山西省地下流体观测井地下水类型综合判定

为提升对山西省地下流体观测井承压性的进一步认识,以位于该省北、中、南部的朔州井、静乐井、祁县井、洪洞井和东郭井为研究对象,选取水位、气压观测数据,并利用井水位的理论固体潮数据,分别对井水位进行气压的阶跃响应函数计算、FFT频谱和潮汐相位响应分析,综合判定地下流体观测井—含水层类型,结果表明,5口观测井地下水埋藏类型均为半承压水。     

考虑填充墙影响的钢筋混凝土厂房结构地震易损性分析

采用对角斜撑模拟纵向填充墙的作用,建立考虑填充墙和不考虑填充墙厂房结构模型,采用拉丁超立方抽样技术建立考虑材料不确定性的结构分析样本,基于随机Pushover分析确定结构不同破坏状态下的统计参数。综合考虑结构材料强度及输入地震动不确定性的影响,通过非线性时程分析开展单层钢筋混凝土厂房结构易损性研究,在此基础上比较结构横、纵向易损性的差异,研究填充墙对结构易损性的影响。研究结果表明:钢筋混凝土厂房结构体系横向地震易损性显著大于纵向地震易损性;对纵向结构体系而言,加入填充墙会明显降低结构易损性,但在相同强度的地震动作用下,填充墙破坏程度比主体结构严重,这与厂房结构的实际震害特征相符。     

基坑开挖数值分析中土体硬化模型参数的试验研究

土体硬化模型已成为基坑数值分析中最常用的本构模型之一,其应用的关键是计算参数的确定。首先采用薄壁取土器现场取得土样,通过基于GDS的三轴固结排水剪切试验、三轴固结排水卸载-再加载试验及标准固结试验获得了上海典型土层土体的三轴试验应力-应变曲线和固结试验荷载-应变关系曲线。然后根据曲线确定了各土层的HS模型参数,建立了各土层HS模型参数中切线模量 、割线模量 、加载模量 的比例关系,并探讨了这些模量与压缩模量 之间的比例关系。最后将各层的模型参数与模量间的比例关系与国内外其他软土地区的结果进行了比较。试验结果可作为上海地区及其他软土地区基坑工程数值分析中确定HS模型参数时的参考。     

长白山区暗棕壤成土作用地球化学特征

以代表性暗棕壤垂直剖面土壤地球化学数据为依据,研究了长白山区特定的森林景观条件下成土过程中元素的分异与富集特征。研究结果表明,在岩石风化过程中主要以CaO、Na2O、Sr淋溶为主,有机酸淋溶过程中SiO2、Al2O3、K2O部分被淋溶,部分游离铁下渗到土体中下部氧化成铁锰胶膜;微量元素在风化过程中被次生黏土矿物吸附,不同程度地富集,在腐殖质积累过程中Cd、Zn、Pb、Mo、Hg、Co、Mn、Cr等亲生物元素进一步富集于表层土壤,Ce、Ni、Sb、Ti、V、Y、Zr在表生环境中地球化学性质稳定,残留富集于土壤表层。母质层继承和保留了基岩元素地球化学分布的基本特征。     

Seepage and consolidation of bentonite saturated with pure- or salt-water by the method of unified molecular dynamics and homogenization analysis

Bentonite clay is a micro-inhomogeneous material, which consists of clay minerals (mainly montmorillonite), macro-grains (mainly quartz), water, air and others. Properties of the saturated bentonite clay are essentially characterized by the montmorillonite and water (i.e. montmorillonite hydrate). We analyze the molecular behavior of sodium montmorillonite hydrate Na_1/3Al₂[Si_11/3Al_1/3]O₁₀(OH)₂·nH₂O by applying a molecular dynamics (MD) simulation method. And by using the MD results we calculate the swelling property of the montmorillonite hydrate, and compare with an experimental result. Next, by using the same MD procedure we treat a montmorillonite mineral with a large number of external water molecules to check the properties of the water. Here we treat pure- and salt-water. Then we calculate the diffusivity and viscosity of water molecules and Na⁺ and Cl⁻ ions.

For extending the microscopic characteristics of constituent materials to a macroscopic seepage behavior of the micro-inhomogeneous material we apply a homogenization analysis (HA). That is, starting with the Navier–Stokes equation with distributed viscosity that is calculated by the former MD procedure we determine macroscopic permeability characteristics of bentonite for both cases of pure- and salt-water. Then, by using the permeability property we calculate long-term consolidation behavior of buffering clay, which is planed to be used for high-level radioactive waste (HLRW) management. Here the deformation is treated under the well-defined Cam clay model.     

Bulk-rock Major and Trace Element Compositions of Abyssal Peridotites: Implications for Mantle Melting, Melt Extraction and Post-melting Processes Beneath Mid-Ocean Ridges

This paper presents the first comprehensive major and traceelement data for 130 abyssal peridotite samples from the Pacificand Indian ocean ridge–transform systems. The data revealimportant features about the petrogenesis of these rocks, mantlemelting and melt extraction processes beneath ocean ridges,and elemental behaviours. Although abyssal peridotites are serpentinized,and have also experienced seafloor weathering, magmatic signaturesremain well preserved in the bulk-rock compositions. The betterinverse correlation of MgO with progressively heavier rare earthelements (REE) reflects varying amounts of melt depletion. Thismelt depletion may result from recent sub-ridge mantle melting,but could also be inherited from previous melt extraction eventsfrom the fertile mantle source. Light REE (LREE) in bulk-rocksamples are more enriched, not more depleted, than in the constituentclinopyroxenes (cpx) of the same sample suites. If the cpx LREErecord sub-ridge mantle melting processes, then the bulk-rockLREE must reflect post-melting refertilization. The significantcorrelations of LREE (e.g. La, Ce, Pr, Nd) with immobile highfield strength elements (HFSE, e.g. Nb and Zr) suggest thatenrichments of both LREE and HFSE resulted from a common magmaticprocess. The refertilization takes place in the ‘cold’thermal boundary layer (TBL) beneath ridges through which theascending melts migrate and interact with the advanced residues.The refertilization apparently did not affect the cpx relicsanalyzed for trace elements. This observation suggests grain-boundaryporous melt migration in the TBL. The ascending melts may notbe thermally ‘reactive’, and thus may have affectedonly cpx rims, which, together with precipitated olivine, entrappedmelt, and the rest of the rock, were subsequently serpentinized.Very large variations in bulk-rock Zr/Hf and Nb/Ta ratios areobserved, which are unexpected. The correlation between thetwo ratios is consistent with observations on basalts that D_Zr/D_Hf< 1 and D_Nb/D_Ta < 1. Given the identical charges (5⁺ forNb and Ta; 4⁺ for Zr and Hf) and essentially the same ionicradii (R_Nb/R_Ta = 1·000 and R_Zr/R_Hf = 1·006–1·026),yet a factor of 2 mass differences (M_Zr/M_Hf = 0·511 andM_Nb/M_Ta = 0·513), it is hypothesized that mass-dependentD values, or diffusion or mass-transfer rates may be importantin causing elemental fractionations during porous melt migrationin the TBL. It is also possible that some ‘exotic’phases with highly fractionated Zr/Hf and Nb/Ta ratios may existin these rocks, thus having ‘nugget’ effects onthe bulk-rock analyses. All these hypotheses need testing byconstraining the storage and distribution of all the incompatibletrace elements in mantle peridotite. As serpentine containsup to 13 wt % H₂O, and is stable up to 7 GPa before it is transformedto dense hydrous magnesium silicate phases that are stable atpressures of 5–50 GPa, it is possible that the serpentinizedperidotites may survive, at least partly, subduction-zone dehydration,and transport large amounts of H₂O (also Ba, Rb, Cs, K, U, Sr,Pb, etc. with elevated U/Pb ratios) into the deep mantle. Thelatter may contribute to the HIMU component in the source regionsof some oceanic basalts. KEY WORDS: abyssal peridotites; serpentinization; seafloor weathering; bulk-rock major and trace element compositions; mantle melting; melt extraction; melt–residue interaction; porous flows; Nb/Ta and Zr/Hf fractionations; HIMU mantle sources     

基于正交设计的复杂坝基弹塑性力学参数反演

复杂坝基弹塑性力学参数反演的计算工作量直接取决于采用何种优化方法。根据大坝在运行期的实测资料，运用有限元正交数值试验、回归分析和优化相结合的方法，反演了坝基岩体的弹塑性力学参数。实例研究表明了该方法的有效性和实用性。     

多孔介质渗透系数的空间尺度效应研究进展

多孔介质渗透系数的空间尺度问题是一个与地下流体运动和溶质运移的数值模拟密切相关的应用性课题,广泛的应用需求和新的计算方法使其成为近年的热门课题之一。它涉及到相互联系的两个方面：①非均质介质场渗透系数空间尺度行为的分析与模拟;②将局部测量尺度下的试验参数转化为数值模拟网格尺度下的参数输入值的升尺度（ｕｐｓｃａｌｉｎｇ）方法和计算模型。首先介绍了该课题在概念上的拓展及其物理含义,进而以方法为主线,对这一领域具有代表性的研究成果进行了分类和评述,讨论了该课题的研究对地下水流和溶质运移的模拟分析乃至整个多孔介质流体运动研究的意义。     

水中氯代烃单体碳同位素分析中预富集方法进展

高精度准确测定氯代烃单体碳同位素对示踪污染物来源,了解污染物的生物降解过程具有重要意义。在环境转化过程中,有机污染物的同位素组成可能是稳定不变的,也有可能发生改变。若污染物的同位素组成在迁移转化过程中不变,根据其同位素组成可以示踪污染物的来源;若同位素组成变化,根据同位素分馏结果,可以评价环境中有机污染物降解发生的可能性和程度。本文综述了固相微萃取、静态顶空进样、吹扫-捕集、多级串联技术等前处理方法与气相色谱-燃烧-同位素比值质谱仪(GC-C-IRMS)联用分析水中氯代烃单体碳同位素的研究进展,比较了分析方法的优缺点。液-液萃取较少用于水中氯代烃的单体同位素分析。静态顶空进样、固相微萃取、吹扫-捕集都是无溶剂富集技术,与GC-C-IRMS联用分析水中氯代烃单体同位素过程中不存在或存在小且恒定的可校正的同位素分馏,分析精度一般优于1‰,没有二次污染,降低了杂质干扰,提高了GC-C-IRMS的分辨率和分析精度,降低了检测限。从静态顶空进样、固相微萃取、吹扫-捕集,到多级串联等技术与GC-C-IRMS联用分析水中氯代烃单体同位素比值,检测限逐渐降低。目前,吹扫-捕集-GC-C-IRMS在分析水中氯代烃中应用最广泛,重现性好、检测限低。针内微萃取、管内微萃取、搅动棒吸附萃取和顶空进样吸附萃取等前处理方法与GC-C-IRMS仪联用具有一定的应用前景。     

GBHM模型原理及其在中尺度流域的应用

分布式水文模型核心之一是对流域的离散方法.基于地形分析和单位线概念,GBHM利用面积函数和宽度函数概化流域地形特性,将流域划分为一系列内部均一的流带和流条,形成均质坡面流单元,使模型可用一维水份运动方程描述降水产流过程.模型在永定河流域的应用表明,其原理和效率均较为满意.