Isotopic (C–O–S) geochemistry and Re–Os geochronology of the Haobugao Zn–Fe deposit in Inner Mongolia,NE China

The Haobugao Zn–Fe deposit is a typical skarn deposit located in the southern part of the Great Xing’an Range that hosts polymetallic mineralization over a large region. The main ore minerals at the deposit include sphalerite, magnetite, galena, chalcopyrite and pyrite, and the main gangue minerals include andradite, grossular garnet, hedenbergite, diopside, ilvaite, calcite and quartz. There are broadly two mineralizing periods represented by the relatively older skarn and younger quartz–sulfide veins. In detail, there are five metallogenic stages consisting of an early skarn, late skarn, oxide, early quartz–sulfide, and late quartz–sulfide–calcite stages. Electron microprobe analyses show that the garnet at the deposit varies in composition from And_97.95Gro_0.41Pyr_1.64 to And_30.69Gro_66.69Pyr_2.63, and pyroxene is compositionally in the diopside–hedenbergite range (i.e. Di_90.63Hd_8.00Jo_1.37–Hd_88.98Di_4.53Jo_6.49). Petrographic observations and electron microprobe analyses indicate that the sphalerite has three generations ([Zn_0.93Fe_0.08]S–[Zn_0.75Fe_0.24]S). The Zn associated with the first generation sphalerite replaced Cu and Fe of early xenomorphic granular chalcopyrite (i.e. [Cu_1.01Fe_1.03]S₂–[Cu_0.99Fe_0.99]S₂), and part of the first generation sphalerite is coeval with late chalcopyrite (i.e. [Cu_0.96Fe_0.99Zn_0.03]S₂–[Cu_1.00Fe_1.03Zn_0.01]S₂). Magnetite has a noticeable negative Ce anomaly (δCe = ∼0.17 to 0.54), which might be a result of the oxidized ore-fluid. Thirty δ³⁴S_V-PDB analyses of sulfides from the ore range from −2.3 to −0.1‰ in value, which are indicative of a magmatic source. The δ¹³C‰ and δ¹⁸O‰ values for calcite from the ore formed at quartz–sulfide–calcite stage vary from −9.9 to −5.5‰ and from −4.2 to 1.1‰, respectively, contrasting with δ¹³C‰ (2.9–4.8‰) and δ¹⁸O‰ (9.8–13.9‰) values for calcite from marble. It is suggested that the ore-forming fluid associated with late stage of mineralization was predominantly magmatic in origin with some input of local meteoric water.Molybdenite from the Haobugao deposit defines an isochron age of 142 ± 1 Ma, which is interpreted as the mineralization age being synchronous, within error, with the zircon U–Pb ages of 140 ± 1, 141 ± 2, and 141 ± 1 Ma for granite at the deposit. These data and characteristics of lithology and mineralization further show that the Zn–Fe mineralization is temporally and spatially related to the emplacement of granite in an extensional tectonic setting during the Mesozoic.     

相山北部善堂庵地区北东向断裂对铀成矿的控制作用

善堂庵地区处在控制相山铀矿田富大矿床产出的邹家山-石洞断裂的北东向延伸端,区内主要发育东西向和北东向断裂。东西向断裂是控岩、控矿构造(早期控岩、晚期控矿);北东向断裂产状较陡,深切基底,成矿期活动强烈,常常与之前的东西向构造复合,深部流体和含矿热液沿其上升,形成较好的铀矿化。善堂庵地区铀矿化主要受花岗斑岩体及北东向巴泉-善堂庵断裂、邹家-布水断裂控制,区内多期、多序次构造发育,热液活动强烈,斑岩体广泛分布,铀成矿地质条件优越,具有良好的成矿远景。     

10,000 years of climate control over carbon accumulation in an Iberian bog(southwestern Europe)

The northwest region of the Iberian Peninsula is home to a unique ecosystem of bogs,which are particularly sensitive to projected climate cha nge.In this context,the rate of carbon(C)accumulation in Chao de Veiga Mol.an intact raised bog,was analysed.Changes in the accumulation rate over the past10 millennia were determined in a peat core of 847 cm in depth,with a high mean rate of peat growth(11 yr cm^-1,0.09 cm yr^-1).An age-depth model was generated from 22 14C dates and fallout radionuclides.Chronological,stratigraphical and physico-chemical data confirmed the existence of a single cycle of peat formation throughout the Holocene and the formation of ombrotrophic peat 9500 years ago.The total mean C content was 50.2%,and over 10 millennia 583 kg C m^-2 accumulated at a mean rate of 35.3 g C m^-2 yr^-1,with a long-term(apparent)rate of carbon accumulation in the catotelm of59.9 g C m^-2 yr^-1.These values are much higher than reported for other Iberian peatlands and are amongst the highest documented for peatlands in the northern hemisphere.The dynamics of C accumulation and other measured parameters reveals important variations throughout the Holocene.They could be associated with the main climatic events described in the northern hemisphere and are highly consistent with models established for northern latitudes.The Chao de Veiga Mol raised bog is unique and of great potential value for carrying out high resolution palaeoenvironmental studies,especially in relation to regional and Iocal modulations in southern Europe.     

中国、西班牙在莱斯诺德（LANZAROTE）岛的火山与地球动力学合作研究的首期结果

本文介绍中、西双方在西班牙莱斯诺德（ＬＡＮＺＡＲＯＴＥ）火山与地球动力学地下实验室共同进行静力水准仪、水平应变伸缩仪、岩体和空气测温计等仪器的合作研究实验以及分析所得的首批成果。     

The Aguablanca Cu–Ni ore deposit (Extremadura, Spain), a case of synorogenic orthomagmatic mineralization: age and isotope composition of magmas (Sr, Nd) and ore (S)

The Aguablanca Cu–Ni orthomagmatic ore deposit is hosted by mafic and ultramafic rocks of the Aguablanca stock, which is part of the larger, high-K calc-alkaline Santa Olalla plutonic complex. This intrusive complex, ca. 338 Ma in age, is located in the Ossa-Morena Zone (OMZ) of the Iberian Variscan Belt. Mineralization consists mainly of pyrrhotite, pentlandite and chalcopyrite resulting from the crystallization of an immiscible sulphide-rich liquid. Isotope work on the host igneous rocks (Sr, Nd) and the ore (S) suggests that contamination with an upper-crustal component took place at some depth before final emplacement of the plutons (Nd₃₃₈=−6 to −7.5; Sr₍₃₃₈₎=0.7082 to 0.7100; δ³⁴S_(sulphides) near +7.4‰). Assimilation–fractional crystallization (AFC) processes are invoked to explain early cumulates and immiscible sulphide-magma formation. Intrusion took place at the beginning of the type-A oblique subduction of the South Portuguese Zone under the Ossa-Morena Zone and was probably driven by transpressive structures (strike-slip faults). The mineralization is thus synorogenic.Aguablanca is probably the first case referred to in the literature of a magmatic Cu–Ni ore deposit hosted by calc-alkaline igneous rocks.     

洪江市大坪金矿床地质特征及其找矿前景

大坪金矿床产于黄茅园与中华山花岗岩体之间外接触带，赋矿地层为上元古界及震旦系浅变质绿片岩相碎屑岩系，金源物质丰富，区域构造变形强烈，褶皱断裂发育，矿床总体受NE向大型韧脆性剪切带（F8)控制，矿化明显分为NW向和NE向两组，以NW向矿脉蚀变强，矿物组合复杂，金含量较高，富矿体产于两者交叉处，主要矿体均分布于变形强带内部及附近，矿化与硅化，绢云母化，黄铁矿，毒砂关系密切，目前发现含放脉37条，矿体近30个，找矿前景十分广阔。     

浏阳市普乐钴多金属矿床地质特征及找矿标志

“湘东北地区的钴多金属矿床,赋存于区域性北北东向断裂带的混合岩带中,矿体呈层状、似层状,沿侧伏方向长,斜长～,厚～。剖面上钴矿体与铜1 500 m1701 400 m1.0217.63 m矿体相间产出。钴矿体品位(10-2:,伴生、× ) Co 0.036Cu 0.259Au 0.2510-6;铜矿体(10-2: ),伴生、×Cu 0.714Co 0.015Au 0.2710-6。、互为消长关系。矿石类型主要为含钴黄铁矿石CoCu和含铜钴黄铁矿石,地表见含钴褐铁矿石。矿物成分以黄铁矿、含钴黄铁矿、黄铜矿和石英、方解石、绢云母、绿泥石为主;矿石结构构造主要有自形、半自形、他形晶粒结构、交代结构和浸染状、团块状,脉状构造;个北东向钴异常带、北东向与北北东向断裂交汇部位、岩体接触带3或顶盖,以及黄铁矿化、硅化、褐铁矿化蚀变等为湘东北地区原生钴矿床的找矿标志。     

Sediment yield variability in Spain: a quantitative and semiqualitative analysis using reservoir sedimentation rates

An existing dataset of area-specific sediment yield (SSY) for 60 catchments in Spain that was retrieved from sediment deposition rates in reservoirs [Avendaño Salas, C., Sanz Montero, E., Rayán, C., Gómez Montaña, 1997. Sediment yield at Spanish reservoirs and its relationship with the drainage basin area. In: Proceedings of the 19th Symposium of Large Dams, Florence, 1997. ICOLD (International Committee on Large Dams), pp. 863–874] reveals that catchment area alone explains only 17% of the variability in SSY. In this study, an attempt to explain the remaining variability in SSY was made using a quantitative and a semiqualitative approach for 22 catchments. During a field survey, the 22 selected catchments were characterised by topography, vegetation cover, lithology, shape and the presence of gullies in the broad vicinity of the reservoir. This information was used to develop a factorial scoring index model that provides a fairly accurate and reliable prediction of SSY. A classical multiple regression model using climatic, topographic and land use properties derived from regional datasets could not explain as much variance as the qualitative index model, nor did it appear to be as reliable. The same conclusion could be drawn when using the CORINE soil erosion risk map of southern Europe. The low prediction capability of the multiple regression models and the CORINE soil erosion risk map could be attributed mainly to the fact that these methods do not incorporate gully erosion and that the land cover data are not a good representation of soil cover. Both variables have been shown to be of great importance during the field surveys. Future assessments of SSY could be quickly and efficiently made using the proposed factorial scoring index model. In comparison with other models, which demand more data, the index model offers an alternative prediction tool.     

Below-ground relationships of soil texture, roots and hydraulic conductivity in two-phase mosaic vegetation in South-east Spain

Results led to the development of a conceptual model, which describes that the presence of deep larger diameter roots in shrub areas form large open channels at deeper soil depths, facilitating deep-water percolation, while presence of thin shallow roots in grass areas form small open channels at shallow depths, causing water to remain within shallow depths. Over time these roots systems will alter their environment and facilitate storage and uptake of water and nutrient availability. The difference in rooting depth will decrease the competition for water between the shrub areas and grass areas and cause differences in water distribution and availability.     

中亚造山带东段古生代山弯构造

中亚造山带东段位于西伯利亚和华北克拉通之间，经历了多构造体系叠加和多旋回洋陆转换的复杂演化过程，目前大量研究均以构造带为核心来限定区域构造格局，但一直争议较大。本文以构造单元的构造属性及其形成过程为主线，结合区域构造带演化，重新厘定了中国东北地区基本构造格局，建立了中国东北山弯构造演化模型。研究表明，古生代时期中国东北地区的主要构造单元由两个具前寒武纪基底的古老地块——额尔古纳地块和佳木斯地块及其张广才岭陆缘弧与两个古生代增生地体——兴安增生地体和松辽增生地体组成，其间由古亚洲洋分支新林- 喜桂图洋、贺根山- 嫩江洋、龙凤山洋和索伦洋分割。早古生代，西部额尔古纳地块东南部为西太平洋型活动陆缘，发育有嘎仙- 吉峰- 环宇洋内弧和头道桥等洋岛，~500 Ma随着新林- 喜桂图洋的关闭，这些洋内弧和洋岛拼贴增生至额尔古纳地块东南缘。随后贺根山- 嫩江洋的俯冲和后撤形成了一系列沟- 弧- 盆体系，持续的俯冲导致弧陆碰撞和陆缘增生，形成兴安增生地体的主体。同时，东部佳木斯地块西侧发育有龙凤山洋的安第斯型俯冲活动陆缘，形成了张广才岭陆缘弧。伴随着各大洋的俯冲和陆缘增生，额尔古纳地块和佳木斯地块以及它们的陆缘增生带构成了一个早古生代近东西向展布的地块链。南部以锡林浩特- 龙江微地块为核心发生陆缘俯冲，形成松辽增生地体雏形。索伦洋发生双向俯冲，并通过弧陆碰撞产生陆缘增生。晚古生代，伴随着古亚洲洋的北向俯冲和后撤，早期形成的地块链逐渐发生向南弯曲。二叠纪末期—中三叠世古亚洲洋俯冲消减闭合以及西北部蒙古- 鄂霍茨克洋和东部泛大洋的俯冲挤压，导致地块链进一步弯曲，同时，早期的古老地块、增生地体、弧岩浆岩、沉积建造等发生汇聚，最终形成一个以额尔古纳地块和兴安增生地体为西翼，佳木斯地块和张广才岭陆缘弧为东翼，松辽增生地体为核心的大规模山弯构造——中国东北山弯构造。