Clay Minerals and Geotechnical Index Properties of Marine Clays in East Asia

Clay mineral composition and geotechnical index properties of marine clays collected from Singapore, Korea, and Japan were investigated, and the correlation of clay mineral composition with the consistency limits and activity of the clays was examined. Predominant clay minerals were kaolinite for Singapore clay, kaolinite, vermiculite, and illite for Pusan clay, and smectite for Hachirogata and Ariake clay from Japan. The activity of clay indicates that Singapore clay is classified as normal or inactive, Pusan clay as normal, and Hachirogata and Ariake clays mostly as active. Significant positive correlations were found between smectite percentage in bulk soil and the liquid and plastic limits of the clays.     

Effect of salt of various concentrations on liquid limit,and hydraulic conductivity of different soil-bentonite mixtures

Effect of the various concentrations of NaCl and CaCl₂ on the four different soil-bentonite mixtures has been evaluated. The results show that the liquid limit of the mixtures decreases with an increase in the salt concentration. Liquid limit decreased significantly with an increase in CaCl₂ concentration from 0 to 0.1 N. However, a further increase in the concentration did not produce any significant decrease in liquid limit. A quite opposite trend was observed for the NaCl solution. An increase in NaCl concentration from 0 to 0.1 N did not produce any major decrease in the liquid limit, but a further increase in concentration from 0.1 to 1 N decreased the liquid limit significantly. Consolidation tests were carried out on the mixtures to evaluate the effect of mineralogical composition of the bentonite on the hydraulic conductivity (k) of the mixture in the presence of various salts concentrations. The k for any mixtures was found to be decreasing with decrease in the salt concentration. At relatively low concentration, Ca²⁺ had more effect on the k in comparison to the same concentration of Na⁺. However, at 1 N of NaCl and CaCl₂ almost an equal value of k was observed. A comparison of the performance of four bentonites showed that the mixture with bentonite having highest exchangeable sodium percentage (ESP) exhibited the lowest k when permeated with de-ionized (DI) water, however, k increased with an increase in the salt concentration. Similarly, mixture with a bentonite of lower ESP exhibited a higher k with DI water but with the increase in the salt concentration alteration in the k, compared to all other mixtures, was relatively less.     

The liquid limit of peat and its application to the understanding of Irish blanket bog failures

Catastrophic failures of blanket bogs, involving the escape and outflow of large volumes of semi-liquid basal peat, are well-known phenomena in Ireland but have only very rarely been reported from elsewhere in the world. Their precise causes and mechanisms are as yet unclear. The liquid limit (w _L) was identified as a potentially useful indicator of the susceptibility of peat to such failure because peat has extremely high natural water contents and, as an index property, w _L takes no account of the properties or structures of highly heterogeneous intact peat. However, the usual procedure for determining the w _L of peat is not fully standardised. Prepared samples will normally include potentially highly reactive particles of disrupted fibres and wood fragments that would not be present in such freshly disintegrated form in the field. This paper presents results from w _L determinations of peat obtained from the scar margins of three bog failures in northwest Ireland, using four different test procedures including a method involving wet-sieving of the peat to separate the humified <425-μm fraction for testing without incorporating artificially fragmented particles of fibres. The sampled peat was classified as H₈–H₁₀ according to the von Post humification scale. The fibre contents varied between the sites, but the ash contents were <3% in all but one test sample, and bulk densities (dry and field-wet) of the peat from all three sites were almost identical. w _L results from the wet-sieving method were 708–785%, compared with 633–980% from the standard method. The highest measured field water contents exceeded the wet-sieved w _L for all three of the field sites. Tests of cone penetration into intact peat cores demonstrated the influence of the reinforcing effect of in situ fibres. The results strongly suggest the need to adopt a fully standardised procedure for determining the w _L of peat. Additional shear vane measurements of intact and remoulded peat from a bog failure in Northern Ireland indicated a very high ‘strength sensitivity’. This leads to the suggestion that a slight disturbance of basal peat can lead to a loss of strength that rapidly propagates as local stresses change and cause further remoulding as water contents exceed w _L.     

Effect of organic solvent type on the removal of nitrate ion using liquid membrane technique

In this study, the removal of nitrate ions from aqueous solutions with liquid membrane technique has been investigated for different organic solvent types in which solubilized tetradecyl trimethyl ammonium bromide (TDTMABr) as carrier. n-butyl alcohol, chloroform, and mixture of chloroform + n-hexane (n-hexane 85% + chloroform 15%) were used as organic solvent. Kinetic parameters (k _1d, k _2m, k _2a, t _max, R _m^max, J _m^max, J _a^max) were calculated from obtained data. time R _a values of mixture, butyl alcohol, and chloroform are 0.81, 0.78, and 0.55, respectively. Similarly R _d, R _m, and t _max values of the mixture equal to 0.14, 0.04, and 87.92 min, respectively. This behavior of the system shows the organic solvent type is an effective parameter on separation yield. It can be concluded that the mixture is the most effective organic solvent type among the investigated ones, because liquid membrane systems should be operated within the range of having the R _m, R _d, and t _max values are minimum while R _a values are maximum.     

Reaction between liquid iron and (Mg,Fe)SiO3-perovskite and solubilities of Si and O in molten iron at 27 GPa

The Earth’s core contains light elements and their identification is essential for our understanding of the thermal structure and convection in the core that drives the geodynamo and heat flow from the core to the mantle. Solubilities of Si and O in liquid iron coexisting with (Mg,Fe)SiO₃-perovskite, a major constituent of the lower mantle, were investigated at temperatures between 2,320 and 3,040 K at 27 GPa. It was observed that Si dissolved in the liquid iron up to 1.70 wt% at 3,040 K and O dissolved in the liquid iron up to 7.5 wt% at 2,800 K. It was also clearly seen that liquid iron reacts with (Mg,Fe)SiO₃-perovskite to form magnesiowüstite and it contains Si and O at 27 GPa and at 2,640 and 3,040 K. The amounts of Si and O in the liquid iron are 1.70 and 2.25 wt% at 3,040 K, respectively. The solubilities of Si and O in liquid iron coexisting with (Mg,Fe)SiO₃-perovskite have strong positive temperature dependency. Hence, they can be plausible candidates for the light elements in the core.     

液态二氧化碳(LC)播撒装置应用研究

针对液态二氧化碳(LC)的播撒问题, 给出了其播撒装置的基本特征、播撒率及主要影响因子;用FSSP-100 、2D-C粒子测量仪、三用滴谱仪及能见度仪等设备测定了LC播出物的相态、粒子形状和尺度谱。测定表明:LC播出物为液、固、气态二氧化碳三相共存混合物。液态、固态粒子存在时间约100～101s, 粒子尺度10-1～102μm, 播出物流束中单位体积质量可达3.6 g·m-3。这些测定结果为使用LC作为冷云催化剂提供了可靠依据, 为国内在较暖云顶层状云中开展人工增雨作业提供了合适的催化技术。     

Immiscible two-liquid regions in the Fe-O-S system at high pressure: Implications for planetary cores

We have determined phase relations in the Fe-O and Fe-O-S systems in the range of 15-21 GPa and 1825-2300 °C. Below the liquidus temperatures, solid FeO and metallic liquids are observed in both the Fe-O and the Fe-O-S systems. An immiscible two-liquid region exists in the Fe-O binary system in the pressure range investigated, and the immiscibility gap between Fe-rich metallic liquid and FeO-rich ionic liquid does not greatly change with either pressure or temperature. On the other hand, an immiscible two-liquid region in the Fe-O-S ternary system narrows significantly with increasing pressure at constant temperature and vice versa, and it almost disappears at 21 GPa, and 2300 °C. Immiscible two-liquid regions are thus not expected to exist in the Fe-O-S system in the Earth's core, suggesting that both oxygen and sulfur can be incorporated into the core. Our results are consistent with a geochemical model for the core containing 5.8 wt.% oxygen and 1.9 wt.% sulfur as proposed by McDonough and Sun [McDonough, W.F., Sun, S.-S., 1995. The composition of the Earth. Chem. Geol. 120, 223-253].     

硅酸盐-盐（硫酸盐）流体不混溶：蒙古南部Mushugai-Khuduk含火成碳酸岩杂岩体矿物中的熔体包裹体研究

Crystalline and melt inclusions were studied in garnet,diopside,potassium feldspar,and sphene from the garnet syenite porphyry of the carbonatite-bearing complex Mushugai-Khuduk,southern Mongolia.Phlogopite,clinopyroxene,albite,potassium feldspar,spheric,wollastonite,magnetite,Ca and Sr sulfates,fluorite,and apatite were identified among the crystalline inclusions. The melt inclusions were homogenized at 1010～1080℃and analyzed on an electron microprobe.Silicate,salt,and combined silicate- salt melt inclusions were found.Silicate melts show considerable variations in SiO_2 concentration(56 to 66wt% ),high Na_2O K_2O (up to 17wt% ),and elevated Zr,F,and C1 contents.In terms of bulk rock chemistry,the silicate melts are alkali syenites.During thermometric experiments,salt melt inclusions quenched into homogeneous glasses of predominantly sulfate compositions containing no more than 1.3wt% SiO_2.These melts are enriched in alkalis,Ba,Sr,P,F,and C1.The investigation of the silicate and salt melt inclusions in minerals of the garnet syenite porphyries indicate that these rocks were formed under influence of the processes of crystallization differentiation and magma separation into immiscible silicate and salt(sulfate)liquids.     

岩石破裂过程中电阻率变化机理的探讨

受压岩石在破裂过程中,视电阻率会出现明显的变化,其异常形态与实验条件有很大的关系. 实验中对磁铁石英岩样品施加了单轴压缩,岩石的破裂经反复加载和卸载实现,并在岩样的裂隙中注入了食盐溶液. 在实验的各阶段,对样品的主剖面重建出一系列内部真电阻率分布的图像,揭示了介质内的微细结构,从而探讨了视电阻率变化的原因. 实验发现,岩石中裂隙的存在及所含液体的饱和状态,是岩石在主破裂前控制电阻率变化的两个最重要的因素;低应力状态属常态导电过程,孔隙度的变化是主要因素;高应力状态属裂隙表面导电机制,随着破裂面在岩体内部出现,水和孔隙有了完全贯通的平面,多种导电机制都得以发挥作用. 此外,体导电结构的变化在宏观上表现为各向异性和图样有序性的增强.     

由X射线衍射获得的液体径向分布函数

主要介绍单原子液体、同核分子液体、杂核分子液体和水溶液电子径向分布函数、原子径向分布函数和分子径向分布函数的定义 ,简明阐述了气体、液体和晶体 ,尤其是二维晶体的径向分布函数的物理意义和几何意义。