四川盆地东部地区下志留统龙马溪组页岩储层特征

四川盆地是中国西南部重要的含油气盆地,在东部和南部地区下志留统龙马溪组页岩广泛发育。在川东南、鄂西渝东地区的勘探井中志留系具有良好的气显示。研究区龙马溪组厚65~516m,底部为一套海侵沉积的富含笔石的黑色页岩,龙马溪组向上和向东砂质和钙质含量增加,演变为浅水陆棚沉积。龙马溪组主要由层状-非层状泥/页岩、白云质粉砂岩、层状钙质泥/页岩、泥质粉砂岩、层状-非层状粉砂质泥/页岩、粉-细粒砂岩、钙质结核、富含有机质非层状页岩8种岩相组成。总有机碳含量(TOC)为0.2%~6.7%。有机质以II型干酪根为主,Ro为2.4%~3.6%。页岩中石英矿物含量在2%~93%,主要呈纹层状或分散状分布,主要为陆源碎屑外源成因。龙马溪组页岩岩心孔隙度为0.58%~0.67%,渗透率为0.01×10^-3μm²~0.93×10^-3μm²。扫描电镜下龙马溪组页岩微孔隙度为2%左右,主要包括晶间孔和粒内孔,孔隙直径为100nm~50μm。页岩储层的形成机理主要为有利矿物组合、成岩作用和有机质热裂解作用。龙马溪组与美国Barnett页岩具有一定差异,主要表现在龙马溪组页岩埋藏较深、热演化程度较高、含气量较低、储层较致密、以陆源成因石英为主。对于评价下志留统龙马溪组页岩气勘探前景而言,今后须重点加强针对龙马溪组底部黑色硅质岩系石英成因、成熟度、埋藏史、含气量等方面的研究,以及进行详细的古地貌和古环境恢复。     

Defining the concept of stratigraphic grade and applying it to stratal (reservoir) architecture and evolution of the slope-to-basin profile: An outcrop perspective

Stratigraphic grade is the similarity of the morphology of successive slope-to-basin profiles in a genetically related depositional system. In this article we use data collected from regional cross-sections of six depositional systems, stratal architecture derived from outcrops of the Lewis Shale (Wyoming, USA), and the Ross Sandstone (Ireland), and supplementary outcrop and subsurface data from other depositional systems to determine how stratigraphic grade relates to stratal (reservoir) architecture in deepwater systems.Four methods are developed that collectively define stratigraphic grade: (1) regional stacking patterns of fourth-order stratigraphic surfaces, (2) the relationship between the trajectory of the shelf edge (T_se) and the trajectory of the depocenter (T_d) for fourth-order stratigraphic units, (3) morphology of the slope-to-basin profiles of fourth-order stratigraphic surfaces, and (4) the similarity of the morphologies of slope-to-basin profiles of fourth-order surfaces in a system (σ_s, σ_r). Several characteristics of stratigraphic (reservoir) architecture of fourth-order stratigraphic cycles are related to stratigraphic grade: (1) longitudinal distribution of sandstone in fourth-order cycles, (2) location of maximum sandstone relative to the depocenter of fourth-order cycles, (3) lengths of fourth-order submarine fans, and (4) longitudinal and vertical distribution of architectural elements. Stratigraphic grade is thus a predictor of reservoir architecture and can thereby be used to reduce the uncertainty in the interpretation of subsurface data.The concept of stratigraphic grade is useful in understanding the stratigraphic evolution of deepwater systems. Most deepwater systems analyzed in this study initiated as out-of-grade and temporally evolved to graded systems over a time span of millions of years. Systems rarely evolve from graded to out-of-grade. First-order controls on stratigraphic grade are determined to be angle of slope, tectonically forced changes in angle of slope during deposition, and sediment supply.     

桂中坳陷环江凹陷上古生界海相页岩储层孔隙结构和分形特征研究

通过有机地化分析、全岩X衍射矿物分析、甲烷等温吸附及低压氮气吸附实验,本文对桂中坳陷环江凹陷上古生界页岩样品的孔隙结构及分形特征进行了研究.结果表明:研究区页岩总有机碳含量(TOC)平均为2.40%,热成熟度(Ro)平均为2.65%,处于过成熟演化阶段.页岩主要的矿物组成为石英和黏土.页岩的比表面积平均为5.86 m2/g,孔容平均为0.014 9 mL/g,平均孔径为11.2 nm.页岩中发育大量的中孔,主要呈两端开口的圆筒形孔或四边开放的平行板状孔.页岩中TOC含量和石英含量越多,微-中孔越发育、比表面积和孔容越大,而平均孔径则变小.通过Frenkel-Halsey-Hill (FHH)模型和氮气吸附实验数据计算得到孔隙表面分形维数D1(平均为2.428 4)和孔隙结构分形维数D2(平均为2.622 2),对应的相对压力(P/P0)分别是0~ 0.45和0.45 ~ 0.99.分形维数D1、D2随着比表面积、孔容的增加而增加,而平均孔径随着前者的增加而减小.分形维数D1、D2、TOC含量、石英含量和甲烷吸附量之间呈现较好的正相关性,但随着黏土矿物含量的增多而减小.分形维数D1与Langmuir压力存在弱负相关性,分形维数D2随Langmuir压力增大有变大的趋势.桂中坳陷西北部页岩分形维数越大,孔隙结构越复杂,其对天然气的吸附和存储能力越强.     

低孔隙度泥页岩应力依赖的各向异性裂纹演化特性研究

本文在实验室对所获取的东营地区层理发育的低孔隙度页岩和泥岩的各向异性裂纹演化特性进行了研究, 获得了各向同性条件下泥页岩的力学与超声波响应特性, 分析了应力幅度对于页岩声波速度和各向异性的影响.主要结论包括:(1)泥页岩在循环载荷下存在滞后效应, 表明其经历了去压实或油气产生导致的超压; (2)泥岩和页岩具有不同程度的各向异性, 随着各向同性压力的增高微裂隙逐渐闭合, 样品的各向异性程度减弱; (3)分析了岩石韧度和裂纹损伤参数随压力的变化特征, 相比泥岩, 页岩各向异性程度更高, 随压力变化更明显, 其裂纹导致的附加各向异性更强; (4)分析了各向异性岩石的动态弹性模量特征, 由于软裂隙空间的闭合, 动态弹性模量在低压条件下都随着围压的增加有硬化趋势.     

泥岩、页岩声速各向异性及其影响因素分析

在实验室超声波频率下(纵波主频为700kHz、横波为250kHz)对层理发育的页岩和泥岩的各向异性进行了研究,给出了在干燥和油饱和条件下,样品不同方向上纵、横波速度以及各向异性参数随压力的变化规律. 用X 射线衍射和扫描电镜分析了样品中引起各向异性的原因,指出平行于层理定向排列的粘土矿物和微裂隙是使样品显示出强弹性各向异性的内在原因. 随着压力的增高微裂隙逐渐闭合,样品的各向异性程度减弱. 孔隙流体的存在增强了孔隙（裂隙）的刚度,减弱了各向异性随压力增大而减小的趋势.     

鄂尔多斯盆地南部延长组长7油组页岩层系天然裂缝发育特征及主控因素

利用地表露头、岩心、薄片和测井资料,对鄂尔多斯盆地南部长7油层组陆相页岩层系天然裂缝的成因类型、发育特征和主控因素进行研究。按地质成因,鄂尔多斯盆地南部长7油层组页岩层系的天然裂缝可以分为构造裂缝和成岩裂缝两大类,其中构造裂缝主要包括剪切裂缝和张性裂缝;成岩裂缝主要包括层理缝、页理缝和收缩裂缝。不同岩性中的天然裂缝发育情况明显不同,致密砂岩中以构造裂缝为主,层理缝仅在粉砂岩和局部细砂岩中发育;页岩和凝灰岩中页理缝、层理缝和构造裂缝均比较发育。不同类型的天然裂缝主控因素明显不同,构造裂缝的发育主要受岩性和岩石力学层层厚控制;砂岩中层理缝的发育主要受碳质纹层、粘土矿物转化程度等因素控制;凝灰岩中层理缝的发育主要受刚性玻屑脱玻化作用的控制;页岩中页理缝的发育主要受纹层、TOC含量和黄铁矿含量的控制。     

河南中牟区块页岩气特征及勘探前景分析

文章通过对河南中牟区块海陆过渡相太原组和山西组页岩气形成的地质条件与特征分析,认为区块构造较为简单、稳定,其海陆交互相沉积环境控制太原组和山西组页岩发育,分布广泛,富含有机质页岩厚度大,为页岩气目标层;有机碳含量w(TOC)=1.1%~3.7%,有机质类型为Ⅲ型,有机质成熟度指标镜质体反射率(Ro)3.0%~3.8%;目标层有效孔隙度1.0%~5.0%,黏土矿物以伊利石和伊/蒙混层为主;含气量0.5~3.3m~3/t,平均1.7m~3/t。对牟页1井太原组、山西组三段采用快钻桥塞分段压裂,累计注入压裂液量5 055.9m~3,加砂量202.7m~3,三层合采求产为1 256m~3/d,标志着南华北盆地海陆过渡相页岩气勘探取得重大发现。通过地质评价和资源量计算,中牟区块太原组、山西组页岩气地质资源量较为丰富,勘探有利区面积大,具备较好的页岩气勘探前景。     

Jurassic source rocks in the Vienna Basin (Austria): Assessment of conventional and unconventional petroleum potential

The Upper Jurassic marlstones (Mikulov Fm.) and marly limestones (Falkenstein Fm.) are the main source rocks for conventional hydrocarbons in the Vienna Basin in Austria. In addition, the Mikulov Formation has been considered a potential shale gas play. In this paper, organic geochemical, petrographical and mineralogical data from both formations in borehole Staatz 1 are used to determine the source potential and its vertical variability. Additional samples from other boreholes are used to evaluate lateral trends. Deltaic sediments (Lower Quarzarenite Member) and prodelta shales (Lower Shale Member) of the Middle Jurassic Gresten Formation have been discussed as secondary sources for hydrocarbons in the Vienna Basin area and are therefore included in the present study.The Falkenstein and Mikulov formations in Staatz 1 contain up to 2.5 wt%TOC. The organic matter is dominated by algal material. Nevertheless, HI values are relative low (<400 mgHC/gTOC), a result of organic matter degradation in a dysoxic environment. Both formations hold a fair to good petroleum potential. Because of its great thickness (∼1500 m), the source potential index of the Upper Jurrasic interval is high (7.5 tHC/m²). Within the oil window, the Falkenstein and Mikulov formations will produce paraffinic-naphtenic-aromatic low wax oil with low sulfur content. Whereas vertical variations are minor, limited data from the deep overmature samples suggest that original TOC contents may have increased basinwards. Based on TOC contents (typically <2.0 wt%) and the very deep position of the maturity cut-off values for shale oil/gas production (∼4000 and 5000 m, respectively), the potential for economic recovery of unconventional petroleum is limited. The Lower Quarzarenite Member of the Middle Jurassic Gresten Formation hosts a moderate oil potential, while the Lower Shale Member is are poor source rock.     

特殊测井在准南地区乌鲁木齐一带芦草沟组页岩油气层评价中运用

以地表地质调查成果为基础,以钻探、地质综合录井、核磁共振测井、电成像测井、正交多极子阵列声波等测井方法为手段,以岩石学特征、储层物性、储集空间类型和储集性能研究为重点,开展准南冲段带东段乌鲁木齐一带二叠系芦草沟组页岩油气评价。研究结果表明:该区带芦草沟组页岩含油气7层,其中优质含油层2层(64和66层);页岩储层矿物成分以高脆性矿物为主,物性特征表现为天然高导裂缝发育和低孔特低渗;油气藏表现为具中等含油饱和度的典型裂缝型油气藏特征。页岩储层各向异性较强,总体最大水平主应力为NWW向。     

Pore structure and heterogeneity of shale gas reservoirs and its effect on gas storage capacity in the Qiongzhusi Formation

Fine characterization of pore systems and heterogeneity of shale reservoirs are significant contents of shale gas reservoir physical property research.The research on micro-control factors of low productivity in the Qiongzhusi Formation(Fm.)is still controversial.The lower Cambrian Qiongzhusi Fm.in the Qujing,Yunnan was taken as the object to investigate the influence of mineral compositions on the phys-ical properties of the reservoir and the heterogeneity of shale,using the algorithm to improve the char-acterization ability of Atomic Force Microscopy(AFM).The results showed that:(1)The pores are mainly wedge-shaped pores and V-shaped pores.The pore diameter of the main pore segment ranges from 5 to 10 nm.Mesopores are mainly developed in the Qiongzhusi Fm.shale in Well QD1,with the average pore diameter of 6.08 nm.(2)Microscopic pore structure and shale surface properties show strong hetero-geneity,which complicates the micro-migration of shale gas and increases the difficulty of identifying high-quality reservoirs.(3)The increase of clay mineral content intensifies the compaction and then destroys the pores.Conversely,brittle minerals can protect pores.The support and protection of brittle minerals to pores space depend on their content,mechanical properties and diagenesis.(4)Compression damage to pores,large microscopic roughness and surface fluctuations and strong pore structure heterogeneity are the reasons for the poor gas storage capacity of the Qiongzhusi Fm.,which will lead to poor productivity in the Qiongzhusi Fm.