The 117.38 m of gabbroic core drilled during the Ocean Drilling Program (ODP) Leg 153 at Sites 921 to 924 in the Mid-Atlantic Ridge (MAR) between 23 °N and the Kane Fracture Zone, exhibits a remarkable primary compositional heterogeneity, such as magmatic layering, intrusive contacts and late magmatic veining, which express a succession of magmatic events. Textural indicators suggest that the cooling of the crystal mush occurred in a dynamic environment, with infiltration of progressively evolved liquids. Magmatic features include random shape fabric and magmatic lamination; the subsequent deformational overprint occurred in subsolidus conditions. The ductile deformation, generally concentrated in discrete domains of the gabbro, is associated with continuous re-equilibration of the metamorphic assemblages of (1) olivine + clinopyroxene + orthopyroxene + plagioclase + ilmenite + Ti-magnetite, (2) olivine + clinopyroxene + plagioclase + ilmenite + Ti-magnetite + red hornblende. At lower temperatures brittle deformation prevails and subsequent fractures control the development of metamorphic assemblages: (3) clinopyroxene + plagioclase + red brown hornblende + Ti-magnetite + magnetite (?) + ilmenite, (4) plagioclase + brown hornblende + Ti-magnetite + magnetite + hematite + titanite ± Ti-oxide, (5) plagioclase + green hornblende + magnetite + titanite, (6) plagioclase + actinolite + chlorite + titanite + magnetite, (7) albite + actinolite + chlorite + prehnite ± epidote ± titanite and (8) albite + prehnite + chlorite ± smectite. Assemblages 1 to 8 express increasing water/rock ratios and decreasing degrees of recrystallization.
During the ductile phase, red hornblende is stable and its abundance increases with deformation intensity, possibly as an effect of the introduction of hydrous fluids. During the brittle phase, water diffusion controls the development of the fracture-filling mineral assemblages and re-equilibration of the adjacent rock; temperatures decrease further, as demonstrated by mineral zoning and incompletely re-equilibrated assemblages. The lowest temperatures correspond to the development of hydrothermal assemblages.
Compared with oceanic gabbros from fast-spreading transform environments, high-temperature ductile phases (granulite and amphibolite) are well developed, whereas brittle phases are widespread, as microcracks, prevalent on fracturing associated with discrete veins. 相似文献
Orthogneisses are the major country rocks hosting eclogites in the Sulu UHP terrane, eastern China. All of the analyzed orthogneiss cores from the main drilling hole of the Chinese Continental Scientific Drilling Project (CCSD-MH) have similar major and trace element compositions and a granite protolith. These rocks have relatively high LREE/HREE ratios, strong negative Eu anomalies (Eu/Eu*=0.20–0.39), and negative Ba anomalies (Ba/Ba*=0.25–0.64). Coesite and coesite-bearing UHP mineral assemblages are common inclusions in zircons separated from orthogneiss, paragneiss, amphibolite, and (retrograded) eclogite of the CCSD-MH. This suggests that the eclogite, together with its country rocks, experienced in situ ultrahigh-pressure (UHP) metamorphism. Laser Raman spectroscopy and cathodoluminescence (CL) images show that zircons from the orthogneisses are zoned and that they have distinct mineral inclusions in the different zones. Most zircons retain early magmatic cores with abundant low-pressure mineral inclusions, which are mantled with metamorphic zircon-containing inclusions of coesite and other UHP minerals. The outermost rims on these grains contain low-pressure mineral inclusions, such as quartz and albite. SHRIMP U–Pb dating of the zoned zircons gives three discrete and meaningful groups of ages: Proterozoic ages for the protolith, 227±2 Ma for the coesite-bearing mantles, and 209±3 Ma for the amphibolite facies retrograde rims. The widespread occurrence of UHP mineral inclusions in zircons from the Sulu metamorphic belt dated at about 227 Ma suggests that voluminous continental crust experienced late Triassic subduction to depths of at least 120 km and perhaps more than 200 km. Eighteen million years later, the terrane was rapidly exhumed to midcrustal levels, and the UHP rocks were overprinted by amphibolite facies metamorphism. The exhumation rate deduced from the zircon age data and previously obtained metamorphic P–T data is estimated to be 5.6–11.0 km/Ma. Such rapid exhumation of the Sulu UHP terrane may be due to the buoyancy forces produced by subduction of low-density continental material into the deep mantle. 相似文献
Different downstream variation patterns were observed for a range of bed sediment-borne metals (aqua regia-extractable fraction) in a subtropical stream system receiving acid mine drainage. Mine-originated Fe tended to be deposited in the acidic (mean pH < 4.9) upstream reach in forms of goethite and/or hematite. In contrast, other metals tended to be transported farther downstream and settled in a low-gradient reach with high pH (mean pH > 5.6). The peak of sediment-borne Al, Be, Ca, Cd, Co, Cu, La, Mn, Ni and Zn corresponded very well with the peak of the sediment-borne organic matter, suggesting a close association between the water-borne organic colloids and the inorganic metal oxides/hydroxides during their transport. The marked increase in the sediment-borne Al and Pb started more upstream than the other metals, suggesting that the water-borne Al and Pb were more susceptible to pH rise-induced precipitation, as compared to the other metals. It appeared that the organic colloids played no important role in Pb transport and settlement. The iron precipitates had a limited role to play in affecting the transport and fates of other metals since they were predominantly formed and deposited in the acidic reach, which made them incapable of scavenging cationic metals by co-precipitation or adsorption. 相似文献
The 558-m-deep ZK703 drillhole located near Donghai in the southern part of the Sulu ultrahigh-pressure metamorphic belt, eastern China, penetrates alternating layers of eclogites, gneisses, jadeite quartzites, garnet peridotites, phengite–quartz schists, and kyanite quartzites. The preservation of ultrahigh-pressure metamorphic minerals and their relics, together with the contact relationship and protolith types of the various rocks indicates that these are metamorphic supracrustal rocks and mafic-ultramafic rock assemblages that have experienced in-situ ultrahigh-pressure metamorphism. The eclogites can be divided into five types based on accessory minerals: rutile eclogite, phengite eclogite, kyanite–phengite eclogite, quartz eclogite, and common eclogite with rare minor minerals. Rutile eclogite forms a thick layer in the drillhole that contains sufficient rutile for potential mining. Two retrograde assemblages are observed in the eclogites: the first stage is characterized by the formation of sodic plagioclase+amphibole symplectite or symplectitic coronas after omphacite and garnet, plagioclase+biotite after garnet or phengite, and plagioclase coronas after kyanite; the second stage involved total replacement of omphacite and garnet by amphibole+albite+epidote+quartz. Peak metamorphic P–T conditions of the eclogites were around 32 to 40 kbar and 720°C to 880°C. The retrograde P–T path of the eclogites is characterized by rapidly decreasing pressure with slightly decreasing temperature. Micro-textures and compositional variations in symplectitic minerals suggest that the decompression breakdown of ultrahigh-pressure minerals is a domainal equilibrium reaction or disequilibrium reaction. The composition of the original minerals and the diffusion rate of elements involved in these reactions controlled the symplectitic mineral compositions. 相似文献