the relatively high energy site. Taxa that best discriminated between the dissimilarities observed in macroinvertebrate assemblage composition inside and outside farms were principally polychaetes (more abundant inside) and ophiuroids (more abundant outside). Sediment total organic matter and number of mussel shells were the parameters that best explained the difference in macroinvertebrate assemblage observed at the two relatively sheltered farm study sites. No taxa or environmental variables were particularly good at discriminating or explaining differences observed inside and outside the relatively high energy farm site. The present study indicates there is a relationship between the hydrodynamic regime of a farm site, organic enrichment of seabed sediments by mussel biodeposits, and a subsequent modification of the macroinverebrate assemblages. This finding has implications for the site selection of mussel farms in coastal environments.     

虾塘养殖中有机质自身污染速率及程度的研究

利用养殖期间水体中颗粒有机质垂直迁移通量，测定了虾塘自污速率；并以虾塘沉积物的Ｅｈ和Ｃｏｍ值为指标，结合其空间分布形式，初步探讨了虾塘中有机质污染程度。结果表明，新、旧虾塘尤其是不同养殖区域间的自污速率都存在明显差别；而沉积物中Ｅｈ和Ｃｏｍ值的垂直分布形式，则可能成为虾塘有机质污染程度的重要评估参数。     

筼筜湖纳潮排污对厦门西港水质的影响

本文据1988年8～11月共6个航次采用多船同步、浮子跟踪和化学监测相结合的方法所获得的资料,研完了筼筜湖纳潮排污污水对厦门西港水质影响的范围和污染程度。