Measurements of peroxyacetylnitrate in the marine boundary layer over the Atlantic

The atmospheric concentration of peroxyacetylnitrate (PAN) was measured during a cruise of the R.S. Polarstern from Bremerhaven (Germany) to Rio Grande do Sul (Brazil) in September/ October 1988. The measurements were made in-situ by a combination of electron capture gaschromatography with a cryogenic preconcentration step. The theoretical lower limit of detection (3) was 0.4 ppt. The mixing ratios of PAN varied by more than three orders of magnitude from 2000 ppt in the English Channel to less than 0.4 ppt south of the Azores (38° N). South of 35° N, PAN levels were below the detection limit, except at 30–31° S off the eastern coast of South America. Here, PAN mixing ratios of 10 to 100 ppt were detected in continentally influenced air masses. Detectable levels of PAN were mostly observed in air masses of continental or high northern origin. Changes in the wind directions were usually associated with substantial changes in the PAN mixing ratios.     

弹性波的三维有限元模拟

本文讨论了弹性波瞬态传播问题的三维有限元计算方法及当前存在的实际困难.针对要求计算机内存大和计算时间长的问题,采取了改进措施.由于采用了集中质量矩阵和修正的中心差分时间积分显格式相结合的方法,可以使计算机内存和计算时间大为减少;由于采用结点定位法,最适合用于目前发展的并行计算机系统,可使计算速度大大增快;还采用了有效激发震源法,有效激发区是随时间步进的增加而逐步增大,这不仅能节省计算时间,而且使波场的传播过程一目了然,本文计算了由两种介质组成的三维楔形问题,得到若干典型剖面的瞬时波场图及随时间变化的合成地震图.     

Seasonal variation of atmospheric dimethylsulfide at Amsterdam Island in the southern Indian Ocean

Daily measurements of atmospheric concentrations of dimethylsulfide (DMS) were carried out for two years in a marine site at remote area: the Amsterdam Island (37°50S–77°31E) located in the southern Indian Ocean. DMS concentrations were also measured in seawater. A seasonal variation is observed for both DMS in the atmosphere and in the sea-surface. The monthly averages of DMS concentrations in the surface coastal seawater and in the atmosphere ranged, respectively, from 0.3 to 2.0 nmol l^-1 and from 1.4 to 11.3 nmol m^-3 (34 to 274 pptv), with the highest values in summer. The monthly variation of sea-to-air flux of DMS from the southern Indian Ocean ranges from 0.7 to 4.4 mol m^-2 d^-1. A factor of 2.3 is observed between summer and winter with mean DMS fluxes of 3.0 and 1.3 mol m^-2 d^-1, respectively.     

Some breakage characteristics of ultra-fine wet grinding with a centrifugal mill

A centrifugal mill is a high-power intensity media mill that can be used for ultra-fine grinding, employing centrifugal forces generated by gyration of the axis of the mill tube in a circle. The mill charge motion is quite different depending on the ratio of the gyration diameter to the mill diameter (G / D ratio), varying from a motion similar to that of a conventional tumbling media mill to that of a vibration mill. In this study, a centrifugal mill was constructed with an arrangement where the gyration diameter could be readily adjusted. The batch grinding characteristics of three different minerals (limestone, talc and illite) in water with dispersing agent were investigated at various G / D ratios. It was found that the optimum G / D ratio in terms of the specific energy consumption to give a desired fineness of product was different for the three minerals. This was due to their different reactions to the breakage mechanisms provided by the mill charge motion at varying G / D ratios. The size distributions became progressively narrower at increased grinding times, and particles finer than about 0.1 μm were not detected even for prolonged grinding times. Measurement of specific surface areas indicated that this was not due to an artifact of the size measurements by laser diffractometry. This implies that there is a limitation in which particles finer than 0.1 μm are not produced under the conditions tested in this type of mill, but further investigation is needed for experimental verification of this limit of comminution.     

On the role of heat flow, lithosphere thickness and lithosphere density on gravitational potential stresses

Gravitational potential stresses (GPSt) are known to play a first-order role in the state of stress of the Earth's lithosphere. Previous studies focussed mainly on crust elevation and structure and little attention has been paid to modelling GPSt using realistic lithospheric structures. The aim of the present contribution is to quantify gravitational potential energies and stresses associated with stable lithospheric domains. In order to model realistic lithosphere structures, a wide variety of data are considered: surface heat flow, chemical depletion of mantle lithosphere, crustal thickness and elevation. A numerical method is presented which involves classical steady-state heat equations to derive lithosphere thickness, geotherm and density distribution, but additionally requires the studied lithosphere to be isostatically compensated at its base. The impact of varying surface and crustal heat flow, topography, Moho depth and crust density on the signs and magnitudes of predicted GPSt is systematically explored. In clear contrast with what is assumed in most previous studies, modelling results show that the density structure of the mantle lithosphere has a significant impact on the value of the predicted GPSt, in particular in the case of thick lithospheres. Using independent information from the literature, the method was applied to get insights in the state of stress of continental domains with contrasting tectono-thermal ages. The modelling results suggest that in the absence of tectonic stresses Phanerozoic and Proterozoic lithospheres are spontaneously submitted to compression whereas Archean lithospheres are in a neutral to slightly tensile stress state. These findings are in general in good agreement with global stress measurements and observed geoid undulations.     

Deep structure of the Nojima Fault, southwest Japan, estimated from borehole observations of fault-zone trapped waves

To estimate the deep structure of the southern part of the Nojima Fault, southwest Japan without the influence of near-surface structures, we analyzed the Love-wave-type fault-zone trapped waves (LTWs) recorded by a borehole seismometer at 1800 m depth. We examined the polarization, dispersion, and dominant frequency of the wavetrain following the direct S-wave in each seismogram to identify the LTW. We selected eight candidates for typical LTWs from 462 records. Because the duration of the LTW increases with hypocentral distance, we infer that the low velocity fault-zone of the Nojima Fault continues towards the seismogenic depth. In addition, since the duration of the LTW increases nonlinearly with hypocentral distance, we infer that the S-wave velocity of the fault-zone increases with depth. The location of events showing the LTW indicates that the fault-zone dips to the southeast at 75° and continues to a depth of approximately 10 km. We assumed a uniform low-velocity waveguide to estimate the average structure of the fault-zone. We estimated the average width, S-wave velocity, and Q_s of the fault-zone by comparing an analytical solution of the LTW with measured data. The average width, S-wave velocity, and Q_s of the fault-zone are 150 to 290 m, 2.5 to 3.2 km/s, and 40 to 90, respectively. Hence the fault-zone structure with a larger width and smaller velocity reduction than the fault-zone model estimated by previous surface observation is more suitable to represent the average fault-zone structure of the Nojima fault. The present study also indicated that the shallow layers and/or a shallow fault-zone structure drastically changes the characteristics of the LTW recorded at the surface, and therefore cause a discrepancy in the fault-zone model between the borehole observation and surface observation.     

冲击凿岩钎杆的瞬态动力学分析

以ANSYS为平台，按照真实工作状态对凿岩钎杆进行了瞬态动力学分析，并对不同活塞形状下分析结果数据进行了比较，为冲击凿岩系统设计提供了理论依据。     

Spatial and temporal variability of Holocene temperature in the North Atlantic region

The early Holocene climate of the North Atlantic region was influenced by two boundary conditions that were fundamentally different from the present: the presence of the decaying Laurentide Ice Sheet (LIS) and higher than present summer solar insolation. In order to assess spatial and temporal patterns of Holocene climate evolution across this region, we collated quantitative paleotemperature records at sub-millennial resolution and synthesized their temporal variability using principal components analysis (PCA). The analysis reveals considerable spatial variability, most notably in the time-transgressive expression of the Holocene thermal maximum (HTM). Most of the region, but especially areas peripheral to the Labrador Sea and hence closest to the locus of LIS disintegration, experienced maximum Holocene temperatures that lagged peak summer insolation by 1000-3000 years. Many sites from the northeastern North Atlantic sector, including the Nordic Seas and Scandinavia, either warmed in phase with maximum summer insolation (11,000-9000 years ago) or were less strongly lagged than the Baffin Bay-Labrador Sea region. These spatially complex patterns of Holocene climate development, which are defined by the PCA, resulted from the interplay between final decay of the LIS and solar insolation forcing.     

Abrupt climate change: An alternative view

Hypotheses and inferences concerning the nature of abrupt climate change, exemplified by the Dansgaard-Oeschger (D-O) events, are reviewed. There is little concrete evidence that these events are more than a regional Greenland phenomenon. The partial coherence of ice core δ¹⁸O and CH₄ is a possible exception. Claims, however, of D-O presence in most remote locations cannot be distinguished from the hypothesis that many regions are just exhibiting temporal variability in climate proxies with approximately similar frequency content. Further suggestions that D-O events in Greenland are generated by shifts in the North Atlantic ocean circulation seem highly implausible, given the weak contribution of the high latitude ocean to the meridional flux of heat. A more likely scenario is that changes in the ocean circulation are a consequence of wind shifts. The disappearance of D-O events in the Holocene coincides with the disappearance also of the Laurentide and Fennoscandian ice sheets. It is thus suggested that D-O events are a consequence of interactions of the windfield with the continental ice sheets and that better understanding of the wind field in the glacial periods is the highest priority. Wind fields are capable of great volatility and very rapid global-scale teleconnections, and they are efficient generators of oceanic circulation changes and (more speculatively) of multiple states relative to great ice sheets. Connection of D-O events to the possibility of modern abrupt climate change rests on a very weak chain of assumptions.     

中国能源安全与南海开发

二十一世纪是海洋经济时代。随着我国经济的发展,能源问题日益突出。由于我国陆上石油资源日益枯竭,海上石油开发成为我国能源的战略重点。南海陆架新生代地层厚约2000～3000m。第三纪沉积有海相、陆相及海陆交互相,具有良好的生油和储油岩系。南海扼海上要冲-马六甲海峡,南海航线是我国能源的海上生命线,具有不可替代的战略地位。我国南海资源和海域主权遭受到极大的侵犯。发展深海油气的勘探和开发技术,开发我国的南海深水石油资源,维护我国海域主权已经刻不容缓。优先进行南海石油开发是破解我国石油能源困局的必选战略。