东北地区中生代区域成矿与岩浆活动时序特征

对中国东北地区中生代区域成矿时序和岩浆活动时序及其对应性的分析表明,区域成矿作用总体上集中发生在150~100 Ma和240~160 Ma两大阶段,中生代的岩浆作用主要发育在190~155 Ma和135~100 Ma两个时段,二者在时序上具有良好的对应性,表明岩浆作用对区域成矿具有重要控制作用.     

Geochronological and geochemical characteristics of fractionated I-type granites associated with the skarn mineralization in the Sangan mining region,NE Iran

The Sangan mining region, which has a proven reserve of approximately 1000 Mt of 53% iron ore, is located in the Khaf-Kashmar-Bardeskan volcano-plutonic belt in northeastern Iran. The geological units in the eastern zone of the Sangan region consist of Precambrian schists, Jurassic sedimentary rocks and Tertiary subvolcanic granitoid intrusions. Iron skarn mineralization consists of stratiform and massive bodies in the carbonate rocks that are adjacent to the granitoid intrusions. Detailed field mapping revealed that 39-Ma syenitic intrusive bodies in the western and central zones of the Sangan region were the main sources of heat and fluid for the iron mineralization.A Mid-Cenozoic biotite granite pluton is associated with the eastern anomalies. However, field relationships suggested that this pluton is not the source of the metals, heat or fluids that were responsible for the iron mineralization. This pluton is rich in silica (SiO₂ contents from 66.4 to 79.1 wt%) and is characterized by high-K series with metaluminous to slightly peraluminous affinity.Geochronological (U-Pb zircon method) and geochemical data, including major and trace elements and Sr-Nd-Pb isotopes, define the complex origin of these plutons, which consist of alkaline granitoids that appear to be A-type in character but also show I-type affinity.New geochemical and isotopic data from plutons in the eastern anomalies and data from previous studies of the western and central anomalies and the southeastern intrusive rocks in the Sangan region show that these plutons have close affiliation with lower to upper crust-derived melts and were largely modified into highly fractionated I-type granite. These rocks were derived from and emplaced by varying degrees of partial melting during the Middle Eocene (Bartonian to Lutetian, 38.3–43.9 Ma) from a crustal protolith in a normal to mature volcanic continental arc setting.The Sangan granitoids were produced from crustal assimilation by a heat source from mantle melts, which are associated with the Kashmar-Neotethyan slab that subducted under Eurasia. The Khaf-Kashmar-Bardeskan igneous rocks reflect an active Cenozoic plate margin that was related to the closure of the Kashmar-Neotethyan Sea between the Lut and Eurasia blocks because of the continuous convergence between the Arabian and Iran plates during the Late Cretaceous–Early Paleocene.     

Fluid Inclusion,H-O,S, Pb and noble gas isotope studies of the Aerhada Pb-Zn-Ag deposit,Inner Mongolia,NE China

The Aerhada Pb-Zn-Ag deposit is located in the western segment of the Great Hinggan Range Ag-Pb-Zn-Cu-Mo-Au-Fe metallogenic belt in NE China. Orebodies occur mainly as vein type and are hosted by sandstone and siliceous slate. Three stages of primary mineralization, including an early arsenopyrite-pyrite-quartz, a middle polymetallic and silver sulfides-quartz and a late sphalerite-pyrite-calcite-fluorite are recognized. Four types of fluid inclusions have been identified in the ore-bearing quartz and fluorite veins, i.e., liquid-rich, gas-rich, three-phase CO₂ aqueous inclusions, and pure gas or liquid aqueous inclusions. Microthermometric studies on fluid inclusions reveal that homogenization temperatures from early to late stages range from 253° to 430 °C, 195° to 394 °C and 133° to 207 °C, respectively. Fluid salinities range from 2.9 to 14.0 wt.% NaCl equiv. The vapor composition of the ore fluid is dominated by H₂O, CO₂ and CH₄, with minor proportions of N₂. The fluid δ¹⁸O_H2O and δD_H2O values vary from +1.6 to +9.3‰ and −122 to −56‰, respectively, and reflect a magmatic fluid and a meteoric fluid dominant hydrothermal system for the early and late stages of mineralization, respectively. The calculated δ³⁴S_H2S values of hydrothermal fluids in equilibrium with sulfides range from +5.2 to +7.1‰, suggesting a mixed source for sulfur, i.e., the local magmatic and sedimentary rocks. The Pb isotope compositions of sulfides are similar to those of the local magmatic and sedimentary rocks, implying that lead and possibly silver relate to these sources. The noble gas isotope compositions of fluid inclusions hosted in ore minerals suggest that the ore-forming fluids were dominantly derived from a deep mantle source. Fluid mixing and dilution are inferred as the dominant mechanisms for ore deposition. The Aerhada Pb-Zn-Ag deposit can be classified as a medium to low temperature hydrothermal vein type deposit.     

A Karst Connection model for Grand Canyon, Arizona, USA

Along the Asturian coast of northern Spain an uplifted wave-cut platform extends for  100 km east–west. The steep cliff which bounds the gently seaward-dipping platform to the north increases in height from 30 m in the west to 100 m in the east and reflects the overall eastward increase in platform elevation. The southern edge of the 2–4 km-wide platform runs along the foothills of the Cantabrian Mountains, as constrained by a high-resolution digital elevation model. The marine platform, which was carved into deformed Paleozoic bedrock with abundant quartzite beds, is largely covered by weathered marine and continental sediments. Quartzite samples from flat bedrock outcrops which are currently not covered by sediment or soil yield cosmogenic nuclide concentrations (²¹Ne, ¹⁰Be and ²⁶Al) that demonstrate a long and complex exposure history, including periods of burial with partial or complete shielding from cosmic rays. The combination of multiple cosmogenic nuclides yields a minimum age of 1–2 Ma for the platform. Taking into account (i) the horizontal and vertical extent of the platform, (ii) the high resistance to erosion of the quartzitic bedrock, and (iii) published data on the magnitude of past sea level fluctuations, we suggest that the wave-cut platform formed in the Pliocene. Subvertical faults cutting the platform at high angles to the coastline offset the southern edge of the platform by 20 to 40 m and reactivate the pre-existing anisotropy in the Paleozoic bedrock. Uplift and crustal deformation of the coastal region have occurred after platform formation in the Pliocene and may still be active. The slow deformation of the northern edge of the Iberian plate including the Cantabrian Mountains may result from the ongoing slow convergence at an incipient subduction zone extending along the coast of northern Spain.     

Origin of the anomalies in light and middle REE in sediments of an estuary affected by phosphogypsum wastes (south-western Spain)

Sc, Y, Th, Cu and rare earth elements (REE) concentrations have been analyzed in 14 samples of surface sediments and in two gravity cores by means of ICP-MS. Mean concentrations of Sc, Y and Th in surface sediments are 6.23, 4.76 and 16.30 ppm, respectively, lower than those present in the Upper Continental Crust (UCC). Cu concentration in these sediments is very high, 1466 ppm, and is caused by inputs from the Odiel and Tinto rivers, affected by acid mine drainage. SigmaREE mean concentration is 106.8 ppm, lower than that observed in other rivers and estuaries. In the cores, Sc, Y and Th concentrations show a significant increase in the intermediate levels, between 10 and 40 cm depth. The same pattern exists with Cu, where concentrations of 4440 ppm can be reached. Vertical evolution patterns for Sc, Y, Cu and heavy REE (HREE) are similar, and contrary to those shown by Th, light REE (LREE) and middle REE (MREE). Plots of North American Shale Composite (NASC)-normalized REE data of surface sediments show a slight depletion in REE concentrations. Most samples present with middle REE enrichment relative to light REE and heavy REE. Conversely, samples of the intermediate levels of the cores show significant enrichment of REE relative to NASC and high values in the (La/Gd)NASC and (La/Yb)NASC ratios. These anomalies in the fractionation patterns caused by enrichments in LREE and MREE concentrations is related to the presence of high concentrations of Th. They were generated by effluents from fertilizer factories between 1968 and 1998 which used phosphorite as source material.     

Natural baseline quality of Madrid Tertiary Detrital Aquifer groundwater (Spain): a basis for aquifer management

The Madrid Tertiary Detrital Aquifer is one of the largest and most important aquifers of Spain. This paper assesses the most relevant controls on the natural baseline quality and the dominant chemical processes within the aquifer. The hydrochemistry of the groundwater is variable despite the relative uniformity of the detrital sediments. The natural baseline is expressed as a range of values that are controlled by lithological and hydrological factors; spatial variations of groundwater chemistry are related to changes in rock type, water-rock interaction and the residence time of groundwater. The fundamental chemical processes within the Arkosic aquifer are hydrolysis of silicates, dissolution of carbonates, dissolution of evaporites (only in the vicinity of the transitional facies), ion exchange, neoformation of clays, precipitation of silica as cement, and precipitation of carbonates due to increasing temperature along the downward pathways. Some chemical and physico-chemical parameters like pH, dissolved oxygen, and hardness, and several elements like calcium, sodium, magnesium, silica, and arsenic show an evolutionary trend according to groundwater flow path. A gradual increase in arsenic concentration from recharge areas to discharge areas is observed; it is the main natural water constituent that deteriorates the quality of the fresh Madrid groundwater as a drinking water supply. The occasionally elevated arsenic concentrations originate from natural sources. The concentration and mobility of arsenic seems to be controlled by pH-dependent anion exchange processes resulting from the evolution to Na-HCO₃ water.     

Calcareous skeletons of sea urchins as indicators of heavy metals pollution. Portman Bay, Spain

 Portman Bay presents elevated quantities of metals and heavy metals in the sediments and rocky outcrops. The calcitic skeletons of the sea urchins that live there present elevated concentrations of Mn, Fe, Zn, and Pb (249, 273, 32, and 59 ppm) in comparison with control zones (beach of La Vila) where the concentrations for these elements are 5, 7, 8, and 2 ppm, respectively. Two species of sea urchins have been studied: Paracentrotus lividus and Arbacia lixula. The different compositions between the plates and the spines of their skeletons have also been studied. Received: 20 November 1995 · Accepted: 25 January 1996     

BOOK REVIEWS

Book Reviewed in this article: Geographical Aspects of Health and Disease in India . Rais Akhtar and A.T.A. Learmonth , eds . Antarctic Treaty System: An Assessment . Proceedings of a Workshop at Beardmore South Field Camp, Antarctica. American Electoral Mosaics . J. Clark Archer and Fred M. Shelley . Kompas op Suidwes-Afrika/Namibie . W.S. Barnard , ed . Jerusalem in the 19th Century: The Old City . Yehoshua Ben -Arieh . The World as a Total System . Kenneth E. Boulding . A Social History of Housing 1815–1985, Second Ed . John Burnett . Human Migration . W.A.V. Clark . Regional Population Projection Models . Andrei Rogers . The State of Population Theory: Forward from Malthus . David Coleman and Roger Schofield , eds . Imagining Tomorrow: History, Technology and the American Future . Joseph C. Corn , ed. Swidden Agriculture in Indonesia: The Subsistence Strategies of the Kalimantan Kantú . Michael R. Dove . Glacial Geologic Processes . David Drewry . Physics of Desertification . Farouk El -Baz and M.H.A. Hassan , eds . Housing the Homeless . Jon Erickson and Charles Wilhelm , eds . Settlement Patterns in Missouri: A Study of Population Origins, with a Wall Map . Russel L. Gerlach . Desert Development: Man and Technology in Sparselands . Yehuda Gradus , ed . Nuclear Winter. The Evidence and Risks . Owen Greene , Ian Percival and Irene Ridge . The Take-off of Suburbia and the Crisis of the Central City . Günter Heinritz and Elisabeth Lichtenberger , eds . Regional Input-Output Analysis . Geoffrey J. D. Hewings . Spatial Transportation Modeling . Christian Werner . The Atlas of Georgia . Thomas W. Hodler and Howard A. Schretter , eds . Latin America. 5th ed . Preston E. James and C.W. Minkel . Applied Remote Sensing . C.P. Lo . Localities, Class, and Gender . The Lancaster Regionalism Group . Urban Social Movements: The City after Castells . Stuart Lowe . Politics and Method . Doreen Massey and Richard Meegan , eds . Land Use . A. S. Mather . The Kingdom of Coal . Donald L. Miller and Richard E. Sharpless . The Presidio and Militia on the Northern Frontier of New Spain, A Documentary History, Vol. 1: 1570–1700 . Thomas H. Naylor and Charles W. Polzer , S.J., comps . and eds . Nuclear Power: Siting and Safety . Stan Openshaw . The Central African Republic: The Continent's Hidden Heart . Thomas O'Toole . Environmental and Dynamic Geomorphology . Márton Pécsi , ed . Remote Sensing Principles and Interpretation . Floyd F. Sabins , Jr . Acid Rain and Friendly Neighbors: The Policy Dispute between Canada and the United States . Jurgen Schmandt and Hilliard Roderick , eds . Earth's Changing Surface: An Introduction to Geomorphology . M.J. Selby . International Migration: The Female Experience . Rita J. Simon and Caroline B. Brettell , eds . On Geography and Its History . D.R. Stoddart . Transportation Networks: A Quantitative Approach . D. Teodorovic . Processes in Physical Geography . R.D. Thompson , A.M. Mannion , C.W. Mitchell , M. Parry , J.R.G. Townshend . Imaging Radar for Resources Surveys . J.W. Trevett . Dominance and Affection: The Making of Pets . Yi -Fu Tuan . Capturing the Horizon. The Historical Geography of Transportation since the Transportation Revolution of the Sixteenth Century . James E. Vance , Jr . Nations at Risk: The Impact of the Computer Revolution . Edward Yourdon .     

Geology and rural landscapes in central Spain (Guadalajara, Castilla—La Mancha)

Methods commonly used in regional geological analysis were employed to study the visual landscapes of the Sigüenza–Molina de Aragón area (Spain). Landscape data were compiled to produce a landscape map and a photograph catalogue. Lithological composition, tectonic structure and recent erosive processes are the main factors controlling the visual landscapes. Territorial properties, such as colours and agricultural capacities, are controlled by these geological characteristics. The landscape map and the photographic catalogue is the main contribution of this paper. The first level of landscape classification distinguishes zones with dominance of either flat, concave or convex areas. Other parts of the territory are, however, composed of concave and convex combinations that originate hybrid orographic structures. In a second level of classification, several subdivisions for each of these types are established.