Generation and Evolution of Ore Fluids for Porphyry Cu-Au Mineralization of the Santo Tomas II (Philex) Deposit, Philippines

Abstract: The Santo Tomas II (Philex) deposit is a porphyry Cu‐Au deposit, located in the southern part of the Baguio mineral district, Benguet Province, northern Luzon, Philippines. The Santo Tomas II deposit is associated with an intrusive complex consisting of four rock types that are distinguished based on petrography. They are 1) post‐ore clinopyroxene‐bearing hornblende andesite porphyry, 2) ore‐generating hornblende andesite porphyry, 3) hornblende quartz diorite porphyry and 4) porphyritic hornblende quartz diorite. K‐Ar age of hydrothermal biotitization was estimated to be 1.5±0.4 Ma. A number of intrusive bodies having broadly similar petrography and K‐Ar age occur in the vicinity of the Santo Tomas II deposit, such as at Clifton, Ligay (Binang), Bumolo (Waterhole) and Philex Main Camp areas. The intrusions at the Santo Tomas II deposit and in the vicinity are characterized by high X_Mg (Mg/[Mg+Fe] atomic ratio, about 0.7 or higher) of mafic silicate phenocrysts such as hornblende, and high sulfur contents (> 0.2 wt% as SO₃) in accessory microphenocrystic apatite, suggesting a highly oxidizing condition. Sulfur is accommodated dominantly as oxidized species since the crystallization of phe‐nocrysts. Sub‐dendritic rim of tremolitic amphibole on hornblende phenocryst in the ore‐generating andesite porphyry at the Santo Tomas II deposit suggests interaction of magma and aqueous fluid(s) exsolved due to decompression during intrusion. Dissemination of magnetite is associated with hydrothermal biotitization and is followed by sheeted and stockwork quartz veinlets having silician magnetite and rare titanohematite instead of Cu‐Fe sulfides. The silician magnetite‐rich quartz veinlet was formed at f_O2 near the hematite‐magnetite buffer at nearly magmatic temperature, where sulfur dominantly existed as oxidized species such as SO₂. Chalcopyrite and bornite, which commonly exhibit micrographic texture often accompanying Pd telluride and native gold/Au‐rich electrum, are associated with subsequent anhydrite (‐quartz) veinlets and stringers. Both intermediate solid solution (iss) and bornite solid solution (bnss) are thought to have coprecipitated primarily at above 500°C based on fluid inclusion microthermometry and sulfur isotope thermometry applied for anhydrite and associated chal‐copyrite and bornite. The initial iss is considered to have converted to chalcopyrite partly replacing bnss during cooling. The hypersaline polyphase fluid inclusions abundantly found in the sheeted and stockwork quartz as well as anhydrite veinlets with scarce gaseous inclusions suggest that they have been trapped in the two aqueous fluid immiscible region. The western Luzon arc associated with porphyry Cu mineralization is characterized by oxidized hydrous magmatism and shallow emplacement, and by the source of sulfur enriched in ³⁴S.     

A Study Of Coherent Structures In The Atmospheric Surface Layer Over Short And Tall Grass

Ejection and sweep eddy motions are coherent structures in the atmospheric surface layer. These structures are responsible for surface-layer fluxes of sensible heat and momentum. This study analyzes these structures over the same surface in short and tall grass situations. It is shown that momentumsweep eddy motions are dominant in both short and tall grass situations. Theratio between eddy structures revealed that the small-scale eddies are activatedin tall grass conditions. The study applies to unstable conditions duringdaytime.     

The Footprint for Estimation of Atmosphere-Surface Exchange Fluxes by Profile Techniques

The flux footprint, that is the contribution per unit emission from each element of the upwind surface area to measurement of the vertical flux of a passive scalar, is calculated for fluxes estimated by micrometeorological profile techniques. It is found that the upwind extent of the footprint for concentration-profile flux estimates is similar to that of the footprint for eddy-covariance flux measurements, when the eddy-covariance measurement is made at a height equal to the arithmetic mean of the highest and lowest profile measurement heights for stable stratification or the geometric mean for unstable stratification. The concentration-profile flux footprint depends on the ratio of the highest to the lowest measurement height, but is insensitive to the number of measurement levels. The concentration-profile flux footprint extends closer to the measurement location than does the 'equivalent eddy-covariance flux footprint, and the difference becomes more pronounced as the ratio of the profile measurement heights increases. The flux footprint for the Bowen-ratio technique is identical to that for a two-level profile measurement only for very limited circumstances. In the more general case, a flux footprint cannot be defined for the Bowen-ratio technique and the uniform upwind fetch required for representative flux measurements depends on the specific spatial distribution of surface fluxes.     

Monitoring alluvial sand suspension by eddy correlation

Eddy correlation techniques are standard tools in micrometeorology and oceanography to measure momentum and contaminant transport across turbulent boundary layers. They can, in theory, be used to estimate the net vertical suspended sediment flux directly over different areas of an alluvial channel boundary, and thus disclose ongoing erosion/deposition patterns. The basic principles and main problems in applying the technique to alluvial suspension are first introduced. Results from a trial application of the method in a large sand bed river are then presented; the focus of the analysis is on the substantial (and surprising) contributions of multi-minute flow fluctuations to suspension work in the study environment. The data were collected in a 10 m deep channel of the Fraser River near Mission, British Columbia, Canada. Turbulent fluctuations of flow components streamwise and normal to the bed, along with the output of an optical suspended sediment sensor, were monitored over 7 h, 1 m above the bed. Flow velocities averaged 0·9 ms^?1 and mean suspended sediment concentrations 500 mgl^?1, at sensor level above 1–5 dm high dunes. Spectral analysis of the records reveals that approximately 30 per cent of the vertical suspended sand mixing across the sensor level (and roughly as much of the momentum exchange) was linked to gradual flow oscillations with periods between 1 and 13·6 min (underlying briefer, turbulent fluctuations). Extended periods of sediment-rich, slightly upward directed but slower mean flow alternated with periods of sediment-poor, slightly downward and faster mean flow; these slow fluctuations involved 10–20 cms^?1 changes in 5 min average flow speed, 2–4· changes in vertical flow angle and 100 mgl^?1 changes in mean sand concentration. To obtain accurate eddy-correlation estimates of the vertical suspension flux in the study conditions, hour-scale flow and turbidity records that include many of these multi-minute cycles appear to be necessary. The spectra of the Fraser River near-bed signals do not conspicuously differ in overall shape (in terms of low-frequency content and location of peak) from turbulent spectra encountered in some atmospheric boundary layers. Nonetheless, the long period fluctuations observed on the Fraser River may not be turbulent; rather they may reflect slowly evolving perturbations in the near-bed streamlines, caused by bedform translation or gradual fluctuation within the large-scale streamwise cells of the secondary flow.     

岩石磁化率各向异性的频散现象

在磁化磁场为恒定磁场（无定向磁力仪─-Ａ）与１０ｋＨｚ交变磁场（ＭｉｎｉｓｅＰ旋转磁力仪─-Ｍ）的两种情况下，作岩样比测时发现，后者测得的主磁化率值к^Ｍ较小，而且沿磁性叶理面方向ｆ的主磁化率值к_ｍａｘ与к_ｉｎｔ比沿其法线方向ｎ上的к_ｉｎｔ减少得更多．作者以涡流磁滞机构对磁性载体材料的“磁屏蔽”作用发生了各向异性的影响来解释此现象；并推测磁化率各向异性存在频散现象．     

Sonic anemometers in aeolian sediment transport research

Fast-response wind and turbulence instruments, including sonic anemometers, are used more and more in aeolian sediment transport research. These instruments give information on mean wind, but also on fluctuations and turbulent statistics, such as the uw covariance, which is a direct measure of Reynolds' stress (RS) and friction velocity. This paper discusses the interpretation of sonic anemometer data, the transformations needed to get proper results and turbulence spectra, and how they are influenced by instrument size, sampling frequency, and measurement height.Turbulence spectra characterize how much the different frequencies in the turbulent signals contribute to the variance of wind speed, or to the covariance of horizontal and vertical wind speed. They are important in determining the measurement strategy when working with fast-response instruments, such as sonic anemometers, and are useful for interpreting the measurement results. Choices on the type of sonic anemometer, observation height, sampling period, sampling frequency, and filtering can be made on the basis of expected high and low-frequency losses in turbulent signals, which are affected by those variables, as well as wind speed and atmospheric stability.Friction velocity and RS, important variables in aeolian sediment transport research, are very sensitive to tilt or slope errors. During a field experiment, the slope sensitivity of the RS was established as 9% per degree of slope, which is 1.5 times the value reported in literature on the basis of theoretical considerations. An important reason for the difference probably is the large influence of streamline curvature on turbulence statistics and thereby on the slope sensitivity of the RS. An error of 9% per degree of slope in the RS will translate into an error of approximately 4% per degree of slope in the calculated friction velocity.Space–time correlation of the horizontal wind speed is much larger than that of the vertical wind speed and the instantaneous RS. This largely explains why, in previous studies, a poor correlation was found between instantaneous RS measured at 3 m height and saltation flux near the surface, whereas the correlation between wind speed at some height and saltation flux was much better. Therefore, the poor correlation between RS away from the surface and saltation flux does not contradict that saltation flux is caused by RS.     

Geology and Hydrothermal Alteration of the Low Sulfidation

Abstract. The Pantingan Gold System (PGS) is a vein-type epithermal prospect exposed within the summit caldera of Mount Mariveles, Bagac, Bataan (Luzon), Philippines. It consists of nine major veins, eight of which trend NW-WNW and distributed in an en echelon array. The eastern tips of these veins appear to terminate near the NE-NNE trending Vein 1, which is located in the easternmost portion of the prospect. Metal assay results on vein and wall rock samples indicate concentrations of 0.01 to 1.1 g/ton Au, trace to 34 g/ton Ag and 0.003 to 0.02 % Cu. Andesite lava flow deposits host the PGS. Potassium-Argon isotopic dating of these andesites yields anarrow age range of 0.88± 0.13 to 1.13 ± 0.17 Ma. The surface exposures of the veins (up to 5 m wide) are encountered at different levels between 590–740 masl. These commonly display a massive texture although banding prominently occurs in Vein 1. The veins consist of gray to cream-colored crystalline and chalcedonic quartz and amorphous silica. Pyrite is the most ubiquitous sulfide mineral. It occurs either as fine-grained disseminations and aggregates in quartz or as infillings in vugs. Calcite, marcasite and bornite are also occasionally noted in the deposit. The prospect shows silicic, argillic, propylitic and advanced argillic alteration zones. Silicic and argillic alterations are confined in the immediate wall rocks of the quartz veins. Argillic alteration grades to a propylitic zone farther away from the veins. The advanced argillic alteration zone, indicated by a suite of acidic clay minerals that include kaolin-ite, dickite, pyrophyllite and alunite, might have been imprinted during the late stages of gold deposition. As a whole, the PGS displays geological and mineralogical features typical of gold mineralization in a low sulfidation, epithermal environment. It is also representative of a young, tectonically undisturbed gold deposit.     

Update of a Footprint-Based Approach for the Characterisation of Complex Measurement Sites

Horizontal heterogeneity can significantly affect the flux data quality at monitoring sites in complex terrain. In heterogeneous conditions, the adoption of the eddy-covariance technique is contraindicated by the lack of horizontal homogeneity and presence of advective conditions. In addition, uncertainty concerning the sources or sinks influencing a measurement compromises the data interpretation. The consideration of the spatial context of a measurement, defined by a footprint analysis, can therefore provide an important tool for data quality assessment. This study presents an update of an existing footprint-based quality evaluation concept for flux measurement sites in complex terrain. The most significant modifications in the present version are the use of a forward Lagrangian stochastic trajectory model for the determination of the spatial context of the measurements, and the determination of effective roughness lengths with a flux aggregation model in a pre-processing step. Detailed terrain data gathered by remote sensing methods are included. This approach determines spatial structures in the quality of flux data for varying meteorological conditions. The results help to identify terrain influences affecting the quality of flux data, such as dominating obstacles upwind of the site, or slopes biasing the wind field, so that the most suitable footprint regions for the collection of high-quality datasets can be identified. Additionally, the approach can be used to evaluate the performance of a coordinate rotation procedure, and to check to what extent the measured fluxes are representative for a target land-use type.     

Turbulence Over Urban-type Roughness: Deductions from Wind-tunnel Measurements

Turbulence data from experiments conducted over a staggered cube array, modelling a neutrally stable atmospheric boundary layer in an urban environment, are presented. The results support the contention that organised eddy structures in the near-wall region differ significantly from those in regular smooth-wall flows or in rough-wall boundary layers with much smaller h/δ ratios (where δ and h are the boundary-layer thickness and the height of the roughness elements, respectively). Attention is concentrated on spatial correlations, spectra (and thus the dominant length and time scales), maps of anisotropy invariants and quadrant analyses of the stress tensor. Results are obtained within both the roughness sublayer (i.e. the region above the roughness but within which the flow is spatially inhomogeneous) and the canopy region (i.e. below the height of the roughness elements) and discussion includes consideration of the turbulence kinetic energy balance at various heights.     

Surface Fluxes and Characteristics of Drying Semi-Arid Terrain in West Africa

This study examines the seasonal cycle of the components of the surface energy balance in the Volta basin in West Africa as part of the GLOWA-Volta project. The regional climate is characterized by a strong north–south gradient of mean annual rainfall and the occurrence of pronounced dry and wet seasons within one annual cycle, causing a strong seasonal variation in the natural vegetation cover. The observations are conducted with a combined system, consisting of a Large Aperture Scintillometer (LAS) for areally averaged sensible heat flux, radiometers and sensors for soil heat flux. For comparisons the eddy-covariance (EC) method providing the fluxes of momentum, sensible and latent heat is utilized as well. The measurements of a seasonal cycle in 2002/2003 were gathered including the rapid wet-to-dry transition after the wet season at two locations in Ghana, one in the humid tropical southern region and one in the northern region. A direct comparison and the energy balance closure of the two methods are investigated for daytime and nighttime separately. An attempt is made to understand and explain the differences between the two methods and the closure of energy budget found for these. It is found that the two systems correspond well during daytime. During nighttime the LAS seems to perform more realistically than the EC system. Considering the fact that a LAS system is much easier to use in the climate conditions of the Volta basin, it is concluded that the LAS approach is very suitable in this type of climate conditions. Surface conductances are estimated by rearranging the Penman–Monteith equation and compared to a Jarvis-type model optimised for savannah conditions. It is found that temperature dependence should be included in the conductance formulation in contrast to earlier findings. Based on the findings the gathered dataset can be used for further model studies of the climate and environment of West Africa.