直流激电测深二维反演的若干问题研究

目前,激电数据的二维反演主要针对高密度激电数据,而对于常规的激电测深则很少涉及.据此,针对常规激电测深二维反演所涉及到的一些技术难点进行探讨.在正演过程中,根据实测数据实现有限元网格自动剖分,并采用双网格系统,用相邻节点电导率双线性连续进行有限元模拟,并对模拟的误差进行校正.在反演过程中,利用互换原理和Broyden的方法计算偏导数矩阵;采用与奇异值分解算法精度相当的共轭梯度算法求解偏导数矩阵方程.最后通过对模拟数据和实测数据进行反演试算,验证本计算方法是可行的.     

TSP的应用及其与SEG-2数据文件格式间的转换

TSP超前地质预报系统目前在我国已得到了比较广泛的应用,但厂家未提供其数据文件存储格式.为此,在举例说明TSP的应用效果后,笔者采用UltraEdit软件对多个TSP数据文件进行分析,弄清了其原始数据的总体存储结构.另外,还简单介绍了国际标准地震数据SEG-2文件的存储格式,并在Matlab语言环境下编制了读取SEG-2数据文件与TSP数据文件的程序,实现了将SEG-2文件转换成TSP数据文件的功能.因此,在今后的工作中可直接应用TSP的数据处理软件包TSPwin来处理国产的超前地震数据.     

活性炭负载磷钨酸催化合成氯乙酸乙二醇双酯

以氯乙酸、乙二醇为原料,活性炭负载磷钨酸为催化剂合成了氯乙酸乙二醇双酯,并根据酸醇摩尔比、催化剂用量、反应时间及带水剂苯加入量等条件对反应的影响,确定了最佳反应条件。测定了产物的熔点,用IR对产物的结构进行了表征。结果表明,活性炭负载磷钨酸是合成氯乙酸乙二醇双酯的良好催化剂,且可重复利用多次。     

Interactions between basalts and oil source rocks in rift basins： CO2 generation

Basalts interbedded with oil source rocks are discovered frequently in rift basins of eastern China, where CO2 is found in reservoirs around or within basalts, for example in the Binnan reservoir of the Dongying Depression. In the reservoirs, CO2 with heavy carbon isotopic composition (δ13C>-10‰ PDB) is in most cases accounts for 40% of the total gas reserve, and is believed to have resulted from degassing of basaltic magma from the mantle. In their investigations of the Binnan reservoir, the authors suggested that the CO2 would result from interactions between the source rocks and basalts. As the source rocks around basalts are rich in carbonate minerals, volcanic minerals, transition metals and organic matter, during their burial history some of the transition metals were catalyzed on the thermal degradation of organic matter into hydrocarbons and on the decomposition of carbonate minerals into CO2, which was reproduced in thermal simulations of the source rocks with the transition metals (Ni and Co). This kind of CO2 accounts for 55%-85% of the total gas reserve generated in the process of thermal simulation, and its δ13C values range from -11‰- -7.2‰ PDB, which are very similar to those of CO2 found in the Binnan reservoir. The co-generation of CO2 and hydrocarbon gases makes it possible their accumulation together in one trap. In other words, if the CO2 resulted directly from degassing of basaltic magma or was derived from the mantle, it could not be accumulated with hydrocarbon gases because it came into the basin much earlier than hydrocarbon generation and much earlier than trap formation. Therefore, the source rocks around basalts generated hydrocarbons and CO2 simultaneously through catalysis of Co and Ni transition metals, which is useful for the explanation of co-accumulation of hydrocarbon gases and CO2 in rift basins in eastern China.     

初论塔里木盆地砂岩储层中SiO2的溶蚀类型及其机理

根据显微镜观察,塔里木盆地砂岩储层中SiO₂溶蚀分为石英颗粒边缘溶蚀、次生加大边溶蚀和交代溶蚀。通过对石英颗粒和加大边溶蚀特征及其与粘土矿物组合、与碳酸盐胶结、与古油藏破坏以及现今油田水中Si离子含量等关系的综合研究,这些SiO₂溶蚀可能存在两种机理:碱性环境下的SiO₂溶蚀和有机酸(烃类微生物降解产生的有机酸以及有机质成熟产生的有机酸)引起的SiO₂溶蚀。第一种溶蚀类型较普遍,但程度微弱;第二种溶蚀类型主要发生在古油藏破坏和有机质成熟过程中,这种溶蚀较强烈但很局限。SiO₂的溶蚀作用可以为油气提供一定量的储集空间,这对于深埋的时代较老的志留-泥盆系储层具有重要意义。在古油藏中尽管烃类已经充注储层孔隙,但只要孔隙中存在有机酸或碱性孔隙水,SiO₂的溶蚀和石英次生加大的胶结等作用仍可进行。     

铵(氮)在岩石和矿物中地球化学行为研究进展

地壳中的氮大都以NH4 储存在矿物中.由于成岩时含氮有机物质的分解作用,氮广泛分布在沉积岩和低级变质岩中;在岩浆岩和变质岩中,氮主要以NH4 存在于含钾硅酸盐(长石和云母类)中;岩浆岩的δ(15N)值和氮浓度明显地不同于沉积物和变沉积岩,主要是由于有机物的缺乏.具有明显铵含量的火成岩主要是含钾矿物的深成岩.因而NH4 可以作为一个"示踪元素"而用于成矿作用等方面的研究.文章还提出了未来的研究方向.     

C02-CH4流体与金成矿作用：以阿尔泰山南缘和穆龙套金矿为例

造山型金矿的成矿作用与H20-CO2流体有着密切的联系。然而对阿尔泰山南缘和穆龙套金矿的流体包裹体研究表明，无水的CO2-CH4流体在中亚成矿域中一些金矿床中具有同样重要意义。阿尔泰山南缘萨热阔布金矿包裹体的Xch4达0.20～0.23，穆龙套金矿的XCH4为0.07～0.23。CH4扩大了流体不混溶的范围，有利于对Au的富集沉淀。CO2流体在Au成矿中的重要作用至少包括了三方面的意义，即：缓冲流体PH值范围、提高流体中的Au含量并使其维持与还原硫的络合作用进行迁移；扩大超临界流体的温度范围；增加流体不混溶的区域。CH4的加入扩大了流体不混溶的范围，有利于对Au的富集沉淀。     

Heat capacity of γ-Fe2SiO4 between 5 and 303 K and derived thermodynamic properties

A multi-anvil device was used to synthesize 24 mg of pure γ-Fe₂SiO₄ crystals at 8.5 GPa and 1,273 K. The low-temperature heat capacity (C _p) of γ-Fe₂SiO₄ was measured between 5 and 303 K using the heat capacity option of a physical properties measurement system. The measured heat capacity data show a broad λ-transition at 11.8 K. The difference in the C _p between fayalite and γ-Fe₂SiO₄ is reduced as the temperature increases in the range of 50–300 K. The gap in C _p data between 300 and 350 K of γ-Fe₂SiO₄ is an impediment to calculation of a precise C _p equation above 298 K that can be used for phase equilibrium calculations at high temperatures and high pressures. The C _p and entropy of γ-Fe₂SiO₄ at standard temperature and pressure (S°₂₉₈) are 131.1 ± 0.6 and 140.2 ± 0.4 J mol⁻¹ K⁻¹, respectively. The Gibbs free energy at standard pressure and temperature (ΔG° _f,298) is calculated to be −1,369.3 ± 2.7 J mol⁻¹ based on the new entropy data. The phase boundary for the fayalite–γ-Fe₂SiO₄ transition at 298 K based on current thermodynamic data is located at 2.4 ± 0.6 GPa with a slope of 25.4 bars/K, consistent with extrapolated results of previous experimental studies.     

楚雄龙岗地区超级不整合与金成矿

龙岗地区陇川运动-华力西运动间造成整个古生代地层缺失，中上三叠统直接覆于下元古界哀牢山岩群、大红山岩群等基底岩系之上，本文称为“超级不整合”。华力西期-喜马拉雅期历次地壳事件在“超级不整合”接触带形成“矿质”的“浪淘砂”式、叠次‘堆积’作用，对该区金成矿有决定性作用，先后发现小水井与大龙潭两个典型金矿床。前者为“地下水热卤水溶滤中低温热液蚀变角砾岩微粒浸染型金矿床”，可类比为“卡林型”；后者为“原生沉积地下热水溶滤中低温热液蚀变砂砾岩微粒-粗粒型金矿床”，为该区首次发现的新类型。     

伪三维地震勘探法在煤田勘查中的应用

勘探区属郭庄煤矿的后备井田，勘探的目的是掌握井田主可采煤层的赋存形态与断层、陷落柱发育特征。根据勘探区的地质条件，地质任务，兼顾质量和成本，勘探设计方案最终确定为3线1炮制线束状观测系统，采用中间放炮，使勘探物理点由常规二维设计的3000个减至700个，勘探成本明显降低。勘探前后的资料对比分析表明，3#煤层的展布特征和断层构造有较大不同，其中3#煤层展布形态由NE向变化均匀，两翼对称的背斜构造修改为等高线变化扭曲相对剧烈，两翼对称的向斜构造；勘探后新解释断层5条，断点3处，另外3条已知断层的形态、位置、落差等相差各异。