The role of porosity in the development of authigenic dolomite and palygorskite. An example in siliceous sandstones of continental origin in Western Spain

During the Tertiary, the Hercynian basement of the Iberian Peninsula was uneven due to Alpine tectonism which led to the development of a set of horsts and grabens forming its main geological structure. One of these grabens is the Ciudad Rodrigo Basin, located close to the Portuguese border. The south-western margin of this graben is filled with arkosic sandstones of continental origin that, once deposited, underwent important low-grade diagenetic processes related to the surface processes. The main diagenetic processes were hydrolysis, replacement by carbonate, and argillization to palygorskite. These three processes led to the differentiation of three main levels within the outcrops studied: (1) the Lower Level, where the original clayey sandstone outcrops, displaying fairly hydromorphic traits; (2) the Middle Level, where part of the clayey matrix has been replaced by dolomitic carbonate; and (3) the Upper Level, where palygorskite is the new neoformed clay. The change in porosity seems to have been the controlling factor, since it governs the dynamics of the solutions inside the rocks. These conditions changed from being diffusion-driven, at the start of the diagenesis, to flow-driven as porosity increased.     

INDUSTRIAL HERITAGE AND PLACE IDENTITY IN SPAIN: FROM MONUMENTS TO LANDSCAPES*

In Spain, the birth of interest in the nation's industrial heritage dates from the 1980s and occurred alongside the process of deindustrialization. Policies concerning derelict industrial sites have shifted gradually from destruction to preservation, rehabilitation, and enhancement, and industrial heritage enhancement projects are now widespread in the country. However, a clear mismatching has arisen between institutional and academic initiatives and local communities, which exhibit widespread disinterest in or even rejection of industrial remains. This problematic situation can be related to the utilization of industrial heritage as an economic resource without paying much attention to its connections with memory and identity. Also, the mismatching is due to a positivist approach to industrial heritage whereby the monument and the museum are prioritized. We argue that projects which consider industrial remains as part of cultural landscapes might shorten the gap between the institutional and economic side of industrial heritage and its identity‐building and popular facets.     

“GALICIA'S HURRICANE”: ACTOR NETWORKS AND ICONIC CONSTRUCTIONS*

Monumental constructions are created for a purpose, often as a symbolic representation of a particular vision of a people or a place. Spain's Cidade da Cultura, a museum conceptualized by Galicia's former president with the hubristic goal of creating a world icon, is one such example. Like many iconic constructions, the Cidade da Cultura project was highly contentious and sparked a regionwide political debate, vastly overran its projected cost, and years later remains controversial and incomplete. An actor‐network theory analysis of why the project failed reveals the different roles played by individual components in the vast network of actors, including the monument itself, which came to exercise influence over the outcome of the project. Because the former president could not fully control this expanding network of actors, events soon spun out of control in what became popularly known as “Galicia's Hurricane.”     

BUILDING A COLONIAL RESOURCE MONOPOLY: THE EXPANSION OF SULPHUR MINING IN NEW SPAIN, 1600–1820*

The discovery, extraction, and monopolistic control of key natural resources was a priority of New Spain's colonial administration. Managing the region's abundant resources, however, often proved difficult for the Spanish Crown. Human and environmental challenges impeded protoindustrial growth and development, and monopolistic control of resources often met resistance. In this article I examine these processes in the context of New Spain's little‐known monopoly on sulphur—a yellow, powdery mineral the Crown jealously guarded as its own. Sulphur was critical for gunpowder and explosives production, yet the Crown often failed to produce enough of it to meet the growing demand by its military and the silver blast‐mining industry. Colonial documents reveal administrators’ attempts to improve sulphur production through reform measures, which included advising sulphur miners on how to discover sulphur deposits and, eventually, how to develop their mines. Efforts to improve sulphur production were moderately successful, although the process was messy and inefficient.     

Do extrusion ages reflect magma generation processes at depth? An example from the Neogene Volcanic Province of SE Spain

The high-K calc-alkaline volcanic rocks along the Neogene Volcanic Province of SE Spain represent crustal anatectic melts mixed with mantle components during the opening of the Alborán Sea. Partially melted metapelitic enclaves, along with the geochemical signature, provide evidence of their crustal source. U–Pb SHRIMP geochronology on monazite and zircon from enclaves and their hosting lavas in the localities of El Hoyazo, Mazarrón and Mar Menor reveals variable delays between the melting at depth and the eruption of the volcanics. These data indicate that: (1) the most important event of anatexis in the Neogene spanned at least the 3 m.y. interval between 12 and 9 Ma; (2) there is no trend in age of crustal melting; and (3) the delay between magma generation and extrusion varies from more than 3 m.y. at El Hoyazo to ~0.5 m.y. and possibly 2.5 m.y. at Mar Menor, with no significant delay measurable at Mazarrón. The variable time delay between anatexis and lava extrusion indicates that radiometric ages of volcanics may provide misleading information on the timing of magma genesis occurring at depth. This highlights the pitfall of basing detailed geodynamic models on volcanic extrusion ages alone. Electronic supplementary material  The online version of this article (doi:) contains supplementary material, which is available to authorized users.     

Sequence stratigraphy and architecture of a late Early–Middle Aptian carbonate platform succession from the western Maestrat Basin (Iberian Chain, Spain)

The attributes of a ‘four-systems-tract’ sequence are at times difficult to identify in outcrop-scale carbonate successions. Poor exposure conditions, variable rates of sediment production, erosion and/or superposition of surfaces that are intrinsic to the nature of carbonate systems frequently conceal or remove its physical features. The late Early–Middle Aptian platform carbonates of the western Maestrat Basin (Iberian Chain, Spain) display facies heterogeneity enabling platform, platform-margin and slope geometries to be identified, and provide a case study that shows all the characteristics of a quintessential four systems tract-based sequence. Five differentiated systems tracts belonging to two distinct depositional sequences can be recognized: the Highstand Systems Tract (HST) and Forced Regressive Wedge Systems Tract (FRWST) of Depositional Sequence A; and the Lowstand Prograding Wedge Systems Tract (LPWST), Transgressive Systems Tract (TST) and subsequent return to a highstand stage of sea-level (HST) of Depositional Sequence B. An extensive carbonate platform of rudists and corals stacked in a prograding pattern marks the first HST. The FRWST is constituted by a detached, slightly cross-bedded calcarenite situated at the toe of the slope in a basinal position. The LPWST is characterized by a small carbonate platform of rudists and corals downlapping over the FRWST and onlapping landwards. The TST exhibits platform backstepping and marly sedimentation. Resumed carbonate production in shelf and slope settings characterizes the second HST. A basal surface of forced regression, a subaerial unconformity, a correlative conformity, a transgressive surface and a maximum flooding surface bound these systems tracts, and are well documented and widely mappable across the platform-to-basin transition area analyzed. Moreover, the sedimentary succession studied is made up of four types of parasequence that constitute stratigraphic units deposited within a higher-frequency sea-level cyclicity. Ten lithofacies associations form these basic accretional units. Each facies assemblage can be ascribed to an inferred depositional environment in terms of bathymetry, hydrodynamic conditions and trophic level. The architecture of the carbonate platform systems reflects a flat-topped non-rimmed depositional profile. Furthermore, these carbonate shelves are interpreted as having been formed in low hydrodynamic conditions. The long-term relative fall in sea-level occurred during the uppermost Early Aptian, which subaerially exposed the carbonate platform established during the first HST and resulted in the deposition of the FRWST, is interpreted as one of global significance. Moreover, a possible relationship between this widespread sea-level drop and glacio-eustasy seems plausible, and could be linked to the cooling event proposed in the literature for the late Early Aptian. Because of the important implications in sequence stratigraphy of this study, the sedimentary succession analyzed herein could serve as an analogue for the application of the four-systems-tract sequence stratigraphic methodology to carbonate systems.     

Pendleian (early Serpukhovian) marine carbonates from SW Spain: sedimentology,biostratigraphy and depositional model

The San Antonio–La Juliana tectono‐sedimentary unit contains the only Namurian marine carbonates in the southwestern part of the Iberian Peninsula. The analysis of this unit is fundamental in understanding the sedimentary evolution and tectonic movements which operated during the Namurian in this area. Using foraminifera the succession has been assigned to two biozones (Zones 17 and 18), both occurring in the Pendleian (early Namurian). Seven stratigraphic sections have been analysed: San Antonio, Burjadillo, Lavadero de la Mina, Cornuda, Lozana, Caridad and Via Crucis. The stratigraphic succession of the San Antonio–La Juliana Unit consists of olistolites in the basal part, with common debris‐flow deposits (mainly of carbonates, with minor siliciclastic rocks), and turbidites, all of them embedded in shales. These rocks, interpeted as slope deposits, pass up into shallow‐water platform facies, with sediments characteristic of the inner platform and tidal flats. Above these rocks, terrigenous deltaic deposits occur. Thus, the stratigraphic sections show an overall shallowing‐upward trend. The isolation of some outcrops, and the duplication and absence of some parts of the stratigraphic succession are explained by tectonic movements. Overall, tectonic factors seem to be the main control rather than glacio‐eustatic or autocyclic processes, and sedimentation took place in a strike‐slip regime. Copyright © 2004 John Wiley & Sons, Ltd.     

Reproduction of Donax venustus Poli 1795, Donax semistriatus Poli 1795 and Intermediate Morphotypes (Bivalvia: Donacidae) in the Littoral of Málaga (Southern Spain)

The reproduction and sexual cycles of Donax venustus Poli 1795, Donax semistriatus Poli 1795, and individuals with intermediate shell morphotypes were studied in the littoral of Málaga (Southern Spain) from February 1990 to January 1991, using histology and analysing the changes in flesh dry weight. The littoral of Málaga has mild seawater temperatures and several upwellings with high levels of chlorophyll a. Due to these environmental conditions, the reproductive periods of these bivalve species are very extensive, from February to November. The histological study shows asynchronous sexual cycles, with continuous but partial individual spawnings from April to November in about 50% of the D. semistriatus population, and percentages higher than 40% of the sample in most months for D. venustus. An important decrease in the ratio flesh dry weight/length³ was noted from June to August in the three populations; this is apparently related with peaks of spawning. Based on the macroscopic observation of the gonads, on the flesh dry weight study and on histological data, the sexual cycle of the intermediate morphotypes is simultaneous and similar throughout the year with those of D. venustus and D. semistriatus .     

Succession,palaeoecology, evolution,and speciation of Pennsylvanian non‐marine bivalves,Northern Appalachian Basin,USA

Seventeen horizons of non‐marine bivalves are described within the Appalachian succession from the base of the Pottsville Group of Westphalian A‐B age to the Uniontown coal of Stephanian C age at the top of the Carboniferous System. A new highly variable fauna of Anthraconaia from the roof shales of the Upper Freeport coal near Kempton, west Maryland, dates from late Westphalian D or very early Cantabrian time, on the evidence of non‐marine shells and megafloras. Below this horizon, the Appalachian sequence reveals zones of Anthraconauta phillipsii and Anthraconauta tenuis in the same order as in Britain, whereas faunas of Anthraconaia of these zones are less common and differ from those of Britain. In all horizons above the Upper Freeport coal all non‐marine bivalve faunas consist of stages in the sequences of two natural species, the groups of Anthraconaia prolifera and Anthraconaia puella‐saravana. The first shows evidence of having lived in well‐oxygenated, probably shallow, fresh water conditions of relatively wide extent. The second group lived preferentially in a plant‐rich environment of relatively stagnant fresh water. Both groups are found in horizons associated with coal seams and may be seen together in the same habitats, but diagrams of variation (pictographs) suggest that there was no interbreeding between the two groups in either the Northern Appalachians or in southern Germany where the species split was first recognized. In the northern Spanish coalfields of Guardo‐Valderrueda and Central Asturia, facies evidence suggests how an initial split may have taken place in the same morphological directions and into the same palaeoenvironments as the later split into two species. Appalachian deposition was generally slow and intermittent with frequent palaeosols. There is also evidence of erosion and of small palaeontological breaks in the sequence, especially near the eastern edge of the Northern Appalachian Basin in western Maryland. The amount of accumulated sediment was less than one‐tenth of that of western Europe when basin centre deposition is compared. We found no evidence of a major palaeontological break representing Westphalian D strata overlain by Stephanian C strata. We figure non‐marine bivalve faunas of Stephanian B age in association with the Pittsburgh and the Little Pittsburgh coals. Two new species of non‐marine bivalves are described: Anthraconaia anthraconautiformis sp. nov. and Anthraconaia extrema sp. nov. Copyright © 2003 John Wiley & Sons, Ltd.     

Rhuddanian to Aeronian (Llandovery,early Silurian) carbon isotope stratigraphy throughout carbonate sequences in the upper Yangtze region,South China block

The Xiangshuyuan Formation (middle Rhuddanian to middle Aeronian stages of the Llandovery Series, lower Silurian) records a shelly fauna representing recovery after the end-Ordovician mass extinction in a well-oxygenated shallow carbonate platform of the Upper Yangtze region, South China Block. Carbon isotope stratigraphy is documented from limestone sequences of the formation at the Qiankou section, northeast Guizhou. The early Aeronian carbon isotope excursion (EACIE, with an amplitude of about 2 ‰ and peak value of 2.44 ‰) is identified in the middle and upper parts of the formation (Ozarkodina obesa conodont Biozone). The EACIE recorded herein correlates well with those in Baltica, Canada, and the United States; together with its records from organic material (δ¹³C_org) the data verify that the EACIE is a global event. The beginning of the EACIE can be used as a chemostratigraphic marker defining the Rhuddanian/Aeronian boundary in strata that lack high-resolution biostratigraphic constraints.