Groundwater mixing between different aquifer types in a complex structural setting discerned by elemental and stable isotope geochemistry

Karst aquifers are well known for their intricate stratigraphy and geologic structures, which make groundwater characterization challenging because flowpaths and recharge sources are complex and difficult to evaluate. Geochemical data, collected from ten closely spaced production wells constructed in two karst aquifers (Bangor Limestone (Mb) and Tuscumbia Limestone/Fort Payne Chert (Mftp)) in Trussville, north‐central Alabama, illustrate two distinctive groundwater end‐members: (1) higher major ion, dissolved inorganic carbon, conductivity, alkalinity concentrations, heavier δ¹³C ratios (max: −10.2 ± 0.2‰ Vienna Pee Dee Belemnite (PDB)) and lower residence times (mean: 19.5 ± 2 years, n = 2) of groundwater in the Mb aquifer and (2) lower constituent concentrations, lighter δ¹³C ratios (min: −13.4 ± 0.2‰ PDB) and longer residence times of groundwater (mean: 23.6 ± 2 years, n = 4) in the Mftp aquifer. Summer and fall data and the binary mixing model show aquifer inter‐flow mixing along solution fractures and confirms the distinctive groundwater geochemistry of the two aquifers. Lowering of static water levels over the summer (drawdown from 2 to 5.2 m) leads to more reducing groundwater conditions (lower Eh values) and slightly enriched δ¹⁸O and δD ratios during the fall [δ¹⁸O: −4.8 ± 0.1 to −5.4 ± 0.1‰ Vienna Standard Mean Oceanic Water (VSMOW), n = 9; δD: −25.4 ± 1 to −27.4 ± 1‰ VSMOW, n = 9] when compared with summer season samples (δ¹⁸O: −5.1 ± 0.1 to −5.7 ± 0.1‰ VSMOW, n = 11; δD: −25.0 ± 1 to −30.6 ± 1‰ VSMOW, n = 11). GIS analyses confirm the localized origin of recharge to the investigated aquifers. The combination of GIS, field parameters and geochemistry analyses can be successfully used to identify recharge sources, evaluate groundwater flow and transport pathways and to improve understanding of how groundwater withdrawals impact the sustainability and susceptibility to contamination of karst aquifers. Copyright © 2015 John Wiley & Sons, Ltd.     

Earth pillar formation on the Mountain Pine Ridge,Belize

The roadcuts of Belize's Mountain Pine Ridge feature numerous coarsely textured earth pillars less than 10 cm in height. Preferential impregnation of iron occurs over a buried pebble resulting in a dripline. The higher concentration of iron along the buried pebble's dripline is later oxidized and exposed to the surface by rainsplash erosion. For slopes greater than five degrees, the intensity of sheetwash erosion is great enough to remove pillars. Earth pillar genesis thus seems a function of laterization, slope angle, and sheetwash intensity.     

Gakkel洋中脊基底隆起的非对称地壳结构

超慢速扩张的北冰洋Gakkel洋中脊具有六个沿扩张方向的线性基底隆起（本文编号为A-F）.这些线性基底隆起在中轴两侧的地球物理场和地壳结构呈现不同程度的非对称性.本文利用Gakkel洋中脊的地形、空间重力异常（FAA）和航空磁力数据,计算了它的扩张速率、剩余地幔布格重力异常（RMBA）、地壳厚度和非均衡地形.根据中轴两侧地形和地壳厚度的对称关系,我们将六个基底隆起分为对称型和非对称型两种类型.整体上,B、D和F区基底隆起在中轴两侧的地形和地壳厚度的非对称幅值（两侧差值的绝对值）较小,其中地形的非对称幅值分别为~157 m、~125 m、~208 m,地壳厚度的非对称幅值分别为~1 km、~0.06 km、~0.3 km;而A、C和E区的非对称幅值较大,其中地形的非对称幅值分别为~510 m、~410 m、~673 m,地壳厚度的非对称幅值分别为~2 km、~2.5 km、~1.1 km.我们因此推断B、D和F区具有相对对称的地壳结构,而A、C和E区具有非对称的地壳结构.根据A、C和E区中轴两侧非均衡地形的对称关系和非对称地形的补偿状态,推测A区的非对称性可能是由岩浆分配不均所导致;而C区和E区的非对称性可能是由构造断层作用使断层下盘向上抬升变薄所导致.我们进一步推测洋中脊走向的改变可能使得构造作用更易集中于基底隆起的一侧.

     

Crystal morphologies in pillow basalts: implications for mid-ocean ridge processes

We present the results of a detailed petrological study of a sparsely phyric basalt (MAPCO CH98-DR11) dredged along the Mid-Atlantic Ridge (30°41′N). The sample contains microphenocrysts of olivine that display four different rapid-growth morphologies. Comparison of these morphologies with those obtained in dynamic crystallization experiments allows us to constrain the thermal history of the sample. The dendritic morphology (swallowtail, chain and lattice olivine) is directly related to the final quenching during magma–seawater interaction. In contrast, the three other morphologies, namely the complex polyhedral crystal, the closed hopper and the complex swallowtail morphology result from several cycles of cooling–heating (corresponding to a maximum degree of undercooling of 20–25°C) during crystal growth. These thermal variations occurred before eruption and are interpreted to be the result of turbulent convection in a small magmatic body beneath the ridge. The results suggest that the Mid-Atlantic Ridge is underlain by a mush zone that releases batches of liquid during tectonic segregation. Aphyric basalts are emitted during eruptions controlled by the tectonic activity, whereas phyric basalts correspond to small fractions of magma from the mush zone mobilized by reinjections of primitive magmas.     

Seismic reflection imaging of an oceanic detachment fault: Atlantis megamullion (Mid-Atlantic Ridge, 30°10′N)

We present multichannel seismic reflection data collected over the Atlantis megamullion, at the eastern ridge-transform intersection of Atlantis fracture zone on the northern Mid-Atlantic Ridge, and over its conjugate crust. These data image for the first time the internal structure of a young, well-developed megamullion dome formed by tectonic extension across a long-lived oceanic detachment fault. The exposed, corrugated detachment-fault surface exhibits a sharp, coherent reflection that contrasts with less organized reflectivity of surrounding basaltic seafloor. At the termination of the megamullion the fault is imaged ∼13 km along-strike beneath a volcanic hanging-wall block at a sub-seafloor depth of 0.2-0.5 s two-way travel time, reaching north as far as 30°19′N. The eastward dipping of the fault beneath the hanging-wall block is estimated to be ∼6-14°. The corrugated fault surface is underlain by a continuous, strong, and relatively smooth reflection (D) at 0.2-0.25 s sub-bottom below the central axis of the dome. This reflection deepens up to 0.6 s sub-bottom beneath the western slope and it appears to intersect the seafloor on the eastern slope. We suggest that Atlantis massif formed by sequential slip on two different detachment faults that merged at depth, with breakaways as little as ∼2 km apart. The initial detachment is represented by reflection D, and the second corresponds to the presently exposed fault surface. In this interpretation, much of the sliver between the faults is interpreted to be strongly serpentinized peridotite with reduced seismic velocity; it lies in contact with less altered, higher-velocity mantle below the first detachment, resulting in the strong, smooth character of reflection D. Mantle rocks exposed in the megamullion indicate that the feature formed during a period of extreme tectonic extension and probably limited magmatism. In conjugate crust corresponding to termination of the megamullion, observed sub-bottom reflections are interpreted as base of seismic layer 2A. This layer is as thick as or thicker (∼570-900 m) than layer 2A in normal Atlantic crust, and it suggests that relatively normal crustal accretion occurred by the time the megamullion stopped forming.     

The Statherian itabirite-bearing sequence from the Morro Escuro Ridge,Santa Maria de Itabira,Minas Gerais,Brazil

The itabirite-bearing metasedimentary sequence from Morro Escuro Ridge comprises the basal units of the Espinhaço Supergroup and makes up a small tectonic inlier developed during one of the Brasiliano orogenic events (800-500 Ma), amongst horses of the Archean TTG gneisses, including sheared granites of the anorogenic Borrachudos Suite (∼1700 Ma). The metasedimentary rocks are comprised of low-to intermediate-amphibolite facies schists, quartzites, conglomerates and banded iron formation (itabirite) correlatable with the sequences of the Serro Group, which underlies the metasedimentary rocks of the Espinhaço Supergroup in the Serra da Serpentina Ridge. A maximum Statherian deposition age (1668 Ma) was established using SHRIMP U–Pb isotopic constraints on zircon grains from conglomerate and quartzite units overlying the itabirite. The itabirite is predominantly hematitic and its geochemical characteristics are typical of a Lake Superior-type BIF deposited in a platformal, suboxic to anoxic environment distant from Fe-bearing hydrothermal vents. Close to the contact zone with amphibolites of the Early Neoproterozoic Pedro Lessa mafic suite, an increase of the magnetite content and crystallization of metasomatic Mg-hornblende and Ce-allanite can be observed. These mineralogical changes developed preferentially along the igneous contact zone but are probably co-genetic with the formation of alteration haloes in zircon grains during the Neoproterozoic Brasiliano orogeny (506 ± 6 Ma).     

中印度洋脊Edmond热液区黄铁矿的标型特征及其对海底成矿作用环境的指示

对中印度洋脊Edmond热液区的丘顶和丘坡进行电视抓斗取样,获得了大量的金属硫化物等热液作用产物样品。在进行细致的矿相学分析基础上,对硫化物中黄铁矿的标型特征及其演化进行了详细研究。结果表明,Edmond热液区的黄铁矿可分3种类型,其形态标型和成分标型分别具有以下特征:Ⅰ型:呈自形立方体状,S/Fe原子数比接近于2.00,微量元素具有高Cu,低Zn、As、Pb、Ni和Ag的特点,Cu/Zn值高,平均可达4.26;Ⅱ型:呈半自形立方体状,S/Fe原子数比平均2.03,具有高Zn、Co、低Cu的特点,Cu/Zn值(平均0.04)低;Ⅲ型:主要呈胶状、莓球状,S/Fe原子数比平均2.04,具有Ag、Pb、Zn、As元素富集的特点,Cu/Zn值介于前两者之间(平均1.09)。根据硫化物中矿物共生组合关系,认为这3类黄铁矿分别对应高温、中高温和低温成矿作用,黄铁矿的形态和成分能很好地指示热液区的成矿环境和成矿条件的演变。     

Metamorphic evolution of oceanic gabbros: recrystallization from subsolidus to hydrothermal conditions in the MARK area (ODP Leg 153)

The 117.38 m of gabbroic core drilled during the Ocean Drilling Program (ODP) Leg 153 at Sites 921 to 924 in the Mid-Atlantic Ridge (MAR) between 23 °N and the Kane Fracture Zone, exhibits a remarkable primary compositional heterogeneity, such as magmatic layering, intrusive contacts and late magmatic veining, which express a succession of magmatic events. Textural indicators suggest that the cooling of the crystal mush occurred in a dynamic environment, with infiltration of progressively evolved liquids. Magmatic features include random shape fabric and magmatic lamination; the subsequent deformational overprint occurred in subsolidus conditions. The ductile deformation, generally concentrated in discrete domains of the gabbro, is associated with continuous re-equilibration of the metamorphic assemblages of (1) olivine + clinopyroxene + orthopyroxene + plagioclase + ilmenite + Ti-magnetite, (2) olivine + clinopyroxene + plagioclase + ilmenite + Ti-magnetite + red hornblende. At lower temperatures brittle deformation prevails and subsequent fractures control the development of metamorphic assemblages: (3) clinopyroxene + plagioclase + red brown hornblende + Ti-magnetite + magnetite (?) + ilmenite, (4) plagioclase + brown hornblende + Ti-magnetite + magnetite + hematite + titanite ± Ti-oxide, (5) plagioclase + green hornblende + magnetite + titanite, (6) plagioclase + actinolite + chlorite + titanite + magnetite, (7) albite + actinolite + chlorite + prehnite ± epidote ± titanite and (8) albite + prehnite + chlorite ± smectite. Assemblages 1 to 8 express increasing water/rock ratios and decreasing degrees of recrystallization.

During the ductile phase, red hornblende is stable and its abundance increases with deformation intensity, possibly as an effect of the introduction of hydrous fluids. During the brittle phase, water diffusion controls the development of the fracture-filling mineral assemblages and re-equilibration of the adjacent rock; temperatures decrease further, as demonstrated by mineral zoning and incompletely re-equilibrated assemblages. The lowest temperatures correspond to the development of hydrothermal assemblages.

Compared with oceanic gabbros from fast-spreading transform environments, high-temperature ductile phases (granulite and amphibolite) are well developed, whereas brittle phases are widespread, as microcracks, prevalent on fracturing associated with discrete veins.     

Mineralogy, geochemistry, and Nd isotope composition of the Rainbow hydrothermal field, Mid-Atlantic Ridge

Petrological, geochemical, and Nd isotopic analyses have been carried out on rock samples from the Rainbow vent field to assess the evolution of the hydrothermal system. The Rainbow vent field is an ultramafic-hosted hydrothermal system located on the Mid-Atlantic Ridge characterized by vigorous high-temperature venting (∼365°C) and unique chemical composition of fluids: high chlorinity, low pH and very high Fe, and rare earth element (REE) contents (Douville et al., Chemical Geology 184:37–48, 2002). Serpentinization has occurred under a low-temperature (<270°C) retrograde regime, later overprinted by a higher temperature sulfide mineralization event. Retrograde serpentinization reactions alone cannot reproduce the reported heat and specific chemical features of Rainbow hydrothermal fluids. The following units were identified within the deposit: (1) nonmineralized serpentinite, (2) mineralized serpentinite—stockwork, (3) steatite, (4) semimassive sulfides, and (5) massive sulfides, which include Cu-rich massive sulfides (up to 28wt% Cu) and Zn-rich massive sulfide chimneys (up to 5wt% Zn). Sulfide mineralization has produced significant changes in the sulfide-bearing rocks including enrichment in transition metals (Cu, Zn, Fe, and Co) and light REE, increase in the Co/Ni ratios comparable to those of mafic Cu-rich volcanic-hosted massive sulfide deposits and different ¹⁴³Nd/¹⁴⁴Nd isotope ratios. Vent fluid chemistry data are indicative of acidic, reducing, and high temperature conditions at the subseafloor reaction zone where fluids undergo phase separation most likely under subcritical conditions (boiling). An explanation for the high chlorinity is not straightforward unless mixing with high salinity brine or direct contribution from a magmatic Cl-rich aqueous fluid is considered. This study adds new data, which, combined with the current knowledge of the Rainbow vent field, brings compelling evidence for the presence, at depth, of a magmatic body, most likely gabbroic, which provides heat and metals to the system. Co/Ni ratios proved to be good tools used to discriminate between rock units, degree of sulfide mineralization, and positioning within the hydrothermal system. Deeper units have Co/Ni <1 and subsurface and surface units have Co/Ni >1.