The “Zero-order Model” revisited: Paul Schindler's influence on the development of trace metal scavenging models

In 1975 Paul Schindler produced the first oceanic trace metal scavenging model to explicitly include the role of surface chemistry as a control on trace metal water column residence times. The eighteen years that have elapsed since the publication of Schindler's seminal paper have seen the development of a variety of oceanic scavenging models; yet, the fundamental insight of his Zero-order Model remains the benchmark. This paper describes the role of Paul Schindler's work on surface chemistry in providing a framework for the current generation of trace element scavenging models.     

On the physical model of earthquake precursor fields and the mechanism of precursors＇timespace distribution──origin and evidences of the strong body earthquake──generating model

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Monoterpene concentrations in and above a forest of scots pine

Diurnal and vertical ambient air measurements of the monoterpenes have been made in and above a Scots pine (Pinus sylvestris) forest of central Sweden, within the boreal northern coniferous biome. Sampling was done with Tenax TA, and analysis by GC and ion trap detection. Daytime mixing ratios were on the order of tenths of a ppbv from the forest floor to the top of the forest, and a factor of 2 or 3 lower above the forest. Mixing ratios at night were at the ppbv level, highest near the forest floor and the crown, and decreased with height above the forest. The highest total concentration observed was 8 ppbv inside the forest at 3 am (GMT). The average terpene composition was 3-carene 32%, -pinene 29%, limonene 18%, -pinene 10%, -phellandrene 7%, camphene 5%, and sabinene at less than 2%. The 3-carene/-pinene ratio varied with wind direction and speed, relative humidity, and wet/dry vegetation, but not with ozone or NO₂ concentration, solar radiation, or temperature. Variations in the observed terpene composition at the sampling site are mainly caused by the influence of other vegetation in the vicinity of the site. It would seem that wet Scots pine emits more 3-carene relative to -pinene than does dry pine.     

High-resolution sedimentary record of lead in the coastal mud of the East China Sea in the past one hundred and fifty years

In the East China Sea （ECS）, there are some mud areas, including the south coastal mud area, the north coastal mud area, and the mud area to the southwest of Cheju Island. X-ray fluorescence （XRF） techniques and Thermal Ionization Mass Spectrometry （TIMS） were used to study the high-resolution sedimentary record of Pb concentrations and Pb stable isotopic compositions in the past one hundred and fifty years in the coastal mud of the ECS. Pb concentrations of a ^210Pb dating S5 core in the study area have increased rapidly since 1980, and reached the maximal value with 65.08 μg/g in 2000, corresponding to the fast economic development of China since the implementation of the ＂Reform and Open Policy＂ in 1978; ^206Pb/^207Pb ratios generally had stabilized at 1.195 from 1860 to 1966, and decreased gradually from 1966 to 2000, indicating that the anthropogenic source Pb contribution to the ECS has increased gradually since 1966, especially since 1980. Pb concentrations decreased distinctly from 2000 to 2003 and ^206Pb/^207Pb ratios increased from 2001 to 2003, corresponding closely to the ban of lead gasoline from 2000 in China. From 1950 to 2003, there occurred four distinct decrease events of ^206Pb/^207Pb, possibly responding to the Changjiang River （Yangtze River） catastrophic floods in 1998, 1991, 1981 and 1954; from 1860 to 1966, there were two decrease periods of ^206Pb/^207Pb, which may respond to the catastrophic floods of Changjiang River in 1931 and 1935, and 1870. As a result of the erosion and drowning by the catastrophic floods, the anthropogenic lead accumulated in soil and water environments over a long period of time was brought into the Changjiang River, then part of them was finally transported into the ECS, which leads to changes in Pb stable isotopic composition.     

Heavy metals in freshly deposited sediments of the river Subernarekha, India: an example of lithogenic and anthropogenic effects

Heavy metal distribution patterns in river sediments aid in understanding the exogenic cycling of elements as well as in assessing the effect of anthropogenic influences. In India, the Subernarekha river flows over the Precambrian terrain of the Singhbhum craton in eastern India. The rocks are of an iron ore series and the primary rock types are schist and quartzite. One main tributary, the Kharkhai, flows through granite rocks and subsequently flows through the schist and quartzite layers. The Subernarekha flows through the East Singhbhum district, which is one of India’s industrialised areas known for ore mining, steel production, power generation, cement production and other related activities. Freshly deposited river sediments were collected upstream and downstream the industrial zone. Samples were collected from four locations and analysed in <63-μm sediment fraction for heavy metals including Zn, Pb, Cd and Cu by anodic stripping voltammetry. Enrichment of these elements over and above the local natural concentration level has been calculated and reported. Sediments of the present study are classified by Muller’s geo-accumulation index (I _geo) and vary from element to element and with climatic seasons. During pre-monsoon period the maximum I _geo value for Zn is moderately to highly polluted and for Cu and Pb is moderately polluted, respectively, based on the Muller’s standard. Anthropogenic, lithogenic or cumulative effects of both components are the main reasons for such variations in I _geo values. The basic igneous rock layer through which the river flows or a seasonal rivulet that joins with the main river may be the primary source for lithogenic components.     

大气CO2浓度升高对土壤中不同粒级碳的影响

不同粒级土壤中的碳有着不同的周转规律，在高CO2浓度条件下，它们含量的变化将在一定程度上反映土壤碳是累积还是减少，对明确土壤碳的变化趋势有重要意义．采用田间培养试验初步模拟研究在高CO2浓度条件下土壤不同粒级碳的分布．结果表明，加入秸秆培养1年，由于CO2浓度升高的原因导致在低氮（LN）、常规氮（NN）和高氮（HN）水平下土壤中碳分别增加0．01、1．10、1．22g／kg，表现为粒级〈53μm土壤颗粒中碳分别增加1．53、2．19、2．70g／kg．粒级〈53μmm土壤颗粒碳量的增加，主要是由于其重量分配百分数显著增加36．2％，碳浓度增加5．4％；粒级〉250μm和250～53μm土壤颗粒部分虽然其碳浓度分别增加20．8％和17．3％（P〈0．05），怛由于重量分配百分数分别显著降低22．8％和36．1％，结果碳量降低．试验表明高CO2浓度导致不同粒级土壤的分配及碳浓度的变化；高氮施肥水平下有增加土壤碳量特别是小粒级土壤碳量的趋势．     

半无限空间中圆形孔洞周围SH波的散射

建立了求解在含有圆形孔洞的弹性半空间中SH波散射与圆形孔洞附近动应力集中问题的解析方法。利用SH波散射的对称性和多极坐标的方法，构造了一个可以预先满足半空间自由表面上应力自由边界条件的圆形孔洞对SH波散射的波函数。利用这一波函数，则可将该问题转化成对一个圆形孔洞散射的求解问题。该问题的解答最终又可归结为对一组无究代数方程组的求解问题，并可利用截断有限项的方法对其进行计算，最后给出了有关圆形也洞附近动应力集中问题的算例和数值结果，并讨论了波数与圆孔至自由边界距离变化对动应力集中的影响。     

香港海域叶绿素-a浓度的时空分布规律

选取香港海域7个水环境控制区在1988－1999年期间每月或每半月定位边疆聚样的37个水质测站，每个测站选用17个水质参数，研究香港海域海岸带水体叶绿素－a浓度及其相关因子的时空分布规律。对37个测站17个参数作聚类分析，结果表明，香港海域东部由半封闭海湾组成的水域控制区，其赤潮发生频率较高；西部水域属于河口环境。多变量分析结果表明，BOD5对叶绿素－a浓度普遍存在显著性影响，氮和光照条件在东部地叶绿素－a浓度的影响比西部海域更显著，而磷以及包括盐度，温度，溶解氧和pH在内的海洋物理化学条件在西部海域有更显著的影响。在整个香港海域，年内平均最高叶绿素－a浓度主要出现在冬末春初和夏末秋初，东部海域的年平均叶绿素－a浓度一般高于西部海域。香港海域的叶绿素－a浓度普遍存在一个8－10年的周期性变化规律。     

区域经济空间集中化的产业成因分析——兼析海南省经济空间集中化问题

经济空间集中化起因于产业经济活动在一定空间内聚集并形成大规模的专业化生产，它以区域城市为增长中心，与区域产业结构转变有着密切的关系。经济空间集中化过程大致可以划分为三个与区域产业结构转变有关的经济增长阶段：初级阶段——均衡低速增长；中级阶段——集中快速增长；高级阶段——稳定增长。     

格罗夫山:我国新发现的一个陨石富集区

中国南极考察队在1998—2000年两次对南极洲格罗夫山地区进来了考察,共回收32块陨石,根据陨石的分布位置和岩石化学类型的差异性,初步确定格罗夫山是我国新发现的一个陨石富集区,但是该区的陨石富集模式还有待于进一步研究。