济南四大泉群附近补给路径及补给比例研究

济南地区岩溶大泉是集供水、旅游、生态等功能于一体的重要自然资源,但随着经济社会的快速发展,人类活动影响不断增强,各岩溶大泉受到水质劣化、流量衰减的威胁。为了明确济南四大泉群附近主要补给路径,更加科学合理的保护泉水资源,文章采用流速流向定量分析、地下水流场分析、水化学同位素分析、聚类分析、三端元混合比计算等研究方法,分析了济南四大泉群主要补给路径,定量计算了各泉群补给路径贡献比例。研究表明,四大泉群的主要补给路径可划分为西部、南部、东南部补给路径,每个泉群受到不同补给路径的混合补给作用,其中趵突泉、黑虎泉、五龙潭、珍珠泉泉群的主要补给来源分别为南部补给路径（流量占比40.21%）、东南部补给路径（流量占比47.42%）、西部补给路径（流量占比47.13%）、南部补给路径（流量占比51.04%）,研究工作可为我国北方岩溶大泉成因机制和生态保护提供参考。     

Formation and evolution of the Archean continental crust of China: A review

The mainland of China is composed of the North China Craton, the South China Craton, the Tarim Craton and other young orogenic belts. Amongst the three cratons, the North China Craton has been studied most and noted for its widely-distributed Archean basement rocks. In this paper, we assess and compare the geology, rock types, formation age and geochemical composition features of the Archean basements of the three cratons. They have some common characteristics, including the fact that the crustal rocks prior to the Paleoarchean and the supracrustal rocks of the Neoarchean were preserved, and Tonalite-Trondhjemtite-Granodiorite (TTG) magmatism and tectono-magmatism occurred at about 2.7 Ga and about 2.5 Ga respectively. The Tarim Craton and the North China Craton show more similarities in their early Precambrian crustal evolution. Significant findings on the Archean basement of the North China Craton are concluded to be: (1) the tectonic regime in the early stage (>3.1 Ga) is distinct from modern plate tectonics; (2) the continental crust accretion occurred mostly from the late Mesoarchean to the early Neoarchean period; (3) a huge linear tectonic belt already existed in the late Neoarchean period, suggesting the beginning of plate tectonics; and (4) the preliminary cratonization had already been completed by about 2.5 Ga. Hadean detrital zircons were found at a total of nine locations within China. Most of them show clear oscillatory zoning, sharing similar textures with magmatic zircons from intermediate-felsic magmatic rocks. This indicates that a fair quantity of continental material had already developed on Earth at that time.     

Meteoric diagenesis and dedolomite fabrics in precursor primary dolomicrite in a mixed carbonate–evaporite system

Dedolomitization is a common diagenetic process in shallow burial environments and is often associated with sulphates in mixed carbonate‐evaporite successions. In these settings, elevated Ca²⁺/Mg²⁺ ratios necessary for dedolomitization result from the dissolution of sulphate phases by the incursion of undersaturated groundwater. Reported dedolomite textures from other studies are varied, but the most prevalent is a rhombic texture interpreted to result from the partial to complete pseudomorphic replacement of secondary dolomite rhombs formed in the burial diagenetic realm. In this study of primary cryptocrystalline to finely crystalline dolomicrites in the Prairie Evaporite Formation of north‐eastern Alberta, dedolomitization has resulted in sutured to loosely packed mosaics of dedolomite that range from subhedral to distinctly euhedral (rhombic) crystal fabrics; however, no prior aggrading neomorphism producing dolomite rhombs is evident in the precursor dolomicrites. Non‐pseudomorphic dedolomitization of the dolomicrites results in textures that include rhombic dedolomite crystals with cloudy cores comprising remnant dolomicrite and clear rims. These textures are similar to those observed in the pseudomorphic dedolomitization of secondary dolomite rhombs. The Prairie Evaporite Formation of north‐eastern Alberta has experienced extensive karstification near the erosional margin of the sedimentary succession. Dedolomitization of dolomicrites occurs in marker beds within the Prairie Evaporite succession associated with evaporite karstification. Along with stratigraphic and petrographic considerations, stable isotope results support the interpretation of a shallow dedolomitization event influenced by meteoric waters derived from the basin margin. Negative δ ¹⁸O and low δ ¹³C values (averages of −13·6‰_VPDB and 0·5‰_VPDB, respectively) of the dedolomite, compared with those of the primary dolomicrite (averages of −6·0‰_VPDB and 1·2‰_VPDB, respectively), point to isotopically light diagenetic fluids. These results show that rhombic dedolomite textures can form through shallow, non‐pseudomorphic dedolomitization of dolomicrites by meteoric fluids in the presence of sulphates, with resulting textures that are similar to the pseudomorphic dedolomitization of secondary dolomite rhombs.     

The Late Pleistocene megafauna of the Chulym River basin,southeastern West Siberian Plain: chronology and stable isotope composition

New data were obtained for the Chulym River basin in the southeastern part of the West Siberian Plain, one of the understudied parts of Siberia in terms of age and composition of carbon and nitrogen stable isotopes for Late Pleistocene megafauna. The ¹⁴C dates from the Sergeevo outcrop, the most complete section of Late Quaternary deposits in the region, are mostly greater than ~30 550 bp. Other localities yielded ¹⁴C values in the range from >44 500 to ~19 300 bp. The finite date of ~42 270 bp for the Khozarian steppe elephant (Mammuthus trogontherii chosaricus) from Asino is intriguing because previously it was not detected in the Late Pleistocene of Siberia after the last interglacial (Marine Isotope Stage 5e), ~115 000–130 000 years ago. Stable isotope data show both similarities and differences compared to the pre-Last Glacial Maximum megafaunal species in other parts of Siberia.     

滇东南老君山矿集区北部长田W(Sn)矿床成矿时代：来自白钨矿和萤石 Sm- Nd同位素定年的制约

滇东南是我国重要的钨锡多金属成矿区,老君山矿集区是其重要组成部分,围绕燕山期老君山复式花岗岩体,分布有都龙、南秧田、新寨大型-超大型Sn-W多金属矿床及多个中小型矿床(点)。该区地质演化复杂,Sn、W多金属可能存在多期成矿作用,包括燕山期、印支期和加里东期。由于目前该区发现的Sn-W矿化多分布于老君山岩体南、东侧,而岩体北部Sn-W成矿作用的研究相对较薄弱,特别是成矿年代学方面,多数矿床依然缺少精确同位素年代学数据,制约了该区Sn-W多金属成矿作用的认识和地质勘探的深入。长田是老君山岩体北缘代表性W (Sn)多金属矿床,区内加里东期和燕山期花岗岩均有分布,由于缺少年代学数据和地质地球化学研究,W(Sn)成矿作用的认识尚缺少实际地质地球化学依据,难以建立合理的成矿模式,制约了区内地质勘探的深入和突破。基于此,本文通过对长田W (Sn)矿床中白钨矿及共生萤石的Sm-Nd同位素定年,分别获得97 Ma和79 Ma两个年代学数据,显示该矿床钨矿化主成矿期应为燕山晚期,与老君山花岗岩活动时限一致,表明长田钨成矿作用与燕山期老君山花岗岩的侵入活动关系密切,而与加里东期岩浆活动关系不大。该成果丰富了...     

Geology,Geochemistry, and Geochronology of the Fenghuangshan Skarn‐type Copper Deposit in the Tongling Ore Cluster,Anhui Province,East China

The Fenghuangshan skarn-type Cu deposit, Tongling Ore Cluster, Anhui Province, is an important component in the Middle–Lower Yangtze River ore-forming belt. To better understand magmatism and its relationship to mineralization, we investigated geochemical features, ore-forming fluids, and geochronology of the Xinwuli intrusion and the related Fenghuangshan Cu deposit. Lithogeochemical characteristics show that the Xinwuli quartz monzodiorite is formed by mixing magma derived from upper mantle alkaline basalt that has been contaminated by crust materials. C, H and O isotopes indicate that ore-forming fluids mainly come from the magma, with minor amounts of meteoric fluids involved at the late stage. S and Pb isotopic components indicate that ore-forming materials are derived from the mantle. Molybdenite Re–Os isotopic dating yields Re–Os model ages ranging from 139.1±2.4 Ma to 142.0±2.2 Ma, with an isochronal age of 141.1±1.4 Ma, which is consistent with sensitive, high-resolution ion microprobe (SHRIMP) zircon U–Pb ages of quartz monzodiorite and granodiorite in the mining area. Dating analysis yields ages from 136.0±2.0 Ma to 143.0±2.4 Ma for the quartz monzodiorite (a weighted average of 139.4±1.2 Ma) and ages from 136.7±2.0 Ma to 145.3±2.4 Ma for granodiorite (a weighted average of 141.0±1.1 Ma).     

Early Albian marine environments in Madagascar: An integrated approach based on oxygen,carbon and strontium isotopic data

New palaeotemperature reconstructions have been obtained on the basis of oxygen isotopic analysis of 178 aragonitic shell samples taken from specimens of three ammonoid orders (and some corresponding families): Phylloceratida (Phylloceratidae), Lytoceratida (Tetragonitidae) and Ammonitida (Oppeliidae, Desmoceratidae, Silesitidae, Cleoniceratidae and Douvilleiceratidae). Those obtained from aragonite shells, secreted in the lower epipelagic and in the middle mesopelagic zones during coolest season (winter), range from 15.4 to 16.8 °C, and from 11.8 to 12.0 °C, respectively. Presumed spring/autumn palaeotemperatures obtained from aragonite shells, secreted apparently in the upper and lower epipelagic, upper and middle mesopelagic zones, are somewhat higher. Presumed summer palaeotemperatures, calculated apparently for the upper and lower epipelagic, and upper mesopelagic zones range from 19.4 to 21.7 °C, from 17.7 to 19.4 °C, and from 14.4 to 16.1 °C, respectively. The predominant part of investigated ammonoids from Madagascar inhabited the epipelagic zone, but some phylloceratid, tetragonitid and silesitid ammonoids preferred deeper, cooler conditions (upper-middle mesopelagic zone). The study supports the hypothesis that Madagascar was located in middle latitudes within the tropical-subtropical climatic zone during the early Albian. Available carbon and strontium isotope data allow us to assume a more or less expressed carbon and strontium isotope stratification of the water column in this region in the early Albian. On the basis of the stable isotope data, following partly Lukeneder (2015), two large ethological groups can be recognised mainly in mid-aged and adult ammonoids. Some ammonoids (group 1) preferred apparently mesopelagic conditions, and to a lesser degree the epipelagic zone, being mainly cool-requiring animals. However, a significant part of the isotopically investigated ammonoids (group 2) preferred, on the contrary, only epipelagic conditions, being mainly thermophilic dwellers.     

Late Cenomanian environmental conditions at the submerged Tatric Ridge,Central Western Carpathians during the period preceding Oceanic Anoxic Event 2 – A palaeontological and isotopic approach

Micropalaeontological and isotopic studies of the upper Cenomanian turbiditic/hemipelagic sediments from the High-Tatric unit (Central Western Carpathians; Polish part of the Tatra Mountains) has been undertaken to characterize the sedimentary conditions in the Tatric basin, a part of the Western Tethys, related to the interval preceding the late Cenomanian oceanic anoxic event (OAE2). The deposition of these sediments, including organic-rich layers (TOC up to 0.7%), corresponds to the Rotalipora cushmani foraminiferal Zone. Microfacial, foraminiferal and palynological analyses show that the sea floor was located at upper bathyal depths and the water column was poorly oxygenated. The intrabasinal carbonate material indicates moderate primary productivity with rare periods of upwellings. The scarcity of marine fossils in redeposited material and features of carbonate lithoclasts suggest very low productivity in the nearshore surface water, most probably due to a low-density hyposaline cap as surface runoff from the southern margin of the basin. The carbon isotopic study documents the negative values of δ¹³C_carb in the whole section as an effect of transfer of isotopically light carbon sourced from various sources. Such negative values of δ¹³C_carb are characteristic of the upper Cenomanian sediments, deposited in relatively shallow water basins, characterized by input of terrestrial organic matter and/or carbonate particles known from the Western Interior sections, the Atlantic coastal plain, the northwestern African margin, the eastern margin of the Apulian Platform and shelf sediments in the NW Europe and Tethyan Himalayas. Most probably, all of these events could be related to the global sea level fluctuations that occurred ca. 95.5–94.5 Ma comparing with the Haq (2014) eustatic curve.     

The oxygen isotopic composition as an indicator of the genesis of “Basaltic” corundum

This paper reports an oxygen isotopic study of corundums and associated minerals from the Yogo lamprophyres (Montana, US), plagioclase-corundum inclusions in alkali basalt (Tunkin depression, Russia), and from modern alluvium of Podgelbanochnyi alkaline basaltic volcano (Primorye, Russia). It is shown that all sapphires genetically related to mafic magmatic rocks have a similar oxygen isotopic composition (the variations of δ¹⁸O are within 2.5‰) with most values plotting between +4.5 and +7.0‰ SMOW. The oxygen isotopic ratios in the associated minerals (olivines, pyroxenes, mica, and others) and host rocks are plotted in the same interval. This indicates that the sapphire crystallized during evolution of the parental mafic magma. However, there are xenogenic corundums, which were only transported by basaltic magma to the Earth’s surface. They have a sharply distinct oxygen isotopic composition, which suggests their disequilibrium with the host lavas, and, correspondingly, a different genetic nature.     

Geochemistry and potential use of groundwater in the Rocca Busambra area (Sicily, Italy)

In the Rocca Busambra area (mid-west Sicily, Italy), from November 1999 to July 2002, 23 water points including wells and springs were sampled and studied for their chemical and isotopic compositions. Two rain gauges were also installed at different altitudes, and rainwater was collected monthly to determine the isotopic composition. The obtained results revealed the Rocca Busambra carbonate complex as being the main recharge area on account of its high permeability value. From a chemical view point, two main groups of water can be distinguished: calcium–magnesium–bicarbonate-type and calcium–magnesium–chloride–sulphate-type waters. The first group reflects the dissolution of the carbonate rocks; the second group probably originates from circulation within flyschoid sediments. Three water wells differ from the other samples due to their relatively high Na and K content, which probably is to be referred to a marked interaction with the “Calcareniti di Corleone” formation, which is rich in glauconite [(K, Na)(Fe³⁺, Al, Mg)₂(Si, Al)₄O₁₀(OH)₂]. In accordance with WHO guidelines for drinking water (2004), almost all the samples collected can be considered drinkable, with the exception of four of them, whose NO₃ ⁻, F⁻ and Na⁺ contents exceed the limits. On the contrary, the sampled groundwater studied is basically suitable for irrigation.