Investigation of local time dependence of Mercury's sodium exosphere based on a numerical simulation

Mercury has a surface-bounded exosphere (SBE) similar to that of the Moon. One of the atmospheric species, sodium, was found by ground-based observations to be the most prominent component. Mercury's sodium SBE is known to be non-uniform with respect to local time (LT) in low-latitude regions: the sodium column density in the dawn-side region is larger than that in the dusk-side region, and the sodium abundance is the largest in the morning-noon region. To reveal the production processes for the exosphere near Mercury's surface, the LT dependence of the exosphere was investigated through a numerical simulation. Three data sets of sodium column densities observed for the dawn-side hemisphere, observed by Sprague et al. [1997. Distribution and abundance of sodium in Mercury's atmosphere, 1985-1988. Icarus 12, 506-527], were compared with results simulated by a 3D Monte Carlo method, and the source rates and density of sodium of the planetary surface were estimated. In the simulation, the photon-stimulated desorption (PSD) and thermal desorption (TD) processes were assumed as the release mechanisms. The sodium source rates for the three data sets, at respective heliocentric distances of about 0.33, 0.42, and 0.44 AU, were estimated as 1-4×10⁸ Na/cm²/s with weak LT dependence. In contrast, the expected sodium surface density showed clear dependence on LT and the heliocentric distance. The sodium surface density decreases from early morning to noon by a few orders, and, particularly for large heliocentric distances, the surface is in a condition of sodium excess and depletion with respect to the surface sodium density assumed by Killen et al. [2004. Source rates and ion recycling rates for Na and K in Mercury's atmosphere. Icarus 171, 1-19] in the early morning and morning-noon regions, respectively. This study implies that the decrease in sodium surface density from the early morning to noon regions might produce the characteristic LT dependence in the low-latitude dawn-side region.     

Polarimetric NIR reflectance measurements of regolith simulants at zero phase angle

Polarimetric reflectance measurements have been made at a wavelength of for a suite of predominantly lunar regolith simulants in support of development efforts for the BepiColombo Laser Altimeter (BELA). Measurements were made using an instrument at the University of Bern, Switzerland, that has been modified to accommodate photometric characterizations of laboratory samples down to 0^° phase angle (g) with linearly polarized illumination and a linearly polarized receiver. The data reveal opposition surges that are dominated by polarization state-conserving reflectance terms for all samples. Relative strengths of the trans-state reflectance terms are lowest for the darkest samples, suggesting that multiple scattering is responsible for state conversions. Normal albedo measurements of the lunar simulants range from 0.13 to 0.22 at zero illumination angle (i=0^°). The total reflectance of the regolith simulants at g=0^° were found to decrease with increasing i, which is inconsistent with predictions of reflectance models for Mercury. However, the g=0^° reflectance remains higher at i>0^° than would be expected for a gray Lambert surface that is scaled to the g=i=0^° reflectance value. Polarization ratios for reflectance under polarized illumination but unconstrained emission show that the samples scatter light in the in-plane polarization state more efficiently than in the transverse state at g=0^° and i>0^°. The opposite is true for g>0^° polarization ratios, which indicate that transverse polarized illumination scatters more efficiently at high g. The polarization effect appears to correlate with the sample's characteristic grain size, but the statistical basis of this trend is weak. The implications of these measurements upon the performance of the BELA instrument are discussed.     

Mercury's integral phase curve: Phase reddening and wavelength dependence of photometric quantities

We present results of a five-filter photometric study of Mercury's integral phase curve in the Johnson-Cousins UBVRI system, performed with the 0.90-m Westerlund Telescope in Uppsala, Sweden. CCD observations were made of the integrated disk for the phase angle range 22-152°, and the study is the first to cover the extended visible spectrum of Mercury. The observations are analyzed with Hapke's semi-empirical radiative transfer-based light-scattering model and photometric quantities are derived. A statistically significant phase reddening effect of is determined for Mercury based on color index observations, which is similar to that of the Moon. Phase coefficients fit to integral absolute magnitude data and Hapke models in combination with color index data provide a phase reddening effect of which does however not provide statistically significant evidence for its presence. Phase coefficients indicate that phase reddening may be decreasing in magnitude with wavelength. As for the case with the Moon, the value of the phase integral increases with wavelength, but at an eight times higher rate. This value is consistent with the difference in the rate of change in the spectral slope-emission angle relation for the two bodies. We attribute these differences with Mercury's redder spectral slope and an increase with wavelength of the backscattering lobe amplitude in the double Henyey-Greenstein particle phase function formulation. The normal albedo of integral Mercury at 1064 nm, pertinent to the return pulse energy of the BepiColombo laser altimeter (BELA), is estimated to 0.23±0.06 with a range of 0.13-0.33 for 99% of the surface.     

Global MHD modeling of Mercury's magnetosphere with applications to the MESSENGER mission and dynamo theory

We use a global magnetohydrodynamic (MHD) model to simulate Mercury's space environment for several solar wind and interplanetary magnetic field (IMF) conditions in anticipation of the magnetic field measurements by the MESSENGER spacecraft. The main goal of our study is to assess what characteristics of the internally generated field of Mercury can be inferred from the MESSENGER observations, and to what extent they will be able to constrain various models of Mercury's magnetic field generation. Based on the results of our simulations, we argue that it should be possible to infer not only the dipole component, but also the quadrupole and possibly even higher harmonics of the Mercury's planetary magnetic field. We furthermore expect that some of the crucial measurements for specifying the Hermean internal field will be acquired during the initial fly-bys of the planet, before MESSENGER goes into orbit around Mercury.     

Experimental test of a radiative transfer model of the optical effects of space weathering

We compare laboratory measurements of the optical effects of nanophase iron on near-IR reflectance spectra of transparent silica gel infused with small iron particles [Noble, S.K., Pieters, C.M., Keller, L.P., 2007. Icarus 192, 629-642] with a radiative transfer model of the process [Hapke, B., 2001. J. Geophys. Res. 106 (E5), 10039-10074]. We find that the measurements exhibit reddening and darkening effects of nanophase (<50 nm) iron particles, a darkening effect of somewhat larger particles (>50 nm) and mixing effects of silica gel particles of varying total iron abundance. The radiative transfer model reproduces the effects of nanophase iron within the experimental uncertainties.     

气汞的第一个同震效应记录

利用杭州超距科技有限公司最近研发的ATG-6138型测汞仪在云南省弥勒井气汞（Hg）观测中记录到尼泊尔8.1级地震的同震效应。这是我国气汞观测的第一个同震效应的纪录。这一事实表明了进一步提升地震地下流体化学量观测仪器的观测精度与采样率,有可能记录到固体潮与同震效应等更多的地壳动力作用信息,从而进一步提升其地震前兆监测能力。     

Degradation Pathway of the Photochemical Oxidation of Ethylenediaminetetraacetate (EDTA) in the UV/H2O2-process

The degradation pathway for the oxidation of EDTA in the UV/H₂O₂-process was investigated. In absence of iron ions, the mineralization of EDTA is dominated by the reaction of the HO-radicals generated by the photolysis of H₂O₂. The organic degradation products iminodiacetate (IMDA), glycinate, oxamate, glyoxylate, oxalate and formate, and the inorganic degradation products carbon dioxide, ammonia, nitrate, nitrite, and cyanate were found. In the presence of iron ions, photolytic decarboxylation processes inside the complex get an important role during degradation, and the organic degradation products ethylenediaminetriacetate (ED3A), ethylenediaminediacetate (EDDA), ethylenediaminemonoacetate (EDMA) were also found. By combining product studies with balances of carbon and nitrogen, the degradation pathway in the UV/H₂O₂-process could be elucidated. The degradation of EDTA was fast (k_deg = 0.012 s^–1), and no toxic degradation products were identified. Therefore, the process is well suited for the elimination of EDTA in water treatment.     

Organohalogen contaminants and total mercury in forage fish preyed upon by thick-billed murres in northern Hudson Bay

Twelve marine fish species collected from a thick-billed murre (Uria lomvia) breeding colony in northern Hudson Bay in the Canadian Arctic during 2007–2009 were analyzed for legacy organochlorines (e.g. PCBs, DDT), polybrominated diphenyl ethers (PBDEs), perfluorinated carboxylates (PFCAs) and sulfonates (PFSAs), and total mercury (Hg). No one species of prey fish had the highest levels across all contaminant groups analyzed. For the two pelagic fish species sampled, concentrations of the major organochlorine groups (e.g. Σ₂₁PCB, ΣDDT, ΣCHL, ΣCBz), ΣPBDE, ΣPFCA and Hg were consistently higher in Arctic cod (Boreogadus saida) than in capelin (Mallotus villosus). Biomagnification factors from whole fish to thick-billed murre liver across all species were generally higher for Σ₂₁PCB and ΣDDT. ΣPBDE did not biomagnify.     

Mercury enrichments in core sediments in Hugli–Matla–Bidyadhari estuarine complex,north-eastern part of the Bay of Bengal and their ecotoxicological significance

Mercury concentrations (Hg_T) in fine-grained fraction (<63 μm) of core sediments of the Hugli–Matla–Bidyadhari estuarine complex, India were analyzed. Results revealed a wide range of spatial variations (<4–93 ng g⁻¹ dry weight) with a definite enhancement level at the lower stretch of the estuarine complex infested with mangrove plants, which might act as a sink to Hg_T. An elevated concentration of Hg was encountered in surface/subsurface layer of the core in majority of the cases resulting from physical, biogenic and postdepositional diagenetic processes that remobilized and resuspended the metal from deeper sediments. A strong positive correlation was observed between the Hg and clay fraction content of the sediments, while the correlations of Hg with Al, Fe and Mn were poor. Based on the index of geoaccumulation (I _geo) and effects range-low (ER-L) value, it is considered that the sediments are less polluted and thus there is less chance of ecotoxicological risk to organisms living in sediments.     

Could giant impacts cripple core dynamos of small terrestrial planets?

Large impacts not only create giant basins on terrestrial planets but also heat their interior by shock waves. We investigate the impacts that have created the largest basins existing on the planets: Utopia on Mars, Caloris on Mercury, Aitken on Moon, all formed at ∼4 Ga. We determine the impact-induced temperature increases in the interior of a planet using the “foundering” shock heating model of Watters et al. (Watters, W.A., Zuber, M.T., Hager, B.H. [2009]. J. Geophys. Res. 114, E02001. doi:10.1029/2007JE002964). The post-impact thermal evolution of the planet is investigated using 2D axi-symmetric convection in a spherical shell of temperature-dependent viscosity and thermal conductivity, and pressure-dependent thermal expansion. The impact heating creates a superheated giant plume in the upper mantle which ascends rapidly and develops a strong convection in the mantle of the sub-impact hemisphere. The upwelling of the plume rapidly sweeps up the impact-heated base of the mantle away from the core-mantle boundary and replaces it with the colder surrounding material, thus reducing the effects of the impact-heated base of the mantle on the heat flux out of core. However, direct shock heating of the core stratifies the core, suppresses the pre-existing thermal convection, and cripples a pre-existing thermally-driven core dynamo. It takes about 17, 4, and 5 Myr for the stratified cores of Mars, Mercury, and Moon to exhaust impact heat and resume global convection, possibly regenerating core dynamos.