Glaciers and climate in Pacific Far NE Russia during the Last Glacial Maximum

A combined geomorphological–physical model approach is used to generate three‐dimensional reconstructions of glaciers in Pacific Far NE Russia during the global Last glacial Maximum (gLGM). The horizontal dimensions of these ice masses are delineated by moraines, their surface elevations are estimated using an iterative flowline model and temporal constraints upon their margins are derived from published age estimates. The equilibrium line altitudes (ELAs) of these ice masses are estimated, and gLGM climate is reconstructed using a simple degree–day melt model. The results indicate that, during the gLGM, ice masses occupying the Pekulney, Kankaren and Sredinny mountains of Pacific Far NE Russia were of valley glacier and ice field type. These glaciers were between 7 and 80 km in length, and were considerably less extensive than during pre‐LGM phases of advance. gLGM ice masses in these regions had ELAs of between 575 ± 22 m and 1035 ± 41 m (above sea level) – corresponding to an ELA depression of 350–740 m, relative to present. Data indicate that, in the Pekulney Mountains, this ELA depression occurred because of a 6.4°C reduction in mean July temperature, and 200 mm a^?1 reduction in precipitation, relative to present. Thus reconstructions support a restricted view of gLGM glaciation in Pacific Far NE Russia and indicate that the region's aridity precluded the development of large continental ice sheets. Copyright © 2011 John Wiley & Sons, Ltd.     

Hazard-consistent response spectra in the Region of Murcia (Southeast Spain): comparison to earthquake-resistant provisions

Hazard-consistent ground-motion characterisations of three representative sites located in the Region of Murcia (southeast Spain) are presented. This is the area where the last three damaging events in Spain occurred and there is a significant amount of data for comparing them with seismic hazard estimates and earthquake-resistant provisions. Results of a probabilistic seismic hazard analysis are used to derive uniform hazard spectra (UHS) for the 475-year return period, on rock and soil conditions. Hazard deaggregation shows that the largest hazard contributions are due to small, local events for short-period target motions and to moderate, more distant events for long-period target motions. For each target motion and site considered, the associated specific response spectra (SRS) are obtained. It is shown that the combination of two SRS, for short- and long-period ground motions respectively, provides a good approximation to the UHS at each site. The UHS are compared to design response spectra contained in current Spanish and European seismic codes for the 475-year return period. For the three sites analysed, only the Eurocode 8 (EC8) type 2 spectrum captures the basic shape of the UHS (and not the EC8 type 1, as could be expected a priori). An alternative response spectrum, anchored at short- and long-period accelerations, is tested, providing a close match to the UHS spectra at the three sites. Results underline the important contribution of the frequent, low-to-moderate earthquakes that characterize the seismicity of this area to seismic hazard (at the 475-year return period).     

Spheroolithid eggshells in the Lower Cretaceous of Europe. Implications for eggshell evolution in ornithischian dinosaurs

Early Cretaceous spheroolithid eggshells have always been extremely scarce, unlike their putative egg layers, ornithopod dinosaurs, which are ubiquitous in Early Cretaceous ecosystems. In this paper, we re-evaluate eggshells previously assigned to the oofamily Elongatoolithidae, an oofamily related to derived theropod dinosaurs (including maniraptorans and oviraptorids), and reassign them to the oofamily Spheroolithidae, on the basis of the lack of a squamatic ultrastructure, and the presence of a prolatocanaliculate pore system and undulating extinction, typical of spheroolithid eggshells. We erect a new oogenus, Guegoolithus to include material previously reported as Macroolithus turolensis Amo-Sanjuan, Canudo and Cuenca-Bescós 2000, and new material from several lower Barremian localities of the Maestrazgo Basin in Spain. Guegoolithus eggshells exhibit an acicular radial ultrastructure in the lower part of the shell units, which develops into a tabular radial ultrastructure in the upper part, giving an appearance of a two-layered eggshell in thin sections that is not seen in SEM pictures. These features fill the gap between the two-layered prismatic eggshell of ceratopsians and the prolatospherulitic ornithopod eggshell of derived hadrosaurs.     

Assessing the influence of afforestation with Eucalyptus globulus on hydrological response from a small catchment in northwestern Spain using the HBV hydrological model

Land use change as conversion pasture to forest produces several changes on hydrological cycle. In this paper, we analyse the effects on stream discharge of afforestation of a small watershed devoted to pasture using the HBV hydrological model. Streamflow data obtained over the first 10 years after planting were employed to evaluate the capacity of HBV model to simulate hydrological behaviour of catchment after afforestation. Obtained results indicate that the estimation of streamflow was accurate as reflected by statistics (R² = 0.90, NSC = 0.89 and PBIAS = 0.34). Afterwards, streamflow under pasture land use (if afforestation had not occurred) was simulated using hydrometeorological data collected during the period of study and model parameters optimized previously, together with two parameters, pcorr and cevpfo, that were adjusted for pasture conditions. The HBV model results indicate that afforestation produced a water yield reduction around 2000 mm (22% of total stream discharge) during the first 10 years of planting growth. The differences between forest and pasture land cover are increasing in all seasons year by year. The greatest streamflow reduction was observed in wet period (autumn and winter) with 76% of total reduction. In summer, streamflow reduction represents only 3% of total, however, represents 24.7% of discharge in this season. Streamflow reduction was related to increase of rainfall interception (mainly in wet periods) and the increase of evapotranspiration by plantation in dry periods. Copyright © 2013 John Wiley & Sons, Ltd.     

Vapour source and spatiotemporal variation of precipitation isotopes in Southwest Spain

The δ²H and δ¹⁸O composition of 77 precipitation samples collected between January 2014 and April 2019 from two sites across the Guadalquivir Basin, SW Spain, were analysed. The first site is located in an urban area of Seville at 100 km distance to the Atlantic coast and the second site is located in a dune area of the Doñana National Park a few kilometres from the coast. Sampling was performed within intervals of at least 14 days if rain occurred but frequently intervals were longer according to the rainfall incidence. Samples from both sites are available for the period February 2016 to June 2018 with six samples containing identical rain events at both locations. Precipitation weighted averages and local meteoric water lines produced by weighting and non-weighting regression methods are presented for its use in hydrological applications. Results show a remarkably high variability in δ²H and δ¹⁸O values and precipitation weighted average d-excess values of 11.8‰ and 13‰ at the sites Plaza de España and Doñana, respectively. Temperature and amount effects were found to be weak. A significant influence of secondary evaporation for single rainfall events during summer was identified by enriched isotopic signatures with reduced d-excess values plotting close or below the global meteoric water line. Backward trajectory analysis of 115 days with daily rainfall above 3 mm yield a predominant Atlantic Ocean vapour source with negligible Mediterranean influence and therefore, d-excess variability is attributed to the different ocean surface conditions of relative humidity and sea surface temperature. Parallel sampling indicate very similar isotopic signatures at both sites and point to the existence of thermal effects of the Plaza de España site in Seville city during the summer season.     

Mapping groundwater quality variables using PCA and geostatistics: a case study of Bajo Andarax,southeastern Spain

Abstract

A case study is presented for the application of statistical and geostatistical methods to the problem of estimating groundwater quality variables. This methodology has been applied to the investigation of the detrital aquifer of the Bajo Andarax (Almería, Spain). The use of principal components analysis is proposed, as a first step, for identifying relevant types of groundwater and the processes that bring about a change in their quality. As a result of this application, three factors were obtained, which were used as three new variables (VI: sulphate influence; V2: thermal influence; and V3: marine influence). Analysis of their spatial distribution was performed through the calculation of experimental and theoretical variograms, which served as input for geostatistical modelling using ordinary block kriging. This analysis has allowed a probabilistic representation of the data to be obtained by mapping the three variables throughout the aquifer for each sampling point. In this way, one can evaluate the spatial and temporal variation of the principal physico-chemical processes associated with the three variables VI, V2 and V3 implicated in the groundwater quality of the detrital aquifer.     

Isotopic composition (δ18O and δD) of precipitation and groundwater in a semi‐arid,mountainous area (Guadiana Menor basin,Southeast Spain)

We characterize the precipitation and groundwater in a mountainous (peaks slightly above 3000 m a.s.l.), semi‐arid river basin in SE Spain in terms of the isotopes ¹⁸O and ²H. This basin, with an extension of about 7000 km², is an ideal site for such a study because fronts from the Atlantic and the Mediterranean converge here. Much of the land is farmed and irrigated both by groundwater and runoff water collected in reservoirs. A total of approximately 100 water samples from precipitation and 300 from groundwater have been analysed. To sample precipitation we set up a network of 39 stations at different altitudes (800–1700 m a.s.l.), with which we were able to collect the rain and snowfall from 29 separate events between July 2005 and April 2007 and take monthly samples during the periods of maximum recharge of the aquifers. To characterize the groundwater we set up a control network of 43 points (23 springs and 20 wells) to sample every 3 months the main aquifers and both the thermal and non‐thermal groundwater. We also sampled two shallow‐water sites (a reservoir and a river). The isotope composition of the precipitation forms a local meteoric water line (LMWL) characterized by the equation δD = 7·72δ¹⁸O + 9·90, with mean values for δ¹⁸O and δD of − 10·28‰ and − 69·33‰, respectively, and 12·9‰ for the d‐excess value. To correlate the isotope composition of the rainfall water with groundwater we calculated the weighted local meteoric water line (WLMWL), characterized by the equation δD = 7·40δ¹⁸O + 7·24, which takes into account the quantity of water precipitated during each event. These values of (dδD/dδ¹⁸O)< 8 and d‐excess (δD–8δ¹⁸O)< 10 in each curve bear witness to the ‘amount effect’, an effect which is more manifest between May and September, when the ground temperature is higher. Other effects noted in the basin were those of altitude and the continental influence. The isotopic compositions of the groundwater are represented by the equation δD = 4·79δ¹⁸O − 18·64. The groundwater is richer in heavy isotopes than the rainfall, with mean values of − 8·48‰ for δ¹⁸O and − 59·27‰ for δD. The isotope enrichment processes detected include a higher rate of evaporation from detrital aquifers than from carbonate ones, the effects of recharging aquifers from irrigation return flow and/or from reservoirs' leakage and enrichment in δ¹⁸O from thermal water. Copyright © 2010 John Wiley & Sons, Ltd.     

Timing of formation and geological setting of low-sulphidation epithermal gold deposits in the continental margin of NE China

The margin of NE China, a part of the West Pacific metallogenic belt, contains innumerable low-sulphidation mineral deposits. Gold deposits in this region can be classified into three distinct types based on geology and ore mineral paragenesis: (1) low-sulphidation epithermal silver–gold deposits, (2) low-sulphidation tellurium–gold deposits, and (3) low-sulphidation epithermal tellurium–gold deposits. Ores formed during the late Early Cretaceous and the early Late Cretaceous reflect three distinct metallogenic periods: the Fuxin Stage at 115.98 ± 0.89 Ma, the Quantou Stage at 107.2 ± 0.6 Ma or <103 Ma, and the Qingshankou or Yaojiajie Stage at < 97 Ma and 88.2 ± 1.4 Ma. The Fuxin Stage is dominated by trachyandesitic magmatism, with magmas emplaced at hypabyssal depths. In comparison, the Quantou Stage is characterized by high-K calc-alkaline, calc-alkaline, and sodic andesitic, dacitic, and rhyolitic magmatism of three different suites. The first of these is a high-K calc-alkaline andesitic magmatic suite that was accompanied by the emplacement of a calc-alkaline sodic dacite during the formation of the Ciweigou and Wufeng ore deposits. The second suite is dominated by calc-alkaline sodic rhyolite and high-K calc-alkaline sodic dacite magmatism associated with the formation of the Sipingshan ore deposit. The third suite is typified by high-K calc-alkaline andesitic magmatism associated with the emplacement of calc-alkaline hypabyssal granitoid complexes accompanying the formation of the Dong'an and Tuanjiegou ore deposits. The Qingshankou or Yaojia Stage is characterized by calc-alkaline sodic dacite magmatism associated with the formation of the Wuxing ore deposit. Metallogenesis during the Fuxin Stage characterized by trachytic magmatism is closely related to the formation of a deep-seated fault within a magmatic arc or the back-arc region of an immature continental margin and is associated with the Early Cretaceous subduction of the Pacific plate beneath Eurasia. Ore deposits that formed during the Fuxin Stage were generally related to magmato-hydrothermal fluids associated with mantle-derived magmas. In contrast, metallogenesis during the Quantou and Qingshankou or Yaojiajie stages was closely related to the formation of a mature high-K calc-alkaline magmatic arc within a continental margin setting again associated with the westward subduction of the Pacific plate. This metallogenic event was a product of magmato-hydrothermal systems derived from crust–mantle interaction and mixing of magmas derived from partial melting of different sections of the continental crust.     

Links between Mesozoic intermediate–felsic igneous rocks and lower crustal granulite xenoliths,North China Craton: O and Pb isotopic evidence

We present and compare whole-rock and zircon O and Pb isotopic compositions for the Hannuoba granulite xenoliths and Mesozoic intermediate-to-felsic igneous rocks from the Zhangjiakou region, northern margin of the North China Craton, northeast China. The xenoliths have an overall Pb isotopic range similar to rocks from the regionally exposed Neoarchaean granulite terrain. Mesozoic zircons from different types of granulite xenoliths have a narrow range of δ¹⁸O values (6.0–7.7‰) higher than normal mantle δ¹⁸O values (～5.7‰). Mesozoic intermediate–felsic igneous rocks have O and Pb isotopic compositions indistinguishable from the Hannuoba intermediate–mafic granulite xenoliths. Our new data suggest that the Mesozoic igneous rocks and granulite xenoliths are genetically linked and that both were derived from the late Neoarchaean lower crust. This argues against previous proposals that the granulite xenoliths are either products of Mesozoic basaltic underplating or formed by mixing between mantle-derived and pre-existing crustal magmas.