The orientation and vibrational states of H2O in synthetic alkali-free beryl

 The polarized single-crystal Raman spectra of synthetic H₂O-containing alkali-free beryl were recorded at room and low temperatures, and the polarized single-crystal IR spectra at room temperature. The H₂O molecule in the channel cavities is characterized by a Raman-active symmetric stretching vibration (ν₁) at 3607 cm⁻¹ and an IR-active asymmetric stretch (ν₃) at 3700 cm⁻¹ at room temperature. At low temperatures this ν₃ mode is observed in the Raman. Weak ν₁ and ν₃ modes of a second type of H₂O are also observed in the Raman spectra but only at 5 K. The H⋯·H vector of the most abundant type of H₂O is parallel to the channel axis of beryl along [0 0 0 1]. The components of the polarizability tensor of the ν₁ mode of H₂O are similar to, but not exactly the same as, those of a free H₂O molecule. The Raman measurements indicate that the H₂O molecule is rotationally disordered around [0 0 0 1]. External translation and librational modes of H₂O could be observed as overtones with the internal H₂O-stretching modes. In the case of the librational motions, normal modes could also be observed directly in the Raman spectra at ∼200 cm⁻¹. The energies of the translational modes can be determined from an analysis of the overtones and are about 9 cm⁻¹ in energy (i.e., T_z). The energies of the librational modes are about 210 cm⁻¹ for R_x and 190 cm⁻¹ for R_y. Received: 8 April 1999 / Accepted: 5 April 2000     

挪威山地冰川上雪和粒雪中δ18O的解释及对区域气候的指示意义

Variations of δ18O in the snow which accumulates at a Nordic temperate glacier during the win-ter are not entirely eliminated after a few months of ablation in the following summer. Survive of isotopicsignals closely relates to the re-freezing capacity of snow accumulated in winter when its temperature wasbelow 0 ℃. The melt-water re-freezing ice layers formed in winter hindered subsequent melt-water percolation in summer when snow temperature was at melting point and, therefore, varied isotopic record wasreserved between these ice layers. The isotopic record in snow pack can provide an estimate of the ap-proximate trend of the most recent winter season temperatures. The relationship between regional tem-perature changes and δ18O values in the snow pack is affected by many natural factors, but 1989-1990 (aglacier balance year) winter air temperatures were reflected in the snow which remained on the glacierAustre Okstindbreen at an altitude of 1 350 m in July 1990. There was larger amplitude of variations ofδ18O values in the 4. 1 m of snow above the 1989 summer surface, but variations in the underlying firnwere relatively small. Melt water percolation modifies the initial variations of δ18O values in the snowpack. At a site below the mean equilibrium line altitude on Austre Okstindbreen, increased isotopic bom-ogenization within a ten-day period in July accompanied an increase of the mean δ18O value. Although theisotopic record at a temperate glacier is likely to be influenced by more factors than is that at polar glac-iers, it can provide an estimate of the approximate trend of recent local temperature variations.     

东海DGKS96－03岩心中微体化石的古海洋学特点、δ18O曲线与AMS14C测年

运用微体化石的研究结果辨识岩心不同的沉积阶段的沉积特征及古海洋学特点,并辅以δ18O曲线及AMS14C测年去探讨岩心的沉积时代。该岩心是1996年5月中国、法国、韩国科学家一起利用法国L’ATAIANTE号海洋调查船在东海陆架获取的17个岩心中的一个,分别做了粒度、矿物、CaCo2、微体化石、δ18O、AMS14C测年等分析,初步分析认为：依据微体化石的冷、暖水种的丰度变化,可以辨识出该岩心气候的7个冷期(C1、C2、C3、C4-1、C4-2、C5、C6、C7),然后结合岩心中的矿物成份、CaCo3含量、粒度变化、AMS14C的测年数据把岩心划分为4个沉积阶段,1．晚更新世早玉木冰期沉积。2．玉木亚间冰期沉积。3．晚更新世玉木冰期沉积。4．全新世冰后期沉积。另外,利用浮游有孔虫壳体对不同的沉积阶段所做的AMS14C测年结果分别为9690aBP、12980aBP,26350aBP,27960aBP,37410aBP,41260aBP．。     

塔里木盆地北部油气运移二维二相数值模拟分析

油气运移和聚集过程实际上是油（气）水饱和度知疏导层的变化过程，盆地中油（气）二相流动问题的研究就是对这一过程的定量描述，本项研究是在前人工作基础上，考察压实作用造成骨架变形来推导新的二维二相流动方程，它容描述异常压力演化与二相流动于一式，在模拟方法上采用有限分析的数值方法，这应用于新疆塔里木盆地北部地区，展示了该区异常压力、含水饱和度弥散状扩散效应以及流速场在地质历史时期动态模拟演化特征；指出了该     

应用碳、氦、氩同位素探讨济阳拗陷二氧化碳气成因

应用碳、氦、氩同位素和气体组分指标 ,以及流体包裹体测定等手段 ,结合济阳拗陷基本地质条件 ,提出二氧化碳气藏的二氧化碳气主要以幔源成因为主。     

Stratigraphy of the Cenomanian–Turonian Oceanic Anoxic Event OAE2 in shallow shelf sequences of NE Egypt

Two shallow water late Cenomanian to early Turonian sequences of NE Egypt have been investigated to evaluate the response to OAE2. Age control based on calcareous nannoplankton, planktic foraminifera and ammonite biostratigraphies integrated with δ¹³C stratigraphy is relatively good despite low diversity and sporadic occurrences. Planktic and benthic foraminiferal faunas are characterized by dysoxic, brackish and mesotrophic conditions, as indicated by low species diversity, low oxygen and low salinity tolerant planktic and benthic species, along with oyster-rich limestone layers. In these subtidal to inner neritic environments the OAE2 δ¹³C excursion appears comparable and coeval to that of open marine environments. However, in contrast to open marine environments where anoxic conditions begin after the first δ¹³C peak and end at or near the Cenomanian–Turonian boundary, in shallow coastal environments anoxic conditions do not appear until the early Turonian. This delay in anoxia appears to be related to the sea-level transgression that reached its maximum in the early Turonian, as observed in shallow water sections from Egypt to Morocco.     

Fluid inclusions in rocks from the amphibolite-facies gneiss to charnockite progression in southern Karnataka, India: direct evidence concerning the fluids of granulite metamorphism

Abstract Fluid inclusion studies of rocks from the late Archaean amphibolite-facies to granulite-facies transition zone of southern India provide support for the hypothesis that CO₂,-rich H₂O-poor fluids were a major factor in the origin of the high-grade terrain. Charnockites, closely associated leucogranites and quartzo-feldspathic veins contain vast numbers of large CO₂-rich inclusions in planar arrays in quartz and feldspar, whereas amphibole-bearing gray gneisses of essentially the same compositions as adjacent charnockites in mixed-facies quarries contain no large fluid inclusions. Inclusions in the northernmost incipient charnockites, as at Kabbal, Karnataka, occasionally contain about 25 mol. % of immiscible H₂O lining cavity walls, whereas inclusions from the charnockite massif terrane farther south do not have visibile H₂O Microthermometry of CO₂ inclusions shows that miscible CH₄ and N₂ must be small, probably less than 10mol.%combined. Densities of CO₂ increase steadily from north to south across the transitional terrane. Entrapment pressures calculated from the CO₂ equation of state range from 5 kbar in the north to 7.5 kbar in the south at the mineralogically inferred average metamorphic temperature of 750°C, in quantitative agreement with mineralogic geobarometry. This agreement leads to the inference that the fluid inclusions were trapped at or near peak metamorphic conditions. Calculations on the stability of the charnockite assemblage biotite-orthopyroxene-K-feldspar-quartz show that an associated fluid phase must have less than 0.35 H₂O activity at the inferred P and T conditions, which agrees with the petrographic observations. High TiO₂ content of biotite stabilizes it to lower H₂O activities, and the steady increase of biotite TiO₂ southward in the area suggests progressive decrease of aH₂O with increasing grade. Oxygen fugacities calculated from orthopyroxene-magnetite-quartz are considerably higher than the graphite CO₂-O₂ buffer, which explains the absence of graphite in the charnockites. The present study quantifies the nature of the vapours in the southern India granulite metamorphism. It remains to be determined whether CO₂-flushing of the crust can, by itself, create large terranes of largeion lithophile-depleted granulites, or whether removal of H₂O-bearing anatectic melts is essential.     

习水县岩溶水系统ρ(Sr2+)、ρ(Sr)/ρ(Ca)、ρ(Sr)/ρ(Mg)分布特征及其应用

通过对流域内不同类型水取样分析,发现流经不同岩层的地下水具有不同的ρ(Sr2+)、ρ(Sr)/ρ(Ca)、ρ(Sr)/ρ(Mg)值.一般来说,流经砂岩层的基岩裂隙水ρ(Sr2+)低,而ρ(Sr)/ρ(Ca)、ρ(Sr)/ρ(Mg)值较高,当砂岩中的基岩裂隙水受到灰岩岩溶水或煤系地层水补给时,其ρ(Sr2+)、ρ( Sr...     

西南岩溶地区植被喀斯特效应

西南岩溶地区是我国主要岩溶带之一，也是世界岩溶研究重点地区，区内因人口众多，植被破坏严重，部分地区因人为作用已经产生一系列的环境问题，本文从岩溶地区植被演替规律出发，针对不同植被生态条件，通过对比不同表层岩溶泉的水化学特征和表层土壤空气CO2（g)（表示呀以气相形式存在）的含量，分析了植被在岩溶区，特别在表层岩溶带的喀斯特效应，由此，一方面可以推动岩溶研究的进一步发展；另一方面可以提高人们的岩溶环境保护意识，从而为西南地区生态恢复提供基础资料。     

累托石的阳离子交换性能及其应用研究

累托石是二八面体云母层与蒙脱石层1:1规则间层矿物。本文阐明累托石矿物结晶构造与阳离子交换性能的关系。阳离子交换性能在累托石定量与定性、改型、合成交联累托石和有机累托石等方面的应用。并介绍氧化钛交联累托石和在机累托石的有关特性。