超临界CO_2流体萃取土壤中污染物的应用研究进展

CO2在超临界状态下具有许多独特的物理化学性质,作为一种＂绿色＂溶剂,它具有无毒、无污染、易获取等优点。近年来,有关超临界CO2流体热力学相行为和溶解度性质的研究引起人们广泛的关注,与之密切相关的超临界流体萃取技术已在许多领域得到重视和发展。根据近年国内外运用超临界CO2流体对土壤中多环芳烃、多氯联苯、重金属等污染物的萃取应用,分析了温度、压力、共溶剂等因素对萃取效果的影响,通过与其他土壤修复技术的比较,展望了超临界流体萃取技术应用于土壤修复领域的可行性和研究方向。     

西藏冈底斯矿带南缘矽卡岩型铜矿床含矿岩体锆石U-Pb年龄及意义

西藏冈底斯矿带发育大量斑岩铜钼矿床及铜铅锌多金属矿床,形成斑岩铜矿带及多金属矿带。过去的工作表明,冈底斯带南部矿床同位素年龄多小于30Ma,形成于碰撞期后伸展环境。本文测定了冈底斯矿带南缘克鲁-冲木达矽卡岩型铜(金、钼)矿集区桑布加拉矽卡岩型铜(金)矿化岩体锆石LA-ICP-MSU-Pb年龄及锆石Ce4+/Ce3+比值。矿化岩体锆石U-Pb年龄:92.1±0.6Ma,MSWD=1.0,锆石Ce4+/Ce3+比值在90～562之间,平均值为287。锆石Ce4+/Ce3+比值和玉龙矿带含矿岩体锆石的比值基本一致,显示矽卡岩矿化岩体岩浆氧逸度较高。印度板块与欧亚板块碰撞时间在65～45Ma之间,桑布加拉矽卡岩型铜矿化岩体锆石U-Pb年龄表明冈底斯带不但发育碰撞期后大规模成矿作用,也发育与洋壳俯冲构造岩浆事件有关的成矿作用。这为冈底斯矿带洋壳俯冲有关矿床的寻找提供了依据。     

Moho depth variation beneath southwestern Japan revealed from the velocity structure based on receiver function inversion

The Philippine Sea plate is subducting under the Eurasian plate beneath the Chugoku-Shikoku region, southwestern Japan. We have constructed depth contours for the continental and oceanic Mohos derived from the velocity structure based on receiver function inversion. Receiver functions were calculated using teleseismic waveforms recorded by the high-density seismograph network in southwestern Japan. In order to determine crustal velocity structure, we first improved the linearized time-domain receiver function inversion method. The continental Moho is relatively shallow ( 30 km) at the coastline of the Sea of Japan and at the Seto Inland Sea, and becomes deeper–greater than 40 km–around 35°N and 133.8°E. Near the Seto Inland Sea, a low-velocity layer of thickness 10 km lies under the continental Moho. This low-velocity layer corresponds to the subducting oceanic crust of the Philippine Sea plate. The oceanic Moho continues to descend from south to northwest and exhibits complicated ridge and valley features. The oceanic Moho runs around 25 km beneath the Pacific coast and 45 km beneath the Seto Inland Sea, and it extends to at least to 34.5°N. The depth variation of the Moho discontinuities is in good qualitative agreement with the concept of isostasy. From the configurations of both the continental and oceanic Mohos, we demonstrate that the continental lower crust and the subducting oceanic crust overlap beneath the southern and central part of Shikoku and that a mantle wedge may exist beneath the western and eastern part of Shikoku. The southern edge of the overlapping region coincides with the downdip limit of the slip area of a megathrust earthquake.     

Numerical Simulation of CO2 Doubling Impacts on Regional Climate in Northwest China

A numerical study on CO2 doubling effects upon temperature and precipitation in NW China is conducted using an improved regional climate model, with the modeling data from a global climate model (Australian CSIRO R21L9) as the background. Results suggest that the doubling would lead to the rise of surface temperature in the project region, with the maximum occurring in southern Xinjiang Basin and eastern Qilian Mountains in contrast to a relatively smaller increase in northern Xinjiang and southern Shaanxi Provinces. On a seasonal basis the winter temperature warming is most pronounced while the autumn shows a relatively less signi cant rising trend. The study region experiences the greatest warming compared with other parts of the country. With CO2 content doubling, rainfall change varies from place to place in this region, with rainfall increase in the west, particularly in northern Xinjiang, in the vicinity of the Tianshan area, southwestern Qinghai, and Hexi area (west of the Yellow River of Gansu), as opposed to the eastern portion of NW China, where precipitation decreases. If CO2 concentration is doubled, most of the study region would receive more rainfall in spring, implying that spring drought would be alleviated while its eastern part would see varying-degree decreased precipitation in the other three seasons, especially in summer, suggesting that drought there would be intensified in summer and autumn, thereby exerting major influence on rain-fed agriculture there.     

Impure marbles from the UHP Brossasco-Isasca Unit (Dora-Maira Massif, western Alps): evidence for Alpine equilibration in the diamond stability field and evaluation of the X(CO2) fluid evolution

Two impure ultrahigh-pressure (UHP) marbles, a calcite marble with the peak assemblage Grt + Phe + Cpx + Rt + (Arg) and a dolomite marble with the peak assemblage Crn + Chl + Rt + Dol (±Arg), from the same lens from the polymetamorphic complex of the Brossasco-Isasca Unit (BIU) (southern Dora-Maira Massif) have been petrologically investigated and modelled by calculating P – T phase-diagram projections for H₂O–CO₂ mixed-volatile systems. Thermobarometric data obtained from the calcite marble suggest Alpine peak conditions in the diamond stability field (4.0 GPa at 730 °C), and allow reconstruction of the earlier portion of the Alpine retrograde P – T path, which is characterized by a significant decompression coupled with a moderate and continuous cooling to 650 °C at 2.50 GPa. The modelled fluid compositions at peak conditions point to 0.025 ≤  X (CO₂) ≤ 0.10 and X (CO₂) ≤ 0.0012 in the calcite marble and dolomite marble, respectively, suggesting fluid heterogeneity at the local scale and an internally buffered fluid evolution of the studied impure marbles. The lack of micro-diamond in the BIU marbles is explained by the very-low X (CO₂) values, which favoured relatively high f O₂-conditions, preventing the formation of diamond at the UHP peak metamorphic conditions.     

Reactive flow of mixed CO2–H2O fluid and progress of calc-silicate reactions in contact metamorphic aureoles: insights from two-dimensional numerical modelling

Previous models of hydrodynamics in contact metamorphic aureoles assumed flow of aqueous fluids, whereas CO₂ and other species are also common fluid components in contact metamorphic aureoles. We investigated flow of mixed CO₂–H₂O fluid and kinetically controlled progress of calc‐silicate reactions using a two‐dimensional, finite‐element model constrained by the geological relations in the Notch Peak aureole, Utah. Results show that CO₂ strongly affects fluid‐flow patterns in contact aureoles. Infiltration of magmatic water into a homogeneous aureole containing CO₂–H₂O sedimentary fluid facilitates upward, thermally driven flow in the inner aureole and causes downward flow of the relatively dense CO₂‐poor fluid in the outer aureole. Metamorphic CO₂‐rich fluid tends to promote upward flow in the inner aureole and the progress of devolatilization reactions causes local fluid expulsion at reacting fronts. We also tracked the temporal evolution of P‐T‐X_CO2conditions of calc‐silicate reactions. The progress of low‐ to medium‐grade (phlogopite‐ to diopside‐forming) reactions is mainly driven by heat as the CO₂ concentration and fluid pressure and temperature increase simultaneously. In contrast, the progress of the high‐grade wollastonite‐forming reaction is mainly driven by infiltration of chemically out‐of‐equilibrium, CO₂‐poor fluid during late‐stage heating and early cooling of the inner aureole and thus it is significantly enhanced when magmatic water is involved. CO₂‐rich fluid dominates in the inner aureole during early heating, whereas CO₂‐poor fluid prevails at or after peak temperature is reached. Low‐grade metamorphic rocks are predicted to record the presence of CO₂‐rich fluid, and high‐grade rocks reflect the presence of CO₂‐poor fluid, consistent with geological observations in many calc‐silicate aureoles. The distribution of mineral assemblages predicted by our model matches those observed in the Notch Peak aureole.     

含裂隙碳酸盐岩酸化中超临界CO2对虫孔生长的影响初探

酸化是一种广泛应用于碳酸盐岩储层的增渗改造技术,其基本原理是将酸液注入储层裂隙,通过溶蚀反应使矿物溶解形成虫孔等通道,从而提高储层的渗透性和生产效率。以往的研究主要聚焦于优化注酸条件以提高成孔效率,忽略了碳酸盐岩酸化副产物CO2的影响。本研究针对三个含单裂隙的碳酸盐岩试样,开展不同浓度盐酸溶液的酸化实验,监测试样渗透率的变化;并在试验前后分别进行裂隙表面形貌激光扫描和内部空隙CT扫描,基于扫描结果对比分析了注酸条件对溶蚀效果的影响。研究结果表明：在流速、酸液浓度与种类等条件相同的条件下,CO2是否进入超临界态对虫孔形态有重要影响;超临界CO2可有效促进虫孔的生长,生成窄而长的虫孔,并显著提高溶蚀效果,试样的渗透率可提高3~9倍;而在CO2未进入超临界态的条件下,溶蚀形态接近面溶蚀或锥形虫孔,未贯通试样,试验前后渗透率没有显著变化,这是因为酸化反应产生的气态CO2会阻碍酸液的流动,从而降低酸化效果。本文结果揭示了在酸化中正面利用副产物CO2的可能性,有助于对现有酸化工程方案的优化和提升。     

白垩纪—古近纪界限时期的陆地气候重建进展

白垩纪—古近纪(K-Pg)界限时期发生了地质历史中最严重的生物大灭绝事件之一,重建该时期气候演化历史及其对生态系统的影响对理解深时气候演化规律和预测未来气候变化都具有重要意义。相比海相剖面而言,基于陆相剖面的白垩纪—古近纪界限时期古气候重建研究开展较晚,相关成果缺乏系统总结和集成。本文系统回顾了全球陆相白垩纪—古近纪界限剖面的分布情况和事件年代学新进展,总结了基于以上剖面重建的定量古气候记录和德干火山喷发记录,建立了界限时期中纬度陆地年平均温度和大气CO₂浓度时间演化序列。陆相剖面分布相对集中且数量较少,中国是该时期陆相剖面发育最多的国家之一,多个盆地已经建立了德干火山喷发记录,在重建该时期陆地气候上具有很大潜力。基于陆相沉积物汞元素地球化学记录表明,德干火山作用导致了晚马斯特里赫特期变暖事件并触发了白垩纪末期生物大灭绝。中纬度陆地年平均温度重建结果显示马斯特里赫特期中期全球经历了～10℃的降温,到马斯特里赫特期晚期德干火山初始喷发前显著升温至～20℃,并在白垩纪—古近纪界限前后发生多次快速波动。尽管65～63 Ma之间陆地温度记录相对缺失,69～65 Ma之间重...     

三峡水库澎溪河春季水华期p(CO2)及影响因素分析

在三峡水库澎溪河回水区春季水华连续暴发期间(2010年4月10日至5月25日),对渠马至河口总计5个采样断面进行监测。结果表明水华期间水体叶绿素a(Chla),溶解氧(DO)及CO₂分压(p(CO₂))分层现象明显,表层水体受浮游植物光合作用的影响p(CO₂)较低,并且日照充足时,水体为CO₂的汇。研究期间表层水体p(CO₂)最小值出现在4月25日双江断面,为4.3Pa,吸收通量为-0.28 mmol/(m2·h)。p(CO₂)随水深迅速增加,并在10～15m趋于稳定。偏最小二乘回归分析(PLS)表明澎溪河水华期间,浮游植物的生长代谢是控制p(CO₂)的关键因素,水温与p(CO₂)负相关,但并不构成对p(CO₂)的绝对影响。通过引用Ep(CO₂)/ADO参数,观测到了澎溪河水体水华暴发的3个阶段,期间澎溪河表层水体经历了从碳汇到碳源最后又回到碳汇的过程。