Short term fluctuations in dissolved organic matter concentrations in streamflow draining a forested watershed and their relation to the catchment budget

Dissolved organic matter (DOM) concentrations in throughfall, throughflow, and runoff were recorded in a small (95 ha) woodland catchment in North Warwickshire for a period of eight weeks following a prolonged dry spell. DOM is shown to be positively related to stream discharge over the sampling period, although distinctive flushing effects were identified. The net contribution of DOM to total dissolved solids load carried in the river was only 2.4 per cent, and represented significantly less than published carbon losses by mineralization of soil organic matter. Throughfall inputs were some 100 times higher than streamflow outputs from the catchment.     

Impact of open-ocean convection on nutrients,phytoplankton biomass and activity

We describe the impact of an open-ocean convection event on nutrient budgets, carbon budget, elemental stoichiometry, phytoplankton biomass and activity in the Northwestern Mediterranean Sea (NWM). In the convective episode examined here we estimated an input of nutrients to the surface layer of 7.0, 8.0 and 0.4×10⁸ mol of silicate, nitrate and phosphate, respectively. These quantities correspond to the annual nutrient input by river discharges and atmospheric depositions in the Gulf of Lion. Such nutrient input is sufficient to sustain new primary production from 46 to 63 g C m⁻² y⁻¹, which is the same order of magnitude found in the NWM open waters. Our results together with satellite data analysis, propose new scenarios that explain the origin of the spring phytoplankton bloom occurring in NWM.     

乌梁素海冰封期湖泊冰盖组构特征对污染物分布的影响

为探究富营养化浅水湖泊季节性冰盖污染物分布规律,于2013-2014年冰封期,钻取乌梁素海湖泊冰盖冰芯试样,观测冰厚并对冰芯晶体结构、气泡含量、污染物浓度(总氮、总磷和COD_(Cr))进行分析.结果表明:冰盖可分为4层,中间2层冰晶体粒径较大且气泡含量较少,为冰盖热力生长区.冰盖以柱状晶体居多,粒径随深度增加而增加,气泡含量随冰盖密度增加而减少.冰盖结构特征与污染物分布具有相关关系,冰芯密度及气泡分布与总氮、总磷和COD_(Cr)相关关系分别为0.8965、0.8718、0.8184,并建立多元回归模型揭示冰封期湖泊水质特征,为季节性湖泊冰盖研究及冰封期湖泊水资源规划和管理提供理论依据.     

Characterization of nutrients in the atmospheric wet and dry deposition observed at the two monitoring sites over Yellow Sea and East China Sea

To investigate the atmospheric deposition of nutrients into the coastal and shelf regions of the northwest Pacific Ocean, observation sites were established upon Qianliyan Island (within the Yellow Sea) and the Shengsi Archipelago (within the East China Sea), respectively. Nutrient concentrations, including , were determined in both aerosols and rainwater samples. The analytical results contain clear seasonal signatures, with high values during the dry season and low values during the rainy season. Similar trends are observed for deposition fluxes. The amount of wet deposition is greater than that of dry deposition for the studied nutrient species. The influence of meteorological factors such as rainfall means that samples from Qianliyan Island record higher nutrient values than those from Shengsi. Along with riverine inputs, atmospheric deposition plays an important role in determining the biogeochemistry of nutrient species in coastal and shelf oceans. An erratum to this article can be found at     

Suspended basaltic glass–seawater interactions

The objective of this study was to quantify by experiments the initial seawater–suspended basaltic glass interactions following the 1996 outburst flood from the Vatnajökull glacier, Iceland. The altered basaltic glass dissolved in seawater as recorded by the Si release from the glass. The dissolved concentrations of Na, Ca, Si, Ba, Cd, Co, Cu, Hg, Mn, Ni and total dissolved inorganic N increased with time but the concentrations of Mg, K, S, Sr, Fe, Pb and Zn decreased. Calculated 1 to 10 day fluxes for Si range from 38,000 tons/day to 70,000 tons/10 days. The fluxes for other major elements are more uncertain, but the positive flux (release from suspended matter to seawater) of Ca and Na, and negative flux of Mg, K and S are greater than the Si flux.     

基于改进SWAT模型的灌溉—施肥—耕作对乌梁素海流域营养物负荷及作物产量的影响

不合理的灌溉、施肥和耕作是导致乌梁素海流域农业面源污染的主要根源,乌梁素海作为我国北方地区重要的生态安全屏障,多年来面临着湖泊水环境污染、水生态退化等问题,科学开展湖泊水环境综合治理首先要解决流域内农业面源污染问题.研究通过修改土壤水平衡、溶质平衡、地下水平衡和作物生长等模块对SWAT 2012原始版本进行改进,并采用改进的SWAT模型构建了乌梁素海流域分布式水文模型,利用实测径流、硝态氮与总磷排放量、地下水埋深以及作物产量校正和验证模型.基于现状情景,以玉米、葵花和小麦3种主要作物为研究对象,设置了削减灌水量、施肥量及调整耕作方式3种农田管理情景.基于改进SWAT模型不同情景的模拟结果,计算分析各管理情景下的硝态氮与总磷负荷及对各作物产量的影响.结果表明,改进SWAT模型具有良好的模拟效果.不同作物削减5%夏灌水量增产最多达8.41%～10.32%,削减10%秋浇水量均明显减少硝态氮和总磷负荷.不同作物营养物负荷均随着氮磷施肥削减比例的增大呈现逐渐降低的趋势,但下降曲线逐渐趋于平缓;各作物产量随氮磷施肥削减比例的增加呈先增加后减少的趋势,其中玉米、小麦氮磷施肥削减比例达20%时产量开...     

铁假说和HNLC海区的现场铁加富实验

20世纪90年代,JohnMart in提出的"铁假说（ironhypothesis）"和以此为中心的海洋铁加富实验（ironenrichments）成为海洋科学领域最受瞩目的事件。"铁假说"的主要内容是：铁限制了HNLC海区中浮游生物的生产力,并进而影响了CO₂由海洋上层向深层的输出;如果在HNLC海区加入铁,就可以促进浮游植物的生长,消耗掉过剩的 N、P营养盐,加速C从海洋表层向深层输出,最终降低大气中CO₂含量,缓解温室效应。在赤道太平洋和南大洋进行的现场加富实验证明,加入铁以后,这些海区的浮游植物生物量增加,N、P等营养盐被消耗。但是,这些实验并没有降低大气中CO₂含量。铁假说只被证实了一半。     

Intra-annual variability in nutrients in the Godavari estuary,India

Daily variations in nutrients were monitored for 15 months (September 2007–November 2008) in the Godavari estuary, Andhra Pradesh, India, at two fixed locations. River discharge has significant influence on nutrients loading to the estuary, which peaks during June–August (peak discharge period; monsoon) whereas exchanges at the sediment–water interface, groundwater and rainwater contribute significantly during other period. Despite significant amount of nutrients brought by discharge to the study region, phytoplankton biomass, in terms of chlorophyll-a (Chl a), did not increase significantly due to high suspended load and shallow photic depth. Nutrients showed downward gradient towards downstream of the estuary from upstream due to dilution by nutrient poor seawater and biological uptake. The N:P ratios were higher than Redfield ratio in both upstream and downstream of the estuary during no discharge period suggesting PO₄ to be a limiting nutrient for phytoplankton production, at levels <0.10 μmol L⁻¹. On the other hand, Si:N ratios were always more than unity during entire study period at both the stations indicating that Si(OH)₄ is not a limiting nutrient. Our results suggest that suspended matter limits phytoplankton biomass during peak discharge period whereas PO₄ during no discharge period.     

Variations of foliar carbon isotope discrimination and nutrient concentrations in Artemisia ordosica and Caragana korshinskii at the southeastern margin of China’s Tengger Desert

Seasonal variations in foliar stable carbon isotope discrimination (Δ) of Artemisia ordosica and Caragana korshinskii and correlations of foliar Δ with N, P, and K concentrations were studied under different planting regimes at the southeastern margin of China’s Tengger Desert. Foliar Δ, N, P, and K concentrations and the correlations of Δ with N, P, and K differed between the species and planting regimes. Foliar Δ, P and K concentrations in A. ordosica were markedly higher than in C. korshinskii, while foliar N concentrations in C. korshinskii was significantly higher than in A. ordosica. There were no significant differences in N, P, and K concentrations in C. korshinskii between planting regimes, but foliar Δ was significantly increased after June in mixed-species planting. In A. ordosica foliar N concentrations in mixed-species planting and foliar Δ in single-species planting were significantly higher than those of corresponding planting regimes. According to water-use efficiency (WUE) calculated based on foliar Δ, and on N, P, and K concentrations, C. korshinskii’s survival may profit from its higher WUE, whereas A. ordosica can avoid drought damage by its higher P and K concentrations in leaves in arid or semi-arid environments. The complex correlations of foliar Δ with foliar N, P and K suggested that water in C. korshinskii and water and P nutrition in A. ordosica were the key factors limiting their growth.     

Submarine groundwater discharge enhances primary productivity in the Yellow Sea,China:Insight from the separation of fresh and recirculated components

Submarine groundwater discharge(SGD)is being increasingly recognized as a significant source of nutri-ent into coastal waters,and generally comprises two components:submarine fresh groundwater dis-charge(SFGD)and recirculated saline groundwater discharge(RSGD).The separate evaluation of SFGD and RSGD is extremely limited as compared to the conventional estimation of total SGD and associated nutrient fluxes,especially in marginal-scale regions.In this study,new high-resolution radium isotopes data in seawater and coastal groundwater enabled an estimation of SGD flux in a typical marginal sea of the Yellow Sea.By establishing 226Ra and 228Ra mass balance models,we obtained the SGD-derived radium fluxes,and then estimated the SFGD and RSGD fluxes through a two end-member model.The results showed that the total SGD flux into the Yellow Sea was equivalent to approximately 6.6 times the total freshwater discharge of surrounding rivers,and the SFGD flux accounted for only 5.2％-8.8％of the total SGD.Considering the nutrient concentrations in coastal fresh and saline groundwater,we obtained the dissolved inorganic nutrient fluxes(mmol m-2 yr-1)to be 52-353 for nitrogen(DIN),0.21-1.4 for phosphorus(DIP),34-226 for silicon(DSi)via SFGD,and 69-262 for DIN,1.0-3.9 for DIP,70-368 for DSi via RSGD,with the sum of nutrient fluxes equaling to(1.8-9.3)-fold,(1.3-5.6)-fold and(2.0-9.5)-fold of the riverine inputs.Compared to the conventional estimation of the total SGD flux,the nutrient fluxes derived from the separation of SFGD and RSGD were(1.6-2.1),(1.6-1.8)and(4.0-4.9)times lower for DIN,DIP and DSi,respectively,indicating that the estimates by separating SFGD and RSGD could be conservative and representative results of the Yellow Sea.Furthermore,we suggested that SGD played an important role in nutrient sources among all the traditional nutrient inputs sources,providing 15％-48％,33％-68％and 14％-43％of the total DIN,DIP and DSi input fluxes into the Yellow Sea,and the high nutrient stoichiometric ratios(i.e.,DIN/DIP)in SGD probably contributed to the increasing ratios in the Yellow Sea.In addition delivering large amounts of nutrient into the Yellow Sea,SGD would create primary productivity of 10-49,1.6-6.8 and 8.8-42 g C m-2 yr-1 based on N,P and Si,which were equivalent to 5.2％-27％,0.9％-3.7％and 4.7％-23％of the total primary productivity,respectively.In par-ticular,the SFGD-derived DIN flux can be converted to primary productivity of 4.2-28 g C m-2 yr-1 thus demonstrating the disproportionately large role of SFGD in ecological environment of the Yellow Sea rel-ative to its flux.Therefore,we conclude that SGD,particularly SFGD,plays an important role as a nutrient source for the Yellow Sea,and not only affects nutrient budgets and structures but also enhances the pri-mary productivity.